Tentative detection of ethylene glycol toward W51/e2 and G34.3+0.2

How complex organic - and potentially prebiotic - molecules are formed in regions of low- and high-mass star-formation remains a central question in astrochemistry. In particular, with just a few sources studied in detail, it is unclear what role environment plays in complex molecule formation. In this light, a comparison of relative abundances of related species between sources might be useful to explain observed differences. We seek to measure the relative abundance between three important complex organic molecules, ethylene glycol ((CH$_2$OH)$_2$), glycolaldehyde (CH$_2$OHCHO) and methyl formate (HCOOCH$_3$), toward high-mass protostars and thereby provide additional constraints on their formation pathways. We use IRAM 30-m single dish observations of the three species toward two high-mass star-forming regions - W51/e2 and G34.3+0.2 - and report a tentative detection of (CH2OH)2 toward both sources. Assuming that (CH$_2$OH)$_2$, CH$_2$OHCHO and HCOOCH$_3$ spatially coexist, relative abundance ratios, HCOOCH$_3$/(CH$_2$OH)$_2$, of 31 and 35 are derived for G34.3+0.2 and W51/e2, respectively. CH$_2$OHCHO is not detected, but the data provide lower limits to the HCOOCH$_3$/CH$_2$OHCHO abundance ratios of $\ge$193 for G34.3+0.2 and $\ge$550 for W51/e2. A comparison of these results to measurements from various sources in the literature indicates that the source luminosities may be correlated with the HCOOCH$_3$/(CH$_2$OH)$_2$ and HCOOCH$_3$/CH$_2$OHCHO ratios. This apparent correlation may be a consequence of the relative timescales each source spend at different temperatures-ranges in their evolution. Furthermore, we obtain lower limits to the ratio of (CH$_2$OH)$_2$/CH2OHCHO for G34.3+0.2 ($\ge$6) and W51/e2 ($\ge$16). This result confirms that a high (CH$_2$OH)$_2$/CH$_2$OHCHO abundance ratio is not a specific property of comets, as previously speculated.Comment: Accepted for publication by A&

Exploring the Origins of Earth's Nitrogen: Astronomical Observations of Nitrogen-bearing Organics in Protostellar Environments

It is not known whether the original carriers of Earth's nitrogen were molecular ices or refractory dust. To investigate this question, we have used data and results of Herschel observations towards two protostellar sources: the high-mass hot core of Orion KL, and the low-mass protostar IRAS 16293-2422. Towards Orion KL, our analysis of the molecular inventory of Crockett et al. (2014) indicates that HCN is the organic molecule that contains by far the most nitrogen, carrying $74_{-9}^{+5}\%$ of nitrogen-in-organics. Following this evidence, we explore HCN towards IRAS 16293-2422, which we consider a solar analog. Towards IRAS 16293-2422, we have reduced and analyzed Herschel spectra of HCN, and fit these observations against "jump" abundance models of IRAS 16293-2422's protostellar envelope. We find an inner-envelope HCN abundance $X_{\textrm{in}} = 5.9\pm0.7 \times 10^{-8}$ and an outer-envelope HCN abundance $X_{\textrm{out}} = 1.3 \pm 0.1 \times 10^{-9}$. We also find the sublimation temperature of HCN to be $T_{\textrm{jump}} = 71 \pm 3$~K; this measured $T_{\textrm{jump}}$ enables us to predict an HCN binding energy $E_{\textrm{B}}/k = 3840 \pm 140$~K. Based on a comparison of the HCN/H2O ratio in these protostars to N/H2O ratios in comets, we find that HCN (and, by extension, other organics) in these protostars is incapable of providing the total bulk N/H2O in comets. We suggest that refractory dust, not molecular ices, was the bulk provider of nitrogen to comets. However, interstellar dust is not known to have 15N enrichment, while high 15N enrichment is seen in both nitrogen-bearing ices and in cometary nitrogen. This may indicate that these 15N-enriched ices were an important contributor to the nitrogen in planetesimals and likely to the Earth.Comment: Accepted to ApJ; 21 pages, 4 figure

Singlet-Triplet Physics and Shell Filling in Carbon Nanotube Double Quantum Dots

An artifcial two-atomic molecule, also called a double quantum dot (DQD), is an ideal system for exploring few electron physics. Spin-entanglement between just two electrons can be explored in such systems where singlet and triplet states are accessible. These two spin-states can be regarded as the two states in a quantum two-state system, a so-called singlet-triplet qubit. A very attractive material for realizing spin based qubits is the carbon nanotube (CNT), because it is expected to have a very long spin coherence time. Here we show the existence of a gate-tunable singlet-triplet qubit in a CNT DQD. We show that the CNT DQD has clear shell structures of both four and eight electrons, with the singlet-triplet qubit present in the four-electron shells. We furthermore observe inelastic cotunneling via the singlet and triplet states, which we use to probe the splitting between singlet and triplet, in good agreement with theory.Comment: Supplement available at: http://www.fys.ku.dk/~hij/public/singlet-triple_supp.pd

On the origin of H_2CO abundance enhancements in low-mass protostars

High angular resolution H_2CO 218 GHz line observations have been carried out toward the low-mass protostars IRAS 16293-2422 and L1448-C using the Owens Valley Millimeter Array at ~2" resolution. Simultaneous 1.37 mm continuum data reveal extended emission which is compared with that predicted by model envelopes constrained from single-dish data. For L1448-C the model density structure works well down to the 400 AU scale to which the interferometer is sensitive. For IRAS 16293-2422 , a known proto-binary object, the interferometer observations indicate that the binary has cleared much of the material in the inner part of the envelope, out to the binary separation of ~800 AU. For both sources there is excess unresolved compact emission centered on the sources, most likely due to accretion disks ≾200 AU in size with masses of ≳0.02 M_☉ (L1448-C) and ≳0.1 M_☉ (IRAS 16293-2422). The H_2CO data for both sources are dominated by emission from gas close to the positions of the continuum peaks. The morphology and velocity structure of the H_2CO array data have been used to investigate whether the abundance enhancements inferred from single-dish modelling are due to thermal evaporation of ices or due to liberation of the ice mantles by shocks in the inner envelope. For IRAS 16293-2422 the H_2CO interferometer observations indicate the presence of rotation roughly perpendicular to the large scale CO outflow. The H_2CO distribution differs from that of C^(18)O, with C^(18)O emission peaking near MM1 and H_2CO stronger near MM2. For L1448-C, the region of enhanced H_2CO emission extends over a much larger scale >1" than the radius of 50-100 K (0."6-0".15) where thermal evaporation can occur. The red-blue asymmetry of the emission is consistent with the outflow; however the velocities are significantly lower. The H_2CO 3_(22)-2_(21)/3_(03)-2_(02) flux ratio derived from the interferometer data is significantly higher than that found from single-dish observations for both objects, suggesting that the compact emission arises from warmer gas. Detailed radiative transfer modeling shows, however, that the ratio is affected by abundance gradients and optical depth in the 3_(03)-2_(02) line. It is concluded that a constant H_2CO abundance throughout the envelope cannot fit the interferometer data of the two H_2CO lines simultaneously on the longest and shortest baselines. A scenario in which the H_2CO abundance drops in the cold dense part of the envelope where CO is frozen out but is undepleted in the outermost region provides good fits to the single-dish and interferometer data on short baselines for both sources. Emission on the longer baselines is best reproduced if the H_2CO abundance is increased by about an order of magnitude from ~ 10^(-10) to ~ 10^(-9) in the inner parts of the envelope due to thermal evaporation when the temperature exceeds ~50 K. The presence of additional H_2CO abundance jumps in the innermost hot core region or in the disk cannot be firmly established, however, with the present sensitivity and resolution. Other scenarios, including weak outflow-envelope interactions and photon heating of the envelope, are discussed and predictions for future generation interferometers are presented, illustrating their potential in distinguishing these competing scenarios

Externally heated protostellar cores in the Ophiuchus star-forming region

We present APEX 218 GHz observations of molecular emission in a complete sample of embedded protostars in the Ophiuchus star-forming region. To study the physical properties of the cores, we calculate H$_2$CO and c-C$_3$H$_2$ rotational temperatures, both of which are good tracers of the kinetic temperature of the molecular gas. We find that the H$_2$CO temperatures range between 16 K and 124 K, with the highest H$_2$CO temperatures toward the hot corino source IRAS 16293-2422 (69-124 K) and the sources in the $\rho$ Oph A cloud (23-49 K) located close to the luminous Herbig Be star S 1, which externally irradiates the $\rho$ Oph A cores. On the other hand, the c-C$_3$H$_2$ rotational temperature is consistently low (7-17 K) in all sources. Our results indicate that the c-C$_3$H$_2$ emission is primarily tracing more shielded parts of the envelope whereas the H$_2$CO emission (at the angular scale of the APEX beam; 3600 au in Ophiuchus) mainly traces the outer irradiated envelopes, apart from in IRAS 16293-2422, where the hot corino emission dominates. In some sources, a secondary velocity component is also seen, possibly tracing the molecular outflow.Comment: 19 pages, 9 figures, accepted for publication in Ap

A deeply embedded young protoplanetary disk around L1489 IRS observed by the submillimeter array

Circumstellar disks are expected to form early in the process that leads to the formation of a young star, during the collapse of the dense molecular cloud core. It is currently not well understood at what stage of the collapse the disk is formed or how it subsequently evolves. We aim to identify whether an embedded Keplerian protoplanetary disk resides in the L1489 IRS system. Given the amount of envelope material still present, such a disk would respresent a very young example of a protoplanetary disk. Using the Submillimeter Array (SMA) we have observed the HCO$^+$ $J=$ 3--2 line with a resolution of about 1$''$. At this resolution a protoplanetary disk with a radius of a few hundred AUs should be detectable, if present. Radiative transfer tools are used to model the emission from both continuum and line data. We find that these data are consistent with theoretical models of a collapsing envelope and Keplerian circumstellar disk. Models reproducing both the SED and the interferometric continuum observations reveal that the disk is inclined by 40$^\circ$ which is significantly different to the surrounding envelope (74$^\circ$). This misalignment of the angular momentum axes may be caused by a gradient within the angular momentum in the parental cloud or if L1489 IRS is a binary system rather than just a single star. In the latter case, future observations looking for variability at sub-arcsecond scales may be able to constrain these dynamical variations directly. However, if stars form from turbulent cores, the accreting material will not have a constant angular momentum axis (although the average is well defined and conserved) in which case it is more likely to have a misalignment of the angular momentum axes of the disk and the envelope.Comment: 11 pages, 13 figures, accepted by A&

On C*-algebras generated by pairs of q-commuting isometries

We consider the C*-algebras O_2^q and A_2^q generated, respectively, by isometries s_1, s_2 satisfying the relation s_1^* s_2 = q s_2 s_1^* with |q| < 1 (the deformed Cuntz relation), and by isometries s_1, s_2 satisfying the relation s_2 s_1 = q s_1 s_2 with |q| = 1. We show that O_2^q is isomorphic to the Cuntz-Toeplitz C*-algebra O_2^0 for any |q| < 1. We further prove that A_2^{q_1} is isomorphic to A_2^{q_2} if and only if either q_1 = q_2 or q_1 = complex conjugate of q_2. In the second part of our paper, we discuss the complexity of the representation theory of A_2^q. We show that A_2^q is *-wild for any q in the circle |q| = 1, and hence that A_2^q is not nuclear for any q in the circle.Comment: 18 pages, LaTeX2e "article" document class; submitted. V2 clarifies the relationships between the various deformation systems treate

FeederAnt - An autonomous mobile unit feeding outdoor pigs

Small robots and the concept of decentralized animal husbandry make it possible to renew the principles of organic agriculture. The farm animals will be able to use the same type of housing and are placed integrated with the fields. This is expected to achieve a better utilization of nutrients and a better survival rate for useful insects and micro organisms. The small fields are flexible and could fit to the variation in soil structure topography. This type of precision agriculture has the possibility of increasing biodiversity. The paper presents the concept of an autonomic feeding system for outdoor piglets. Initial results are presented using a remote controlled feeding unit (a prototype of the FeederAnt) to feed several pens with piglets. The FeederAnt drives into the grass paddocks twice a day and position itself in a new location for each feeding. This will help to distribute the manure from the animals evenly over the grass paddock to prevent point leaching of nutrients. The FeederAnt replaces many stationary feeding tables and reduce the amount of daily manual feeding routines. Further, it is expected that the problem with vermins will be solved since no feed residues will be left within the pens.

Electron transport in single wall carbon nanotube weak links in the Fabry-Perot regime

We fabricated reproducible high transparency superconducting contacts consisting of superconducting Ti/Al/Ti trilayers to gated single-walled carbon nanotubes (SWCNTs). The reported semiconducting SWCNT have normal state differential conductance up to $3e^2/h$ and exhibit clear Fabry-Perot interference patterns in the bias spectroscopy plot. We observed subharmonic gap structure in the differential conductance and a distinct peak in the conductance at zero bias which is interpreted as a manifestation of a supercurrent. The gate dependence of this supercurrent as well as the excess current are examined and compared to a coherent theory of superconducting point contacts with good agreement.Comment: 10 pages, 4 figure