Silicone rubber selection for passive sampling of pesticides in water.

The authors thank G. Raffin and M. Hangouet (ISA, UMR 5280) for TGA analysis and interpretation, and C. Guillemain (Irstea) for analytical support.International audienceSilicone rubber can extract organic compounds with a broad range of polarities (logKow>2-3) from aqueous samples. Such compounds include substances of major concern in the protection of aquatic ecosystems and human health, e.g. pesticides. Silicone rubbers (SRs) with various characteristics have been successfully used in sorptive methods for water sample extraction in the laboratory (SPME, SBSE), and for passive sampling in aquatic environments. However, only few studies have evaluated variability in organic compound sorption due to the origin of SRs, particularly for pesticides. The aim of this study was to select an SR for the extraction of pesticides from water samples by passive sampling. To this end we measured the impact of seven SR formulations on sorption capacity, defined by the partition coefficient (Ksw). Kinetic experiments and sorption isotherms were performed to determine extraction recovery as a selection criterion for SRs, and pesticide partition coefficients. Very large differences in affinity for pesticides were found between two kinds of SRs: "Polymerized SR kits" and "Manufactured SRs". One SR was chosen among the "Manufactured SRs", and the Ksw values of 21 pesticides were determined, filling a gap in the literature (1.50<logKow<5.51). In light of sorption properties, literature data and additional economic and technical factors, we suggest using SR from Goodfellow in future work to reduce the variability of Ksw literature values

Testing for w<-1 in the Solar System

In scalar-tensor theories of gravity, the equation of state of dark energy, w, can become smaller than -1 without violating any energy condition. The value of w today is tied to the level of deviations from general relativity which, in turn, is constrained by solar system and pulsars timing experiments. The conditions on these local constraints for w to be significantly less than -1 are established. It is demonstrated that this requires to consider theories that differ from the Jordan-Fierz-Brans-Dicke theory and that involve either a steep coupling function or a steep potential. It is also shown how a robust measurement of w could probe scalar-tensor theories.Comment: 4 pages, 1 figur

On the properties of the transition matrix in bouncing cosmologies

We elaborate further on the evolution properties of cosmological fluctuations through a bounce. We show this evolution to be describable either by ``transmission'' and ``reflection'' coefficients or by an effective unitary S-matrix. We also show that they behave in a time reversal invariant way. Therefore, earlier results are now interpreted in a different perspective and put on a firmer basis.Comment: 4 pages, 1 figure, to appear in PR

On the "Causality Argument" in Bouncing Cosmologies

We exhibit a situation in which cosmological perturbations of astrophysical relevance propagating through a bounce are affected in a scale-dependent way. Involving only the evolution of a scalar field in a closed universe described by general relativity, the model is consistent with causality. Such a specific counter-example leads to the conclusion that imposing causality is not sufficient to determine the spectrum of perturbations after a bounce provided it is known before. We discuss consequences of this result for string motivated scenarios.Comment: 4 pages, 1 figure, ReVTeX, to appear in Phys. Rev. Let

Trans-Planckian Dark Energy?

It has recently been proposed by Mersini et al. 01, Bastero-Gil and Mersini 02 that the dark energy could be attributed to the cosmological properties of a scalar field with a non-standard dispersion relation that decreases exponentially at wave-numbers larger than Planck scale (k_phys > M_Planck). In this scenario, the energy density stored in the modes of trans-Planckian wave-numbers but sub-Hubble frequencies produced by amplification of the vacuum quantum fluctuations would account naturally for the dark energy. The present article examines this model in detail and shows step by step that it does not work. In particular, we show that this model cannot make definite predictions since there is no well-defined vacuum state in the region of wave-numbers considered, hence the initial data cannot be specified unambiguously. We also show that for most choices of initial data this scenario implies the production of a large amount of energy density (of order M_Planck^4) for modes with momenta of order M_Planck, far in excess of the background energy density. We evaluate the amount of fine-tuning in the initial data necessary to avoid this back-reaction problem and find it is of order H/M_Planck. We also argue that the equation of state of the trans-Planckian modes is not vacuum-like. Therefore this model does not provide a suitable explanation for the dark energy.Comment: RevTeX - 15 pages, 7 figures: final version to appear in PRD, minor changes, 1 figure adde

On Signatures of Short Distance Physics in the Cosmic Microwave Background

Following a self-contained review of the basics of the theory of cosmological perturbations, we discuss why the conclusions reached in the recent paper by Kaloper et al are too pessimistic estimates of the amplitude of possible imprints of trans-Planckian (string) physics on the spectrum of cosmic microwave anisotropies in an inflationary Universe. It is shown that the likely origin of large trans-Planckian effects on late time cosmological fluctuations comes from nonadiabatic evolution of the state of fluctuations while the wavelength is smaller than the Planck (string) scale, resulting in an excited state at the time that the wavelength crosses the Hubble radius during inflation.Comment: 11 pages, 4 figure

Geodesic Deviation in Kaluza-Klein Theories

We study in detail the equations of the geodesic deviation in multidimensional theories of Kaluza-Klein type. We show that their 4-dimensional space-time projections are identical with the equations obtained by direct variation of the usual geodesic equation in the presence of the Lorentz force, provided that the fifth component of the deviation vector satisfies an extra constraint derived here.Comment: 5 pages, Revtex, 1 figure. To appear in Phys. Rev. D (Brief Report

The Corley-Jacobson dispersion relation and trans-Planckian inflation

In this Letter we study the dependence of the spectrum of fluctuations in inflationary cosmology on possible effects of trans-Planckian physics, using the Corley/Jacobson dispersion relations as an example. We compare the methods used in previous work [1] with the WKB approximation, give a new exact analytical result, and study the dependence of the spectrum obtained using the approximate method of Ref. [1] on the choice of the matching time between different time intervals. We also comment on recent work subsequent to Ref. [1] on the trans-Planckian problem for inflationary cosmology.Comment: 6 pages, Revtex

Coupling Quintessence to Inflation in Supergravity

The evolution of the quintessence field during a phase of chaotic inflation is studied. The inflaton and the quintesssence field are described in a supergravity framework where the coupling between the inflaton and quintessence is induced by non-renormalisable operators suppressed by the Planck mass. We show that the resulting quintessence potential during inflation possesses a time--dependent minimum playing the role of an attractor. The presence of this attractor forces the quintessence field to be small during inflation. These initial conditions are such that the quintessence field is on tracks now.Comment: 16 pages, 6 figure

The scalar bi-spectrum during preheating in single field inflationary models

In single field inflationary models, preheating refers to the phase that immediately follows inflation, but precedes the epoch of reheating. During this phase, the inflaton typically oscillates at the bottom of its potential and gradually transfers its energy to radiation. At the same time, the amplitude of the fields coupled to the inflaton may undergo parametric resonance and, as a consequence, explosive particle production can take place. A priori, these phenomena could lead to an amplification of the super-Hubble scale curvature perturbations which, in turn, would modify the standard inflationary predictions. However, remarkably, it has been shown that, although the Mukhanov-Sasaki variable does undergo narrow parametric instability during preheating, the amplitude of the corresponding super-Hubble curvature perturbations remain constant. Therefore, in single field models, metric preheating does not affect the power spectrum of the large scale perturbations. In this article, we investigate the corresponding effect on the scalar bi-spectrum. Using the Maldacena's formalism, we analytically show that, for modes of cosmological interest, the contributions to the scalar bi-spectrum as the curvature perturbations evolve on super-Hubble scales during preheating is completely negligible. Specifically, we illustrate that, certain terms in the third order action governing the curvature perturbations which may naively be expected to contribute significantly are exactly canceled by other contributions to the bi-spectrum. We corroborate selected analytical results by numerical investigations. We conclude with a brief discussion of the results we have obtained.Comment: v1: 15 pages, 4 figures; v2: 15 pages, 4 figures, discussion and references added, to appear in Phys. Rev.