CONSIDERATIONS ON ENERGETIC CROPS POTENTIAL

In order to breathe fresh and clean air, nature and terrestrial atmosphere should be preserved and protected. Carbon emissions represent one of the main enemies of air quality. Recently, carbon emissions have surpassed all the predictions because the excessive industrialization, becoming the determining factor for global warming. A viable alternative to carbon emissions reduction is the utilization of energy sources that can diminish the noxious substances emissions up to zero. This can be done by using the power of wind, sun, water, energy plants, etc. Among the energetic potential plants, the biomass is obtained- a form of renewable energy which final product is biofuel

A multinuclear solid state NMR, density functional theory and X-Ray diffraction study of hydrogen bonding in Group I hydrogen dibenzoates

An NMR crystallographic approach incorporating multinuclear solid state NMR (SSNMR), X-ray structure determinations and density functional theory (DFT) are used to characterise the H bonding arrangements in benzoic acid (BZA) and the corresponding Group I alkali metal hydrogen dibenzoates (HD) systems. Since the XRD data often cannot precisely confirm the proton position within the hydrogen bond, the relationship between the experimental SSNMR parameters and the ability of gauge included plane augmented wave (GIPAW) DFT to predict them becomes a powerful constraint that can assist with further structure refinement. Both the 1H and 13C MAS NMR methods provide primary descriptions of the H bonding via accurate measurements of the 1H and 13C isotropic chemical shifts, and the individual 13C chemical shift tensor elements; these are unequivocally corroborated by DFT calculations, which together accurately describe the trend of the H bonding strength as the size of the monovalent cation changes. In addition, 17O MAS and DOR NMR form a powerful combination to characterise the O environments, with the DOR technique providing highly resolved 17O NMR data which helps verify unequivocally the number of inequivalent O positions for the conventional 17O MAS NMR to process. Further multinuclear MAS and static NMR studies involving the quadrupolar 7Li, 39K, 87Rb and 133Cs nuclei, and the associated DFT calculations, provide trends and a corroboration of the H bond geometry which assist in the understanding of these arrangements. Even though the crystallographic H positions in each H bonding arrangement reported from the single crystal X-ray studies are prone to uncertainty, the good corroboration between the measured and DFT calculated chemical shift and quadrupole tensor parameters for the Group I alkali species suggest that these reported H positions are reliable

ASPECTS REGARDING THE CULTIVATION OF TOPINAMBOUR

Jerusalem artichoke (Helianthus tuberosusL.) is a perennial plant whose tubers containinulin,which can be used as raw material for healthy products, sweeteners, bioethanol and animal feed. The objective of this paper is o present some consideration about this very important plant for agriculture, medicine, food and health

TRACEABILITY AND FOOD LABELING CONSIDERATIONS

This article presents the current traceability and labeling of foods and how this can be improved with WEB and Cloud Computing applications. The paper label contains details on the traceability and labeling elements applied to products, traceability and labeling elements that are listed under EU and Consumer Guidance on Food (EU) and ways to make this information simpler understandable for end-users and for the competent authorities there is a transparent method of verifying all the information necessary to track and verify the activity of all factors involved in the production, distribution and sale of food product

EQUIPMENT FOR EXTRACTING AND PLANTING EARTH BALE ROOT PLANTS

Trees are one of the biggest  organisms living on the planet and their role is extremely important, namely that to maintain the purity of air we breathe, improve water quality, prevent soil erosion, reduce noise level, ensure food, construction materials and eventually people comfort. Plantation and transplantation of trees by means of specialized equipment  in comparison with human force leads to an increased planting speed and higher yield, economically speaking. This paper is designed to present different constructive variants, at world level, of equipment for extracting and planting trees with earth bale at their roots, necessary for afforestation, landscape design, tree nurseries

CONSIDERATIONS ON THE EXTRACTION TECHNOLOGY OF SUGAR SORGHUM JUICE

Lately there has been an increase in drought periods but also an increase in population and therefore in consumption of food and fuel while arable land remains the same which leads to the cultivation of species with high energy potential and high nutritional potential as drought resistant, species of sorghum. The sorghum is used for: food (flours, juices, syrups, vinegar, etc.), for animal feed, but also in the industry for fuel, energy, building materials, paper, proposes to carry out an analysis of the technologies for obtaining juice from sorghum

Efficient photocatalytic reduction of CO2 catalyzed by the metal–organic framework MFM-300(Ga)

Photocatalytic reduction of CO2 to carbon fuels is an important target but highly challenging to achieve. Here, we report the efficient photoconversion of CO2 into formic acid over a Ga(III)-based metal–organic framework (MOF) material using triethanolamine as the sacrificial agent. Under light irradiation and at room temperature, photoreduction of CO2 over MFM-300(Ga) yields formic acid with a selectivity of 100%, a high productivity of 502 ± 18 μmol·gcat−1·h−1, and excellent catalytic stability. In situ electron paramagnetic resonance spectroscopy reveals that MFM-300(Ga) promotes the generation of CO2•− radical anions as a reaction intermediate driven by strong binding and activation of CO2 molecules at the bridging –OH sites within the pore. This study represents the first example of a Ga(III)-based MOF catalyst for CO2 reduction