Deconvoluting Reversal Modes in Exchange Biased Nanodots

Ensemble-averaged exchange bias in arrays of Fe/FeF2 nanodots has been deconvoluted into local, microscopic, bias separately experienced by nanodots going through different reversal modes. The relative fraction of dots in each mode can be modified by exchange bias. Single domain dots exhibit a simple loop shift, while vortex state dots have asymmetric shifts in the vortex nucleation and annihilation fields, manifesting local incomplete domain walls in these nanodots as magnetic vortices with tilted cores.Comment: 17 pages, 3 figures. Phys. Rev. B in pres

Dynamics of Spontaneous Magnetization Reversal in Exchange Biased Heterostructures

The dependence of thermally induced spontaneous magnetization reversal on time-dependent cooling protocols was studied. Slower cooling and longer waiting close to the N\`{e}el temperature of the antiferromagnet ($T_N$) enhances the magnetization reversal. Cycling the temperature around $T_N$ leads to a thermal training effect under which the reversal magnitude increases with each cycle. These results suggest that spontaneous magnetization reversal is energetically favored, contrary to our present understanding of positive exchange bias

Fabrication and structural characterization of highly ordered sub-100-nm planar magnetic nanodot arrays over 1 cm2 coverage area

Porous alumina masks are fabricated by anodization of aluminum films grown on both semiconducting and insulating substrates. For these self-assembled alumina masks, pore diameters and periodicities within the ranges of 10–130 and 20–200nm, respectively, can be controlled by varying anodization conditions. 20nm periodicities correspond to pore densities in excess of 1012 per square inch, close to the holy grail of media with 1Tbit∕in.2 density. With these alumina masks, ordered sub-100-nm planar ferromagnetic nanodot arrays covering over 1cm2 were fabricated by electron beam evaporation and subsequent mask lift-off. Moreover, exchange-biased bilayer nanodots were fabricated using argon-ion milling. The average dot diameter and periodicity are tuned between 25 and 130nm and between 45 and 200nm, respectively. Quantitative analyses of scanning electron microscopy (SEM) images of pore and dot arrays show a high degree of hexagonal ordering and narrow size distributions. The dot periodicity obtained from grazi..

Loop Bifurcation and Magnetization Rotation in Exchange Biased Ni/FeF2

Exchange biased Ni/ FeF2 films have been investigated using vector coil vibrating sample magnetometry as a function of the cooling field strength H_FC. In films with epitaxial FeF2, a loop bifurcation develops with increasing H_FC as it divides into two sub-loops shifted oppositely from zero field by the same amount. The positively biased sub-loop grows in size with H_FC until only a single positively shifted loop is found. Throughout this process, the negative/positive (sub)loop shift has maintained the same discrete value. This is in sharp contrast to films with twinned FeF2 where the exchange field gradually changes with increasing H_FC. The transverse magnetization shows clear correlations with the longitudinal sub-loops. Interestingly, over 85% of the Ni reverses its magnetization by rotation, either in one step or through two successive rotations. These results are due to the single crystal nature of the antiferromagnetic FeF2, which breaks down into two opposite regions of large domains.Comment: 16 pages, 3 figures, to appear in PR

Bi-domain state in the exchange bias system FeF2/Ni

Independently exchange biased subsystems can coexist in FeF2/Ni bilayers after various field-cooling protocols. We find double hysteresis loops for intermediate cooling fields, while for small or large cooling fields a negatively or positively shifted single loop, respectively, are encountered. Both the subloops and the single loops have the same absolute value of the exchange bias field, mu_0 H_E = 0.09 T. This suggests that the antiferromagnet breaks into two magnetic subsystems with opposite signs but equal magnitude of bias acting on the ferromagnet. In this case the ferromagnet does not experience an average bias from the antiferromagnet but rather two independent subsystems ('bi-domain' state). This idea is confirmed by micromagnetic simulations including the effect of the antiferromagnet. We also present experiments, where thermally activated motion of these antiferromagnetic 'domain' boundaries can be achieved

Antiferromagnetic domain size and exchange bias

Journals published by the American Physical Society can be found at http://journals.aps.org/Using neutron diffraction, we measured the sizes of antiferromagnetic domains in three ferromagnet/antiferromagnet bilayer samples as a function of the magnitude and sign of exchange bias, temperature, and antiferromagnet composition. Neutron-scattering techniques were applied to thin films with masses less than 10 mu g. We found the antiferromagnetic domain size to be consistently small regardless of the exchange bias. For a Co/untwinned single crystalline antiferromagnet (AF)-fluoride bilayer, the antiferromagnetic domain size is comparable to the crystallographic domain size of the AF. For one sample the highest temperature at which the exchange bias was nonzero (i.e., the blocking temperature) was suppressed by similar to 3 K compared to the Neel temperature of the antiferromagnet

Gas adsorption and capillary condensation in nanoporous alumina films

"Gas adsorption and capillary condensation of organic vapors are studied by optical interferometry, using anodized nanoporous alumina films with controlled geometry (cylindrical pores with diameters in the range of 10-60 nm). The optical response of the film is optimized with respect to the geometric parameters of the pores, for potential performance as a gas sensor device. The average thickness of the adsorbed film at low relative pressures is not affected by the pore size. Capillary evaporation of the liquid from the nanopores occurs at the liquid-vapor equilibrium described by the classical Kelvin equation with a hemispherical meniscus. Due to the almost complete wetting, we can quantitatively describe the condensation for isopropanol using the Cohan model with a cylindrical meniscus in the Kelvin equation. This model describes the observed hysteresis and allows us to use the adsorption branch of the isotherm to calculate the pore size distribution of the sample in good agreement with independent structural measurements. The condensation for toluene lacks reproducibility due to incomplete surface wetting. This exemplifies the relevant role of the fluid-solid (van der Waals) interactions in the hysteretic behavior of capillary condensation."http://deepblue.lib.umich.edu/bitstream/2027.42/64187/1/nano8_31_315709.pd

First-principles study of electronic, vibrational, elastic, and magnetic properties of FeF 2 as a function of pressure

We report systematic ab initio calculations of the electronic band structure, phonon dispersion relation, and the structural characterization of FeF 2 in the rutile (P 4 2 /mnm) structure as well as in several high-pressure phases by means of the generalized gradient approximation (GGA) + U approximation. Using the phonon dispersion relations, we calculated the Gibbs free energy and evaluated the phase transitions at 300 K, at which most experimental measurements are performed. Calculated Raman and infrared vibrational modes, lattice parameters, and electronic structure for all considered crystalline structures are compared with available experimental data. Our calculations show that at 5.33 GPa, the FeF 2 undergoes a second-order proper ferroelastic phase transition, rutile → CaCl 2 -type structure. This result is supported by the softening of the elastic shear module C s in the rutile phase, the softening (hardening) of the B 1g (A g ) Raman active mode in the rutile (CaCl 2 -type) structure near the transition pressure, and the decrease of the square of the spontaneous strain e ss from the CaCl 2 -type structure. This demonstrates that the rutile → CaCl 2 -type phase transition is driven by the coupling between the Raman active B 1g mode and shear modulus C s . At 8.22 GPa, the CaCl 2 -type structure undergoes a first-order phase transition to the P bca phase, a distorted fcc P a3 phase with a volume reduction of V ≈ 7%, as reported in experiments. Upon further increase of the pressure, the P bca phase transforms to a F mmm phase othorhombic center-type structure at ∼20.38 GPa, with V ≈ 2.5%. Finally, at 25.05 GPa, there is a phase transition to the orthorhombic cotunnite structure (P nma space group), with V ≈ 5.8%, which is stable up to 45 GPa, the largest considered pressure. The coordination number for the Fe ion in each phase is 6, 6, 6, 8, and 9 for rutile, CaCl 2 -type, P bca, F mmm, and cotunnite structures, respectively. The evolution of the band gap, phonon frequencies, and magnetic moment of Fe ion as a function of the applied pressure is reported for all studied phases. The exchange constants J 1 , J 2 , and J 3 , calculated for rutile and the lowest Gibbs free-energy high-pressure phases, are reported