223 research outputs found

    Non-renewable resource prices: Structural breaks and long term trends

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    In this paper we examine the time series properties of nine non-renewable resources. In particular we are concerned with understanding the relationship between the number of structural breaks in the data and the nature of the resource price path, i.e. is it stationary or a random walk. To undertake our analysis we employ a number of relevant econometric methods including Bai and Perron`s (1998) multiple structural break dating method. Our results indicate that these series are in many cases stationary and subject to a number of structural breaks. These results indicate that a deterministic model of resources prices may well be appropriate.structural change, non-renewable resources, breaks, resource depletion

    Distinct modes of floor plate induction in the chick embryo

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    To begin to reconcile models of floor plate formation in the vertebrate neural tube, we have performed experiments aimed at understanding the development of the early floor plate in the chick embryo. Using real-time analyses of cell behaviour, we provide evidence that the principal contributor to the early neural midline, the future anterior floor plate, exists as a separate population of floor plate precursor cells in the epiblast of the gastrula stage embryo, and does not share a lineage with axial mesoderm. Analysis of the tissue interactions associated with differentiation of these cells to a floor plate fate reveals a role for the nascent prechordal mesoderm, indicating that more than one inductive event is associated with floor plate formation along the length of the neuraxis. We show that Nr1, a chick nodal homologue, is expressed in the nascent prechordal mesoderm and we provide evidence that Nodal signalling can cooperate with Shh to induce the epiblast precursors to a floor-plate fate. These results indicate that a shared lineage with axial mesoderm cells is not a pre-requisite for floor plate differentiation and suggest parallels between the development of the floor plate in amniote and anamniote embryos

    An Investigation of the Deuteration of Mandelic Acid With an Additional Paper on the Measurement of Acidity at Temperatures Over 100&deg

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    The deuteration of optically active mandelic acid was investigated by shaking it in a sealed, evacuated tube under various conditions of temperature, and with different catalytic agents. The effect of acid, base, and platinum catalysts was examined, and in each case the degree of exchange occurring in the alpha position of the mandelic acid was correlated with the simultaneous change in its optical activity. The results indicated that with a basic catalyst present, the reaction occurred by a racemisation mechanism, an attacked molecule having an equal chance of retaining its configuration or undergoing an inversion. The platinum-catalysed exchange in acid solution was more complex, with both racemisation and retention mechanisms playing a part. With no catalyst present, racemisation of the acid occured, but without a corresponding exchange. In presence of platinum, the benzene ring, as well as the alpha hydrogen atom, was deuterated. These conclusions were confirmed by resolutions of the deuterated mandelic acid, when the observed deuterium contents of the resolved fractions were found to be in good agreement with the figures calculated assuming the mechanisms postulated for the first part of the experiment. The resolution also showed that alpha hydrogen exchange and nuclear deuteration were quite independent. Mechanisms for the various reactions have been suggested, and involve an Initial ionisation of the alpha hydrogen atom, either on the catalyst surface, or under the influence of a basic catalyst. The racemisation without exchange is considered to occur by a mechanism involving an initial fission of the bond between the alpha carbon atom and the carboxyl group

    A General Equilibrium Model of Environmental Option Values

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    In this paper we consider the option value of the environment employing a stochastic general equilibrium growth model. In our model, as in existing studies, because of irreversibility, the environment has significant real option value. However, unlike the existing literature, the value of the environment is endogenously determined in our general equilibrium setting. In our model, the elasticity of substitution between the environment and consumption not only has quantitative effects but also qualitative effects on the option value of the environment and the optimal allocation of land. We also show that the volatility of the exogenous shock process has quantitatively significant effects on the size of the option value which has important implications for the practical estimation of environmental option values
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