138 research outputs found
Enhancement of the Curie temperature in small particles of weak itinerant ferromagnets
Self consistent renormalization theory of itinerant ferromagnets is used to
calculate the Curie temperature of clusters down to approximately 100 atoms in
size. In these clusters the electrons responsible for the magnetic properties
are assumed to be (weakly) itinerant. It is shown that the Curie temperature
can be larger than in the bulk. The effect originates from the phenomenon of
level repulsion in chaotic quantum systems, which suppresses spin fluctuations.
Since the latter destroy the magnetic order the resulting Curie temperature
increases, contrary to expectations of the naive Stoner picture. The
calculations are done assuming that the energy levels of the cluster are
described by the Gaussian Orthogonal Ensemble of random matrix theory.Comment: Phys. Rev. B, accepted for publicatio
Model Risks in the Financial Sphere under the Conditions of the Use of Artificial Intelligence and Machine Learning
Objective: within the framework of RegTech and SupTech technologies, to assess the transformation of model risks and ways to minimize them under the increasing use of artificial intelligence methods.Methods: a systematic approach to the analysis of the quality of economic models. Historical, logical, and statistical methods of research.Results: the Russian and foreign experience of accounting for model risks in the financial industry is considered. Theoretical and practical works on the regulation and management of model risks in the activities of financial sector organizations are studied. The role of machine learning and artificial intelligence technologies in solving the modern problems in the functioning and regulation of financial organizations is determined. The key model risks are considered, as well as the directions of changing their specifics as a result of the artificial intelligence technologies development, primarily machine learning, and increasing the capabilities for storage and transmission of a large amount of data. The main methods of data processing and model construction are considered, as well as their advantages in terms of reducing model risks. It is determined that the reduction of model risks using RegTech and SupTech technologies is possible due to the development of artificial intelligence technologies, which will require, among other things, the elaboration of the appropriate legal field.Scientific novelty: the unique feature of the article is a comprehensive consideration of the problem of model risks in the finance industry and of the impact of artificial intelligence technologies on them in mathematical, legal, economic aspects, as well as the description of the situation in this area both abroad and in Russia.Practical significance: the information presented in the article can be used by regulatory authorities and commercial banks in the tasks related to minimizing specific model risks in their activities
Magnetic properties of Co doped Nb clusters
From magnetic deflection experiments on isolated Co doped Nb clusters we made
the interesting observation of some clusters being magnetic, while others
appear to be non-magnetic. There are in principle two explanations for this
behavior. Either the local moment at the Co site is completely quenched or it
is screened by the delocalized electrons of the cluster, i.e. the Kondo effect.
In order to reveal the physical origin, we conducted a combined theoretical and
experimental investigation. First, we established the ground state geometry of
the clusters by comparing the experimental vibrational spectra with those
obtained from a density functional theory study. Then, we performed an analyses
based on the Anderson impurity model. It appears that the non-magnetic clusters
are due to a complete quenching of the local Co moment and not due to the Kondo
effect. In addition, the magnetic behavior of the clusters can be understood
from an inspection of their electronic structure. Here magnetism is favored
when the effective hybridization around the chemical potential is small, while
the absence of magnetism is signalled by a large effective hybridization around
the chemical potential.Comment: 14 pages, 8 figure
Dynamics of pH-sensitive nitroxide radicals in water adsorbed in ordered mesoporous molecular sieves by EPR Spectroscopy
A spin pH probe technique was used to study the influence of the channel diameter on the EPR spectra of pH-sensitive nitroxide radicals (NR) located in the channels of the mesoporous molecular sieves MCM-41 and SBA-15 with diameters ranging from 2.3 to 8.1 nm. From EPR spectra analysis and the results of the NR retention by the mesoporous molecular sieves upon washing with an aqueous KCl solution, the regularities of NR molecular location inside the channels were studied. The obtained dependence of the fraction of the radical molecules in the fast motional regime (with the rotational correlation times, τc = 2 × 10-11 s-9 × 10-11s) in the channels of the mesoporous molecular sieves as a function of pH indicates that both NR in the fast and slow motional regime (with τc = 8 × 10 -9s-7 × 10-10s) may be used for estimation of the solution acidity inside the channels and of the near-surface electrical potential. © 2013 Elsevier Inc. All rights reserved
Correlation effects and orbital magnetism of Co clusters
Recent experiments on isolated Co clusters have shown huge orbital magnetic
moments in comparison with their bulk and surface counterparts. These clusters
hence provide the unique possibility to study the evolution of the orbital
magnetic moment with respect to the cluster size and how competing interactions
contribute to the quenching of orbital magnetism. We investigate here different
theoretical methods to calculate the spin and orbital moments of Co clusters,
and assess the performances of the methods in comparison with experiments. It
is shown that density functional theory in conventional local density or
generalized gradient approximations, or even with a hybrid functional, severely
underestimates the orbital moment. As natural extensions/corrections we
considered the orbital polarization correction, the LDA+U approximation as well
as the LDA+DMFT method. Our theory shows that of the considered methods, only
the LDA+DMFT method provides orbital moments in agreement with experiment, thus
emphasizing the importance of dynamic correlations effects for determining
fundamental magnetic properties of magnets in the nano-size regime
Quantum control on entangled bipartite qubits
Ising interaction between qubits could produce distortion in entangled pairs
generated for engineering purposes (as in quantum computation) in presence of
parasite magnetic fields, destroying or altering the expected behavior of
process in which is projected to be used. Quantum control could be used to
correct that situation in several ways. Sometimes the user should be make some
measurement upon the system to decide which is the best control scheme; other
posibility is try to reconstruct the system using similar procedures without
perturbate it. In the complete pictures both schemes are present. We will work
first with pure systems studying advantages of different procedures. After, we
will extend these operations when time of distortion is uncertain, generating a
mixed state, which needs to be corrected by suposing the most probably time of
distortion.Comment: 10 pages, 5 figure
Linear and nonlinear magneto-optical diffraction from one-dimensional periodic structures
Nonlinear magneto-optical diffraction from periodically structured samples has been studied using magnetization-induced second harmonic generation (MSHG). Several orders of diffraction were clearly observable in MSHG, along with a strong dependence on the magnetization. Sizeable asymmetry between the MSHG signal measured in positive and negative diffraction peaks, especially visible in second order, are explained by Fresnel factors. It was found that first-order diffraction hysteresis loops differ from all others by showing an ''overshoot'' at magnetization reversal, both in MSHG and in the linear magneto-optical Kerr effect. Tentatively this behavior is explained as due to inhomogeneous reversal of the magnetization in the stripes
Symmetry Analysis of Second Harmonic Generation at Surfaces of Antiferromagnets
Using group theory we classify the nonlinear magneto-optical response at
low-index surfaces of fcc antiferromagnets, such as NiO. Structures consisting
of one atomic layer are discussed in detail. We find that optical second
harmonic generation is sensitive to surface antiferromagnetism in many cases.
We discuss the influence of a second type of magnetic atoms, and also of a
possible oxygen sublattice distortion on the output signal. Finally, our
symmetry analysis yields the possibility of antiferromagnetic surface domain
imaging even in the presence of magnetic unit-cell doubling.Comment: 23 pages, 10 figures incorporated. Accepted to Phys. Rev. B,
scheduled for July'9
Electrostatic properties of inner nanopore surfaces of anodic aluminum oxide membranes upon high temperature annealing revealed by EPR of pH-sensitive spin probes and labels
Anodic aluminum oxide (AAO) membranes are versatile nanomaterials that combine the chemically stable and mechanically robust properties of ceramics with homogeneous nanoscale organization that can be tuned to desirable pore diameters and lengths. The AAO substrates feature high surface area that is readily accessible to large and small molecules, making these nanostructures uniquely suited for many possible applications. Examples include templated self-assembly of macroscopically aligned biological membranes and substrates for heterogeneous catalysis. For further development of such applications, one would like to characterize and tune the electrostatic properties of the inner pore surface as well as the local acidity within the nanochannels. Here, we employed electron paramagnetic resonance (EPR) spectroscopy of a small molecule – ionizable nitroxide – as a reporter of the average local acidity in the nanochannels and the local electrostatic potential in the immediate vicinity of the pore surface. The former was achieved by measuring EPR spectra of this molecular probe diffusing in an aqueous phase confined in the AAO nanochannels while for the latter the nitroxide was covalently attached to the hydroxyl group of the alumina surface. We show that the local acidity within the nanochannels is increased by as much as ≈1.48 pH units vs. the pH of bulk solution by decreasing the pore diameter down to ca. 31 nm. Furthermore, the positive surface charge of the as-prepared AAO could be decreased and even switched to a negative surface charge upon annealing the membranes first to 700 °C and then to 1200 °C. For as-prepared AAO, the local electrostatic potential reaches ψ= (163 ± 5) mV for the nitroxide label covalently attached to AAO and located about 0.5 nm away from the surface. Overall, we demonstrate that the acid-based properties of the aqueous volume confined by the AAO nanopores pores can be tuned by either changing the pore diameter from ca. 71 to 31 nm or by thermal annealing to switch the sign of the surface charge. These observations provide a simple and robust means to tailor these versatile high-surface-area nanomaterials for specific applications that depend on acid-base equilibria. © 2020 Elsevier B.V.Russian Foundation for Basic Research. Government Council on Grants, Russian Federation. U.S. Department of Energy. Ministry of Science and Higher Education of the Russian Federation. National Science Foundation. North Carolina State Universit
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