120 research outputs found
Limitations of Near Edge X Ray Absorption Fine Structure as a tool for observing conduction bands in chalcopyrite solar cell heterojunctions
A non optimized interface band alignment in a heterojunctionbased solar cell can have negative eff ects on the current and voltage characteristics of the resulting device. To evaluate the use of Near Edge X ray Absorption Fine Structure spectroscopy NEXAFS as a means to measure the conduction band position, Cu In,Ga S2 chalcopyrite thin film surfaces were investigated as these form the absorber layer in solar cells with the structure ZnO Buffer Cu In,Ga S2 Mo Glass. The composition dependence of the structure of the conduction bands of CuInxGa1 xS2 has been revealed for x 0, 0.67 and 1 with both hard and soft NEXAFS and the resulting changes in conduction band off set at the junction with the bu ffer layer discussed. A comprehensive study of the positions of the absorption edges of all elements was carried out and the development of the conduction band with Ga content was observed, also with respect to calculated densities of state
Investigation of Cu poor and Cu rich Cu In,Ga Se2 CdS interfaces using hard X ray photoelectron spectroscopy
Cu poor and Cu rich Cu In,Ga Se2 CIGSe absorbers were used as substrates for the chemical bath deposition of ultrathin CdS buffer layers in the thickness range of a few nanometers in order to make the CIGSe CdS interface accessible by hard X ray photo emission spectroscopy. The composition of both, the absorber and the buffer layer as well as the energetics of the interface was investigated at room temperature and after heating the samples to elevated temperatures 200 C, 300 C and 400 C . It was found that the amount of Cd after the heating treatment depends on the near surface composition of the CIGSe absorber. No Cd was detected on the Cu poor surface after the 400 C treatment due to its diffusion into the CIGSe layer. In contrast, Cd was still present on the Cu rich surface after the same treatment at 400
Corrigendum to "The Australian bushfires of February 2009 : MIPAS observations and GEM-AQ model results" published in Atmos. Chem. Phys., 13, 1637-1658, 2013
The Australian bushfires of February 2009: MIPAS observations and GEM-AQ model results
Starting on 7 February 2009, southeast Australia was devastated by large bushfires, which burned an area of about 3000 km<sup>2</sup> on this day alone. This event was extraordinary, because a large number of combustion products were transported into the uppermost troposphere and lower stratosphere within a few days. Various biomass burning products released by the fire were observed by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on the Envisat satellite. We tracked the plume using MIPAS C<sub>2</sub>H<sub>2</sub>, HCN and HCOOH single-scan measurements on a day-to-day basis. The measurements were compared with a high-resolution model run of the Global Environmental Multiscale Air Quality (GEM-AQ) model. Generally there is good agreement between the spatial distribution of measured and modelled pollutants. Both MIPAS and GEM-AQ show a fast southeastward transport of the pollutants to New Zealand within one day. During the following 3–4 days, the plume remained northeastward of New Zealand and was located at altitudes of 15 to 18 km. Thereafter its lower part was transported eastward, followed by westward transport of its upper part. On 17 February the eastern part had reached southern South America and on 20 February the central South Atlantic. On the latter day a second relic of the plume was observed moving eastward above the South Pacific. Between 20 February and the first week of March, the upper part of the plume was transported westward over Australia and the Indian Ocean towards southern Africa. First evidence for entry of the pollutants into the stratosphere was found in MIPAS data of 11 February, followed by larger amounts on 17 February and the days thereafter. From MIPAS data, C<sub>2</sub>H<sub>2</sub>/HCN and HCOOH/HCN enhancement ratios of 0.76 and 2.16 were calculated for the first days after the outbreak of the fires, which are considerably higher than the emission ratios assumed for the model run and at the upper end of values found in literature. From the temporal decrease of the enhancement ratios, mean lifetimes of 16–20 days and of 8–9 days were calculated for measured C<sub>2</sub>H<sub>2</sub> and HCOOH. The respective lifetimes calculated from the model data are 18 and 12 days
The Outer Tracker Detector of the HERA-B Experiment Part I: Detector
The HERA-B Outer Tracker is a large system of planar drift chambers with
about 113000 read-out channels. Its inner part has been designed to be exposed
to a particle flux of up to 2.10^5 cm^-2 s^-1, thus coping with conditions
similar to those expected for future hadron collider experiments. 13
superlayers, each consisting of two individual chambers, have been assembled
and installed in the experiment. The stereo layers inside each chamber are
composed of honeycomb drift tube modules with 5 and 10 mm diameter cells.
Chamber aging is prevented by coating the cathode foils with thin layers of
copper and gold, together with a proper drift gas choice. Longitudinal wire
segmentation is used to limit the occupancy in the most irradiated detector
regions to about 20 %. The production of 978 modules was distributed among six
different laboratories and took 15 months. For all materials in the fiducial
region of the detector good compromises of stability versus thickness were
found. A closed-loop gas system supplies the Ar/CF4/CO2 gas mixture to all
chambers. The successful operation of the HERA-B Outer Tracker shows that a
large tracker can be efficiently built and safely operated under huge radiation
load at a hadron collider.Comment: 28 pages, 14 figure
The Outer Tracker Detector of the HERA-B Experiment. Part II: Front-End Electronics
The HERA-B Outer Tracker is a large detector with 112674 drift chamber
channels. It is exposed to a particle flux of up to 2x10^5/cm^2/s thus coping
with conditions similar to those expected for the LHC experiments. The
front-end readout system, based on the ASD-8 chip and a customized TDC chip, is
designed to fulfil the requirements on low noise, high sensitivity, rate
tolerance, and high integration density. The TDC system is based on an ASIC
which digitizes the time in bins of about 0.5 ns within a total of 256 bins.
The chip also comprises a pipeline to store data from 128 events which is
required for a deadtime-free trigger and data acquisition system. We report on
the development, installation, and commissioning of the front-end electronics,
including the grounding and noise suppression schemes, and discuss its
performance in the HERA-B experiment
Polar Stratospheric Clouds Satellite Observations, Processes, and Role in Ozone Depletion
Polar stratospheric clouds (PSCs) play important roles in stratospheric ozone depletion during winter and spring at high latitudes (e.g., the Antarctic ozone hole). PSC particles provide sites for heterogeneous reactions that convert stable chlorine reservoir species to radicals that destroy ozone catalytically. PSCs also prolong ozone depletion by delaying chlorine deactivation through the removal of gas-phase HNO and HO by sedimentation of large nitric acid trihydrate (NAT) and ice particles. Contemporary observations by the spaceborne instruments Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), Microwave Limb Sounder (MLS), and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) have provided an unprecedented polar vortex-wide climatological view of PSC occurrence and composition in both hemispheres. These data have spurred advances in our understanding of PSC formation and related dynamical processes, especially the firm evidence of widespread heterogeneous nucleation of both NAT and ice PSC particles, perhaps on nuclei of meteoritic origin. Heterogeneous chlorine activation appears to be well understood. Reaction coefficients on/in liquid droplets have been measured accurately, and while uncertainties remain for reactions on solid NAT and ice particles, they are considered relatively unimportant since under most conditions chlorine activation occurs on/in liquid droplets. There have been notable advances in the ability of chemical transport and chemistry-climate models to reproduce PSC temporal/spatial distributions and composition observed from space. Continued spaceborne PSC observations will facilitate further improvements in the representation of PSC processes in global models and enable more accurate projections of the evolution of polar ozone and the global ozone layer as climate changes
Ligands of the peripheral benzodiazepine receptor induce apoptosis and cell cycle arrest in oesophageal cancer cells: involvement of the p38MAPK signalling pathway
Corrigendum to "The Australian bushfires of February 2009: MIPAS observations and GEM-AQ model results" published in Atmos. Chem. Phys., 13, 1637–1658, 2013
No abstract available
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