Анализ конструкции и разработка технологии сборки рамы 3D принтера

Цель работы – разработка конструкторской документации, и непосредственная сборка 3D-принтер. В результате исследования изучена и доработана конструкция 3Д-пинтера послойного наплавления, разработана конструкторская документация, проведены изготовление и сборка рабочей модели. Основные конструктивные, технологические и технико-эксплуатационные характеристики: • Габариты изготавливаемых моделей 200х200х220; • Тип используемого пластика PLA или ABS; • Скорость печати до 110 мм/с. Степень внедрения: проводятся пуско-наладочные работы. Область применения: быстрое прототипирование малогабаритных деталей; обучение студентов созданию 3Д-моделей для 3Д-печати и развитие навыков работы с аддитивным оборудованием. В будущем планируется экспериментально отработать рабочие режимы 3Д-принтера.Objective - Development of design documentation, calculation accuracy of the collected parts and direct assembly of 3D-printer. The study examined and refined design 3D-Pinter layered fusing, design documentation, manufacture and assembly held a working model. The basic constructive, technological and technical and operational characteristics: • Dimensions of produced models 200х200х220; • The type of plastic PLA or ABS; • Print speed up 110 mm/s. Degree of implementation: carried out commissioning. Scope: rapid prototyping small parts; teaching students the creation of 3D models for 3D printing and the development of skills with additive hardware. In the future it is planned to work out experimentally operating modes 3D-printer

Патриотическое воспитание молодежи на примере малой Родины

В статье поднята важнейшая тема - патриотическое воспитание подрастающего поколения России. Этот вопрос особенно актуален сейчас, учитывая то, что в современном обществе произошла переоценка значимости жизненных ценностей: материальное благополучие стало основным, духовно-нравственное стало вторичным. Авторы анализируют сложившуюся ситуацию, приводят успешные примеры работы с молодежью на примере Юргинского района. В статье даны рекомендации по возрождению патриотического воспитания, как на местном уровне, так и на уровне государства

Молодежь и современные информационные технологии: сборник трудов XVI Международной научно-практической конференции студентов, аспирантов и молодых учёных, 3-7 декабря 2018 г., г. Томск

Сборник содержит доклады, представленные на XVI Международной научно-практической конференции студентов, аспирантов и молодых ученых «Молодежь и современные информационные технологии», прошедшей в Томском политехническом университете на базе Инженерной школы информационных технологий и робототехники. Материалы сборника отражают доклады студентов, аспирантов и молодых ученых, принятые к обсуждению на секциях: «Компьютерное моделирование и интеллектуальный анализ данных», «Автоматизация и управление в технических системах», «Робототехнические и мехатронные системы», «Цифровизация, IT и цифровая экономика», «Компьютерная графика и дизайн». Сборник предназначен для специалистов в области информационных технологий, студентов и аспирантов соответствующих специальностей

Research and Design of a Routing Protocol in Large-Scale Wireless Sensor Networks

无线传感器网络，作为全球未来十大技术之一，集成了传感器技术、嵌入式计算技术、分布式信息处理和自组织网技术，可实时感知、采集、处理、传输网络分布区域内的各种信息数据，在军事国防、生物医疗、环境监测、抢险救灾、防恐反恐、危险区域远程控制等领域具有十分广阔的应用前景。 本文研究分析了无线传感器网络的已有路由协议，并针对大规模的无线传感器网络设计了一种树状路由协议，它根据节点地址信息来形成路由，从而简化了复杂繁冗的路由表查找和维护，节省了不必要的开销，提高了路由效率，实现了快速有效的数据传输。 为支持此路由协议本文提出了一种自适应动态地址分配算——ADAR（AdaptiveDynamicAddre...As one of the ten high technologies in the future, wireless sensor network, which is the integration of micro-sensors, embedded computing, modern network and Ad Hoc technologies, can apperceive, collect, process and transmit various information data within the region. It can be used in military defense, biomedical, environmental monitoring, disaster relief, counter-terrorism, remote control of haz...学位：工学硕士院系专业：信息科学与技术学院通信工程系_通信与信息系统学号：2332007115216

Preparation and complex formation of lipophilic derivatives of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol

In dieser Arbeit wurden die Liganden 1,3,5-Tris{[(E)-(2-hydroxyphenyl)¬methyl¬iden]¬amino}-1,3,5-tridesoxy-cis-inosit (thici), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris(2-hydroxybenzyl)-1,3,5-cyclohexantriamin (thbca), 1,3,5-Tridesoxy-1,3,5-tris(2-hydroxybenzylamino)-cis-inosit (thci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris[(E)-2-hydroxybenzyliden]-1,3,5-cyclohexantriamin (thbci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris[(E)-(2-pyridylmethyliden)-1,3,5-cyclohexan-triamin (tpmci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris(2-pyridylmethyl)-1,3,5-cyclohexan-triamin (tpmca) und 1,3,5-Tridesoxy-1,3,5-tris(2-pyridylmethyl¬amino)-cis-inosit (pmaci) synthetisiert und ihr koordinationschemisches Verhalten durch Röntgenstrukturanalysen, Potentiometrie, mittels ein- und zweidimensionaler NMR-Spektroskopie sowie durch Cyclovoltammetrie untersucht. Der Co(tpmca)Cl3-Komplex spaltet im basischen Milieu sukzessive alle drei Pyridylmethylsubstituenten ab. Zwischenstufen dieser Reaktion sind hydrolyseempfindliche Iminkomplexe, die durch oxidative Dehydrogenierung entstehen. Kondensationsreaktionen der Co(taci)- und Ni(taci)-1:1-Komplexe mit Pyridin-2-carbaldehyd führten zur Bildung der Komplexe Co(pmenci)(pic) und Ni(pmenci)(pic), die durch Röntgenstrukturanalysen nachgewiesen wurden. Die pKS-Werte und die Stabilitätskonstanten der Kupferkomplexe des Liganden all-cis-2,4,6-Trimethylcyclohexan-1,3,5-triamin (tmeca) wurden mittels potentiometrischer und NMR-Titration bestimmt.New lipophilic ligands derived from 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol (taci), namely, 1,3,5-Trideoxy-1,3,5-tris(2-hydroxybenzylamino)-cis-inositol (thci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris(2-hydroxybenzyl)-1,3,5-cyclohexane-triamine (thbca), 1,3,5-Tris{[(E)-(2-hydroxyphenyl)¬methyl¬iden]¬amino}-1,3,5-trideoxy-cis-inositol (thici), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris[(E)-(2-pyridylmethyliden)-1,3,5-cyclohexane-triamine (tpmci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris[(E)-2-hydroxybenzyliden]-1,3,5-1,3,5-cyclohexane-triamine (thbci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris(2-pyridylmethyl)-1,3,5-cyclohexane-triamine (tpmca) und 1,3,5-Trideoxy-1,3,5-tris(2-pyridylmethyl¬amino)-cis-inositol (pmaci) have been synthesized. The conformation equilibrium of thbca was studied in solution and a strong dependence on pH and temperature was found. The complexing properties of the ligands towards Zn2+, Cd2+, Ga3+, Ni2+, Cu2+ and Co3+ have been investigated in solution and in solid state using NMR-spectroscopy, potentiometry, cyclic voltammetry and X-ray analysis. For the CoIII(tpmca)-complex, an oxidation of the ligand was observed in alkaline solution. Intramolecular condensation reactions between coordinated polyamino-polyalcohols and pyridine-2-carboxyaldehyde have been examined as part of a route to the synthesis of polydentate ligands and complexes. The pKA-values and the stability constants of all-cis-2,4,6-Trimethylcyclohexane-1,3,5-triamin (tmeca) with Cu2+ were measured with potentiometric and NMR-titration experiments

Preparation and complex formation of lipophilic derivatives of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol

In dieser Arbeit wurden die Liganden 1,3,5-Tris{[(E)-(2-hydroxyphenyl)¬methyl¬iden]¬amino}-1,3,5-tridesoxy-cis-inosit (thici), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris(2-hydroxybenzyl)-1,3,5-cyclohexantriamin (thbca), 1,3,5-Tridesoxy-1,3,5-tris(2-hydroxybenzylamino)-cis-inosit (thci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris[(E)-2-hydroxybenzyliden]-1,3,5-cyclohexantriamin (thbci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris[(E)-(2-pyridylmethyliden)-1,3,5-cyclohexan-triamin (tpmci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris(2-pyridylmethyl)-1,3,5-cyclohexan-triamin (tpmca) und 1,3,5-Tridesoxy-1,3,5-tris(2-pyridylmethyl¬amino)-cis-inosit (pmaci) synthetisiert und ihr koordinationschemisches Verhalten durch Röntgenstrukturanalysen, Potentiometrie, mittels ein- und zweidimensionaler NMR-Spektroskopie sowie durch Cyclovoltammetrie untersucht. Der Co(tpmca)Cl3-Komplex spaltet im basischen Milieu sukzessive alle drei Pyridylmethylsubstituenten ab. Zwischenstufen dieser Reaktion sind hydrolyseempfindliche Iminkomplexe, die durch oxidative Dehydrogenierung entstehen. Kondensationsreaktionen der Co(taci)- und Ni(taci)-1:1-Komplexe mit Pyridin-2-carbaldehyd führten zur Bildung der Komplexe Co(pmenci)(pic) und Ni(pmenci)(pic), die durch Röntgenstrukturanalysen nachgewiesen wurden. Die pKS-Werte und die Stabilitätskonstanten der Kupferkomplexe des Liganden all-cis-2,4,6-Trimethylcyclohexan-1,3,5-triamin (tmeca) wurden mittels potentiometrischer und NMR-Titration bestimmt.New lipophilic ligands derived from 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol (taci), namely, 1,3,5-Trideoxy-1,3,5-tris(2-hydroxybenzylamino)-cis-inositol (thci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris(2-hydroxybenzyl)-1,3,5-cyclohexane-triamine (thbca), 1,3,5-Tris{[(E)-(2-hydroxyphenyl)¬methyl¬iden]¬amino}-1,3,5-trideoxy-cis-inositol (thici), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris[(E)-(2-pyridylmethyliden)-1,3,5-cyclohexane-triamine (tpmci), all-cis-2,4,6-Trimethoxy-N1,N2,N3-tris[(E)-2-hydroxybenzyliden]-1,3,5-1,3,5-cyclohexane-triamine (thbci), all-cis-2,4,6-Trimethoxy-N1,N3,N5-tris(2-pyridylmethyl)-1,3,5-cyclohexane-triamine (tpmca) und 1,3,5-Trideoxy-1,3,5-tris(2-pyridylmethyl¬amino)-cis-inositol (pmaci) have been synthesized. The conformation equilibrium of thbca was studied in solution and a strong dependence on pH and temperature was found. The complexing properties of the ligands towards Zn2+, Cd2+, Ga3+, Ni2+, Cu2+ and Co3+ have been investigated in solution and in solid state using NMR-spectroscopy, potentiometry, cyclic voltammetry and X-ray analysis. For the CoIII(tpmca)-complex, an oxidation of the ligand was observed in alkaline solution. Intramolecular condensation reactions between coordinated polyamino-polyalcohols and pyridine-2-carboxyaldehyde have been examined as part of a route to the synthesis of polydentate ligands and complexes. The pKA-values and the stability constants of all-cis-2,4,6-Trimethylcyclohexane-1,3,5-triamin (tmeca) with Cu2+ were measured with potentiometric and NMR-titration experiments

Qualitative Profiling of Polyglucose Degradation Products in Peritoneal Dialysis Fluids

Heat sterilization of peritoneal dialysis (PD) fluids leads to partial degradation of the osmotic agent to form reactive carbonyl structures, which significantly reduce the biocompatibility of PD fluids and impair long-term PD therapy. Hence, it is important to know the exact composition of the degradation products to improve biocompatibility of PD fluids. Our study conducted targeted screening for degradation products in polyglucose (icodextrin)-containing PD fluids (pGDPs) by applying <i>o</i>-phenylenediamine (OPD) to form stable derivatives, which were analyzed by ultrahigh-performance liquid chromatography with hyphenated diode array tandem mass spectrometry (UHPLC–DAD–MS/MS). For the first time, specific degradation products of polyglucose, namely, 4-deoxyglucosone (4-DG) and 3,4-dideoxypentosone (3,4-DDPS), could be identified in PD fluids. Further, a reaction product of 5-hydroxymethylfurfural (5-HMF) and OPD could be characterized to be (5-(1<i>H</i>-benzo­[<i>d</i>]­imidazol-2-yl)­furan-2-yl)­methanol. Additionally, 3-deoxyglucosone (3-DG) and 3-deoxygalactosone (3-DGal), both known to be present in glucose-based PD fluids, were also detected in polyglucose-containing fluids. Trapping a hitherto unknown degradation product with OPD yielded 1,4-bis­(1<i>H</i>-benzo­[<i>d</i>]­imidazol-2-yl)-3,4-dihydroxybutan-1-one, which was present in heat- as well as filter-sterilized PD fluids