Experimental investigation on micromilling of oxygen-free, high-conductivity copper using tungsten carbide, chemistry vapour deposition and single-crystal diamond micro tools

Insufficient experimental data from various micro tools limit industrial application of the micromilling process. This paper presents an experimental comparative investigation into micromilling of oxygen-free, high-conductivity copper using tungsten carbide (WC), chemistry vapour deposition (CVD) diamond, and single-crystal diamond micromilling tools at a uniform 0.4mm diameter. The experiments were carried out on an ultra-precision micromilling machine that features high dynamic accurate performance, so that the dynamic effect of the machine tool itself on the cutting process can be reduced to a minimum. Micromachined surface roughness and burr height were characterized using white light interferometry, a scanning electron microscope (SEM), and a precision surface profiler. The influence of variation of cutting parameters, including cutting speeds, feedrate, and axial depth of cut, on surface roughness and burr formation were analysed. The experimental results show that there exists an optimum feedrate at which best surface roughness can be achieved. Optical quality surface roughness can be achieved with CVD and natural diamond tools by carefully selecting machining conditions, and surface roughness, Ra, of the order of 10nm can also be obtained when using micromilling using WC tools on the precision micromilling machine.EU FP6 MASMICRO projec

Iterative Linearized Density Matrix Propagation for Modeling Coherent Energy Transfer in Photosynthetic Light Harvesting

We present results of calculations [1] that employ a new mixed quantum classical iterative density matrix propagation approach (ILDM , or so called Is‐Landmap) [2] to explore the survival of coherence in different photo synthetic models. Our model studies confirm the long lived quantum coherence , while conventional theoretical tools (such as Redfield equation) fail to describe these phenomenon [3,4]. Our ILDM method is a numerical exactly propagation scheme and can be served as a bench mark calculation tools[2]. Result get from ILDM and from other recent methods have been compared and show agreement with each other[4,5]. Long lived coherence plateau has been attribute to the shift of harmonic potential due to the system bath interaction, and the harvesting efficiency is a balance between the coherence and dissipation[1]. We use this approach to investigate the excitation energy transfer dynamics in various light harvesting complex include Fenna‐Matthews‐Olsen light harvesting complex[1] and Cryptophyte Phycocyanin 645 [6]. [1] P.Huo and D.F.Coker ,J. Chem. Phys. 133, 184108 (2010) . [2] E.R. Dunkel, S. Bonella, and D.F. Coker, J. Chem. Phys. 129, 114106 (2008). [3] A. Ishizaki and G.R. Fleming, J. Chem. Phys. 130, 234111 (2009). [4] A. Ishizaki and G.R. Fleming, Proc. Natl. Acad. Sci. 106, 17255 (2009). [5] G. Tao and W.H. Miller, J. Phys. Chem. Lett. 1, 891 (2010). [6] P.Huo and D.F.Coker in preparationNational Science Foundation (CHE-0911635

An investigation of nanoindentation tests on the single crystal copper thin film via an AFM and MD simulation

Nanoindentation tests performed in an atomic force microscope have been utilized to directly measure the mechanical properties of single crystal metal thin films fabricated by the vacuum vapor deposition technique. Nanoindentation tests were conducted at various indentation depths to study the effect of indentation depths on the mechanical properties of thin films. The results were interpreted by using the Oliver-Pharr method with which direct observation and measurement of the contact area are not required. The elastic modulus of the single crystal copper film at various indentation depths was determined as 67.0±6.9GPa on average which is in reasonable agreement with the results reported by others. The indentation hardness constantly increases with decreasing indentation depth, indicating a strong size effect. In addition to the experimental work, a three-dimensional nanoindentation model of molecular dynamics (MD) simulations with embedded atom method (EAM) potential is proposed to elucidate the mechanics and mechanisms of nanoindentation of thin films from the atomistic point of view. MD simulations results also show that due to the size effect the plastic deformation via amorphous transformation is more favorable than via the generation and propagation of dislocations in nanoindentation of single crystal copper thin films

Boiling two-phase pressure drop in small diameter tubes

An experimental study of two-phase pressure drop in small diameter tubes is described in this paper. Stainless steel tubes of internal diameter and length of 4.26 mm, 500 mm and 2.01 mm, 211 mm were used. The working fluid was R134a and the range covered was: mass flux 100 – 500 kg/m2s; system pressure 8-14 bar and exit quality up to 0.9. The heat flux applied to the tubes ranged from 13 – 150 kW/m2. The effect of diameter on pressure drop is discussed in this paper and a detailed presentation of the results of the comparison with existing pressure drop correlations, some particularly developed for small tubes, is given

Sorting and separation of microparticles by surface properties using liquid crystal-enabled electro-osmosis

Sorting and separation of microparticles is a challenging problem of interdisciplinary nature. Existing technologies can differentiate microparticles by their bulk properties, such as size, density, electric polarizability, etc. The next level of challenge is to separate particles that show identical bulk properties and differ only in subtle surface features, such as functionalization with ligands. In this work, we propose a technique to sort and separate particles and fluid droplets that differ in surface properties. As a dispersive medium, we use a nematic liquid crystal (LC) rather than an isotropic fluid, which allows us to amplify the difference in surface properties through distinct perturbations of LC order around the dispersed particles. The particles are placed in a LC cell with spatially distorted molecular orientation subject to an alternating current electric field. The gradients of the molecular orientation perform two functions. First, elastic interactions between these pre-imposed gradients and distortions around the particles separate the particles with different surface properties in space. Second, these pre-imposed patterns create electro-osmotic flows powered by the electric field that transport the sorted particles to different locations thus separating them. The demonstrated unique sorting and separation capability opens opportunities in lab-on-a-chip, cell sorting and bio-sensing applications

Phonon-Assisted Two-Photon Interference from Remote Quantum Emitters

Photonic quantum technologies are on the verge offinding applications in everyday life with quantum cryptography andquantum simulators on the horizon. Extensive research has beencarried out to identify suitable quantum emitters and single epitaxialquantum dots have emerged as near-optimal sources of bright, on-demand, highly indistinguishable single photons and entangledphoton-pairs. In order to build up quantum networks, it is essentialto interface remote quantum emitters. However, this is still anoutstanding challenge, as the quantum states of dissimilar“artificialatoms”have to be prepared on-demand with highfidelity and thegenerated photons have to be made indistinguishable in all possibledegrees of freedom. Here, we overcome this major obstacle and show an unprecedented two-photon interference (visibility of 51±5%) from remote strain-tunable GaAs quantum dots emitting on-demand photon-pairs. We achieve this result by exploiting forthefirst time the full potential of a novel phonon-assisted two-photon excitation scheme, which allows for the generation ofhighly indistinguishable (visibility of 71±9%) entangled photon-pairs (fidelity of 90±2%), enables push-button biexciton statepreparation (fidelity of 80±2%) and outperforms conventional resonant two-photon excitation schemes in terms of robustnessagainst environmental decoherence. Our results mark an important milestone for the practical realization of quantum repeatersand complex multiphoton entanglement experiments involving dissimilar artificial atom

(2+1) resonant enhanced multiphoton ionization of H_2 via the E, F^(1)Σ^+_g state

In this paper, we report the results of ab initio calculations of photoelectron angular distributions and vibrational branching ratios for the (2+1) REMPI of H_2 via the E, F^(1)Σ^+_g state, and compare these with the experimental data of Anderson et al. [Chem. Phys. Lett. 105, 22 (1984)]. These results show that the observed non‐Franck–Condon behavior is predominantly due to the R dependence of the transition matrix elements, and to a lesser degree to the energy dependence. This work presents the first molecular REMPI study employing a correlated wave function to describe the Rydberg–valence mixing in the resonant intermediate state