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An aerial vehicle rotating in gyroscopic fashion about one of its axes has an optical system which scans an area below the vehicle in determined relation to vehicle rotation. A sensing device is provided to sense the physical condition of the area of scan and optical means are associated to direct the physical intelligence received from the scan area to the sensing means. Means are provided to incrementally move the optical means through a series of steps to effect sequential line scan of the area being viewed keyed to the rotational rate of the vehicle

O stars effective temperature and HII regions ionization parameter gradients in the Galaxy

Extensive photoionization model grids are computed for single star HII regions using stellar atmosphere models from the WM-basic code. Mid-IR emission line intensities are predicted and diagnostic diagrams of [NeIII]/[NeII] and [SIV]/[SIII] excitation ratio are build, taking into account the metallicities of both the star and the HII region. The diagrams are used in conjunction with galactic HII region observations obtained with the ISO Observatory to determine the effective temperature Teff of the exciting O stars and the mean ionization parameter U. Teff and U are found to increase and decrease, respectively, with the metallicity of the HII region represented by the [Ne/Ne_sol] ratio. No evidence is found for gradients of Teff or U with galactocentric distance Rgal. The observed excitation sequence with Rgal is mainly due to the effect of the metallicity gradient on the spectral ionizing shape, upon which the effect of an increase in Teff with Z is superimposed. We show that not taking properly into account the effect of metallicity on the ionizing shape of the stellar atmosphere would lead to an apparent decrease of Teff with Z and an increase of Teff with Rgal.Comment: Accepted in Ap

Density-Dependent Analysis of Nonequilibrium Paths Improves Free Energy Estimates II. A Feynman-Kac Formalism

The nonequilibrium fluctuation theorems have paved the way for estimating equilibrium thermodynamic properties, such as free energy differences, using trajectories from driven nonequilibrium processes. While many statistical estimators may be derived from these identities, some are more efficient than others. It has recently been suggested that trajectories sampled using a particular time-dependent protocol for perturbing the Hamiltonian may be analyzed with another one. Choosing an analysis protocol based on the nonequilibrium density was empirically demonstrated to reduce the variance and bias of free energy estimates. Here, we present an alternate mathematical formalism for protocol postprocessing based on the Feynmac-Kac theorem. The estimator that results from this formalism is demonstrated on a few low-dimensional model systems. It is found to have reduced bias compared to both the standard form of Jarzynski's equality and the previous protocol postprocessing formalism.Comment: 21 pages, 5 figure

Registration of Heat Capacity Mapping Mission day and night images

Neither iterative registration, using drainage intersection maps for control, nor cross correlation techniques were satisfactory in registering day and night HCMM imagery. A procedure was developed which registers the image pairs by selecting control points and mapping the night thermal image to the daytime thermal and reflectance images using an affine transformation on a 1300 by 1100 pixel image. The resulting image registration is accurate to better than two pixels (RMS) and does not exhibit the significant misregistration that was noted in the temperature-difference and thermal-inertia products supplied by NASA. The affine transformation was determined using simple matrix arithmetic, a step that can be performed rapidly on a minicomputer

Scattered Lyman-alpha Radiation Around Sources Before Cosmological Reionization

The spectra of the first galaxies and quasars in the Universe should be strongly absorbed shortward of their rest-frame Lyman-alpha wavelength by neutral hydrogen (HI) in the intervening intergalactic medium. However, the Lyman-alpha line photons emitted by these sources are not eliminated but rather scatter until they redshift out of resonance and escape due to the Hubble expansion of the surrounding intergalactic HI. We calculate the resulting brightness distribution and the spectral shape of the diffuse Lyman-alpha line emission around high redshift sources, before the intergalactic medium was reionized. Typically, the Lyman-alpha photons emitted by a source at z=10 scatter over a characteristic angular radius of order 15 arcseconds around the source and compose a line which is broadened and redshifted by about a thousand km/s relative to the source. The scattered photons are highly polarized. Detection of the diffuse Lyman-alpha halos around high redshift sources would provide a unique tool for probing the neutral intergalactic medium before the epoch of reionization. On sufficiently large scales where the Hubble flow is smooth and the gas is neutral, the Lyman-alpha brightness distribution can be used to determine the cosmological mass densities of baryons and matter.Comment: 21 pages, 5 Postscript figures, accepted by ApJ; figures 1--3 corrected; new section added on the detectability of Lyman alpha halos; conclusions update

Photoionization cross sections of O II, O III, O IV, and O V: benchmarking R-matrix theory and experiments

For crucial tests between theory and experiment, ab initio close coupling calculations are carried out for photoionization of O II, O III, O IV, O V. The relativistic fine structure and resonance effects are studied using the R-matrix and its relativistic variant the Breit Pauli R-matrix (BPRM) approximation. Detailed comparison is made with high resolution experimental measurements carried out in three different set-ups: Advanced Light Source at Berkeley, and synchrotron radiation experiments at University of Aarhus and University of Paris-Sud. The comparisons illustrate physical effects in photoionization such as (i) fine structure, (ii) resolution, and (iii) metastable components. Photoionization cross sections sigma{PI} of the ground and a few low lying excited states of these ions obtained in the experimental spectrum include combined features of these states. Theoretically calculated resonances need to be resolved with extremely fine energy mesh for precise comparison. In addition, prominent resonant features are observed in the measured spectra from transitions allowed with relativistic fine structure, but not in LS coupling. The sigma_{PI} are obtained for ground and metastable (i) 2s^22p^3(^4S^o, ^2D^o, ^2P^o) states of O II, (ii) 2s^22p^2(^3P,^1D,^1S) and 2s2p^3(^5S^o) states of O III, (iii) 2s^22p(^2P^o_J) and 2s2p^2(^4P_J) levels of O IV, and (iv) 2s^2(^1S) and 2s2p(^3P^o,^1P^o) states of O V. It is found that resonances in ground and metastable cross sections can be a diagnostic of experimental beam composition, with potential ap plications to astrophysical and laboratory plasma environments.Comment: 27 pages, 7 figs., submitted to Phys. Rev. A., text with high resolution figures at http://www.astronomy.ohio-state.edu/~pradhan/Oions.p

The hydration state of HO−^-(aq)

The HO$^-$(aq) ion participates in myriad aqueous phase chemical processes of biological and chemical interest. A molecularly valid description of its hydration state, currently poorly understood, is a natural prerequisite to modeling chemical transformations involving HO$^-$(aq). Here it is shown that the statistical mechanical quasi-chemical theory of solutions predicts that $\mathrm{HO\cdot[H_2O]_3{}^-}$ is the dominant inner shell coordination structure for HO$^-$(aq) under standard conditions. Experimental observations and other theoretical calculations are adduced to support this conclusion. Hydration free energies of neutral combinations of simple cations with HO$^-$(aq) are evaluated and agree well with experimental values.Comment: 10 pages, 1 figur