Determination of water content using mass spectrometry

Mass spectrometer is used to measure small quantities of water present in different materials. System has been applied in measuring water and gases desorbed from microcircuitry insulation, can also be used with foods, polymeric materials, and organic solvents

Dynamic delta method for trace gas analysis

Method has been developed in which measurements are made only over viscous flow range, eliminating fractionation before the molecular leak and problems due to surface elution

Orbital Deflection of Comets by Directed Energy

Cometary impacts pose a long-term hazard to life on Earth. Impact mitigation techniques have been studied extensively, but they tend to focus on asteroid diversion. Typical asteroid interdiction schemes involve spacecraft physically intercepting the target, a task feasible only for targets identified decades in advance and in a narrow range of orbits---criteria unlikely to be satisfied by a threatening comet. Comets, however, are naturally perturbed from purely gravitational trajectories through solar heating of their surfaces which activates sublimation-driven jets. Artificial heating of a comet, such as by a laser, may supplement natural heating by the Sun to purposefully manipulate its path and thereby avoid an impact. Deflection effectiveness depends on the comet's heating response, which varies dramatically depending on factors including nucleus size, orbit and dynamical history. These factors are incorporated into a numerical orbital model to assess the effectiveness and feasibility of using high-powered laser arrays in Earth orbit and on the ground for comet deflection. Simulation results suggest that a diffraction-limited 500 m orbital or terrestrial laser array operating at 10 GW for 1% of each day over 1 yr is sufficient to fully avert the impact of a typical 500 m diameter comet with primary nongravitational parameter A1 = 2 x 10^-8 au d^-2. Strategies to avoid comet fragmentation during deflection are also discussed.Comment: 13 pages, 12 figures; AJ, in pres

Non-invasive imaging of subsurface paint layers with optical coherence tomography

Optical coherence tomography (OCT) systems are fast scanning infrared Michelson interferometers designed for the non-invasive examination of the interiors of the eye and subsurface structures of biological tissues. OCT has recently been applied to the non-invasive examinations of the stratigraphy of paintings and museum artefacts. So far this is the only technique capable of imaging non-invasively the subsurface structure of paintings and painted objects. Unlike the traditional method of paint cross-section examination where sampling is required, the non-invasive and non-contact nature of the technique enables the examination of the paint cross-section anywhere on a painting, as there is no longer an issue with conservation ethics regarding the taking of samples from historical artefacts. A range of applications of the technique including the imaging of stratigraphy of paintings and painted artefacts, the imaging of underdrawings to the analysis of the optical properties of paint and varnish layers is presented. Future projects on the application of OCT to art conservation are discussed

Log-periodic modulation in one-dimensional random walks

We have studied the diffusion of a single particle on a one-dimensional lattice. It is shown that, for a self-similar distribution of hopping rates, the time dependence of the mean-square displacement follows an anomalous power law modulated by logarithmic periodic oscillations. The origin of this modulation is traced to the dependence on the length of the diffusion coefficient. Both the random walk exponent and the period of the modulation are analytically calculated and confirmed by Monte Carlo simulations.Comment: 6 pages, 7 figure

Manufacture of DPFC-DMS polymer in the SKG range

BPFC-DMS block copolymers were synthesized on a pre-pilot scale (i.e., to 5 Kg lots) and subsequently fabricated into clear, colorless films. Details of the synthesis procedures, property determinations, and film casting techniques are presented. Solubility, viscosity and molecular weight characteristics of the resulting product are reported

Flammability screening tests of resins

Selected flammability characteristics of glass cloth laminates of thermosetting resins are evaluated. A protocol for the evaluation of the flammability hazards presented by glass cloth laminates of thermosetting resins and the usefulness of that protocol with two laminates are presented. The glass laminates of an epoxy resin, M-751 are evaluated for: (1) determination of smoke generation from the laminates; (2) analysis of products of oxidative degradation of the laminates; (3) determination of minimum oxygen necessary to maintain flaming oxidation; (4) evaluation of toxicological hazards

Carrier dynamics in ion-implanted GaAs studied by simulation and observation of terahertz emission

We have studied terahertz (THz) emission from arsenic-ion implanted GaAs both experimentally and using a three-dimensional carrier dynamics simulation. A uniform density of vacancies was formed over the optical absorption depth of bulk GaAs samples by performing multi-energy implantations of arsenic ions (1 and 2.4MeV) and subsequent thermal annealing. In a series of THz emission experiments the frequency of peak THz power was found to increase significantly from 1.4 to 2.2THz when the ion implantation dose was increased from 10^13 to 10^16 cm-3. We used a semi-classical Monte-Carlo simulation of ultra-fast carrier dynamics to reproduce and explain these results. The effect of the ion-induced damage was included in the simulation by considering carrier scattering at neutral and charged impurities, as well as carrier trapping at defect sites. Higher vacancy concentrations and shorter carrier trapping times both contributed to shorter simulated THz pulses, the latter being more important over experimentally realistic parameter ranges.Comment: 6 pages, 7 figure

ALMA observations of the debris disk around the young Solar Analog HD 107146

We present ALMA continuum observations at a wavelength of 1.25 mm of the debris disk surrounding the $\sim$ 100 Myr old solar analog HD 107146. The continuum emission extends from about 30 to 150 AU from the central star with a decrease in the surface brightness at intermediate radii. We analyze the ALMA interferometric visibilities using debris disk models with radial profiles for the dust surface density parametrized as i) a single power-law, ii) a single power-law with a gap, and iii) a double power-law. We find that models with a gap of radial width $\sim 8$ AU at a distance of $\sim 80$ AU from the central star, as well as double power-law models with a dip in the dust surface density at $\sim 70$ AU provide significantly better fits to the ALMA data than single power-law models. We discuss possible scenarios for the origin of the HD 107146 debris disk using models of planetesimal belts in which the formation of Pluto-sized objects trigger disruptive collisions of large bodies, as well as models which consider the interaction of a planetary system with a planetesimal belt and spatial variation of the dust opacity across the disk. If future observations with higher angular resolution and sensitivity confirm the fully-depleted gap structure discussed here, a planet with a mass of approximately a few Earth masses in a nearly circular orbit at $\sim 80$ AU from the central star would be a possible explanation for the presence of the gap.Comment: (38 pages, 7 figures, accepted for publication in ApJ