A novel route to phase formation of cobalt oxyhydrates using KMnO4 as an oxidizing agent

We have first succeefully synthesized the sodium cobalt oxyhydrate superconductors using KMnO4 as a de-intercalating and oxidizing agent. It is a novel route to form the superconductive phase of NaxCoO2.yH2O without resorting to the commonly used Br2/CH3CN solution. The role of the KMnO4 is to de-intercalate the Na+ from the parent compound Na0.7CoO2 and oxidize the Co ion as a result. The higher molar ratio of KMnO4 relative to the sodium content tends to remove more Na+ from the parent compound and results in a slight expansion of the c-axis in the unit cell. The superconducting transition temperature is 4.6-3.8 K for samples treated by the aqueous KMnO4 solution with the molar ratio of KMnO4 relative to the sodium content in the range of 0.3 and 2.29.Comment: 10 pages, 3 figure

Dielectrophoresis of charged colloidal suspensions

We present a theoretical study of dielectrophoretic (DEP) crossover spectrum of two polarizable particles under the action of a nonuniform AC electric field. For two approaching particles, the mutual polarization interaction yields a change in their respective dipole moments, and hence, in the DEP crossover spectrum. The induced polarization effects are captured by the multiple image method. Using spectral representation theory, an analytic expression for the DEP force is derived. We find that the mutual polarization effects can change the crossover frequency at which the DEP force changes sign. The results are found to be in agreement with recent experimental observation and as they go beyond the standard theory, they help to clarify the important question of the underlying polarization mechanisms

Preparation of atomically clean and flat Si(100) surfaces by low-energy ion sputtering and low-temperature annealing

Si(100) surfaces were prepared by wet-chemical etching followed by 0.3-1.5keV Ar ion sputtering, either at elevated or room temperature. After a brief anneal under ultrahigh vacuum conditions, the resulting surfaces were examined by scanning tunneling microscopy. We find that wet-chemical etching alone cannot produce a clean and flat Si(100) surface. However, subsequent 300eV Ar ion sputtering at room temperature followed by a 973K anneal yields atomically clean and flat Si(100) surfaces suitable for nanoscale device fabrication.Comment: 13 pages, 3 figures, to be published in Applied Surface Scienc

A web-based system for statistical shape analysis in temporomandibular joint osteoarthritis

This study presents a web-system repository: Data Storage for Computation and Integration (DSCI) for Osteoarthritis of the temporomandibular joint (TMJ OA). This environment aims to maintain and allow contributions to the database from multi-clinical centers and compute novel statistics for disease classification. For this purpose, imaging datasets stored in the DSCI consisted of three-dimensional (3D) surface meshes of condyles from CBCT, clinical markers and biological markers in healthy and TMJ OA subjects. A clusterpost package was included in the web platform to be able to execute the jobs in remote computing grids. The DSCI application allowed runs of statistical packages, such as the Multivariate Functional Shape Data Analysis to compute global correlations between covariates and the morphological variability, as well as local p-values in the 3D condylar morphology. In conclusion, the DSCI allows interactive advanced statistical tools for non-statistical experts

SU(5) Unified Theories from Intersecting Branes

We discuss the first string theory examples of three generation non-supersymmetric SU(5) and {\em flipped} SU(5) GUTS, which break to the Standard model at low energy, without extra matter and/or gauge group factors. Our GUT examples are based on IIA $Z_3$ orientifolds with D6-branes intersecting at non-trivial angles. These theories necessarily satisfy RR tadpoles and are free of NSNS tadpoles as the complex structure moduli are frozen (even though a dilaton tadpole remains) to discrete values. We identify appropriately the bifundamental Higgses responsible for electroweak symmetry breaking. In this way, the neutrino see-saw mechanism get nicely realized in these constructions. Moreover, as baryon number is not a gauged symmetry gauge mediated dimension six operators do contribute to proton decay; however proton lifetime may be safely enhanced by appropriately choosing a high GUT scale. An accompanying natural doublet-triplet splitting guarantees the suppression of scalar mediated proton decay modes and the stability of triplet scalar masses against higher dimensional non-renormalizable operators.Comment: 26 pages, 5 figures; no changes, one comment added in the introductio

Metric Properties of the Fuzzy Sphere

The fuzzy sphere, as a quantum metric space, carries a sequence of metrics which we describe in detail. We show that the Bloch coherent states, with these spectral distances, form a sequence of metric spaces that converge to the round sphere in the high-spin limit.Comment: Slightly shortened version, no major changes, two new references, version to appear on Letters in Mathematical Physic

Hexatic-Herringbone Coupling at the Hexatic Transition in Smectic Liquid Crystals: 4-ϵ\epsilon Renormalization Group Calculations Revisited

Simple symmetry considerations would suggest that the transition from the smectic-A phase to the long-range bond orientationally ordered hexatic smectic-B phase should belong to the XY universality class. However, a number of experimental studies have constantly reported over the past twenty years "novel" critical behavior with non-XY critical exponents for this transition. Bruinsma and Aeppli argued in Physical Review Letters {\bf 48}, 1625 (1982), using a $4-\epsilon$ renormalization-group calculation, that short-range molecular herringbone correlations coupled to the hexatic ordering drive this transition first order via thermal fluctuations, and that the critical behavior observed in real systems is controlled by a `nearby' tricritical point. We have revisited the model of Bruinsma and Aeppli and present here the results of our study. We have found two nontrivial strongly-coupled herringbone-hexatic fixed points apparently missed by those authors. Yet, those two new nontrivial fixed-points are unstable, and we obtain the same final conclusion as the one reached by Bruinsma and Aeppli, namely that of a fluctuation-driven first order transition. We also discuss the effect of local two-fold distortion of the bond order as a possible missing order parameter in the Hamiltonian.Comment: 1 B/W eps figure included. Submitted to Physical Review E. Contact: [email protected]

GaN and InN nanowires grown by MBE: a comparison

Morphological, optical and transport properties of GaN and InN nanowires grown by molecular beam epitaxy (MBE) have been studied. The differences between the two materials in respect to growth parameters and optimization procedure was stressed. The nanowires crystalline quality has been investigated by means of their optical properties. A comparison of the transport characteristics was given. For each material a band schema was shown, which takes into account transport and optical features and is based on Fermi level pinning at the surface.Comment: 5 pages, 5 figure