Raman measurements of dye-laser-annealed, ion implanted GaAs

Call number: LD2668 .T4 1986 Y36Master of SciencePhysic

Spectroscopic ellipsometry studies of HF treated Si (100) surfaces

Both ex situ and in situ spectroscopic ellipsometry (SE) measurements were employed to investigate the effects of HF cleaning on Si surfaces. The hydrogen-terminated (H-terminated) Si surface was modeled as an equivalent dielectric layer, and monitored in real time by SE measurements. The SE analyses indicate that after a 20-s 9:1 HF dip without rinse, the Si(100) surface was passivated by the hydrogen termination and remained chemically stable. Roughness of the HF-etched bare Si(100) surface was observed, in an ultrahigh vacuum (UHV) chamber, and analyzed by the in situ SE. Evidence for desorption of the H-terminated Si surface-layer, after being heated to approximately 550 C in the UHV chamber, is presented and discussed. This is the first use of an ex situ and in situ real-time, nondestructive technique capable of showing state of passivation, the rate of reoxidation, and the surface roughness of the H-terminated Si surfaces

Temperature dependence of optical properties of GaAs

Pseudodielectric functions (ε) = (ε1) + i (ε2) of GaAs were measured by spectroscopic ellipsometry (SE), in the range of 1.W.45 eV, at temperatures from room temperature (RT) to ~610 ° C. A very clean, smooth surface was obtained by first growing an epitaxial layer of GaAs on a GaAs substrate and immediately capping it with a protective layer of arsenic. The cap prevented surface oxidation during transport to the measurement chamber, where it was evaporated under ultrahigh vacuum at ~350 °C. Room-temperature SE results from this surface are in good agreement with those in the literature obtained by wet-chemical etching. A quantitative analysis of the (ε) spectrum was made using the harmonic-oscillator approximation (HOA). It is shown by the HOA that the E1 and E1 + Δ1 energy-band critical points shift downward ~300 meV as temperature increases from RT to ~610 °C. An algorithm was developed, using the measured optical constants at a number of fixed temperatures, to compute the dielectric function spectrum at an arbitrary temperature in the range of 22-610 °C. Therefore, the ellipsometer can be utilized as an optical thermometer to determine the sample surface temperature

Laser Joining of Continuous Glass Fiber Composite Pre-forms

A laser fusion joining method is investigated for the purpose of through thickness strengthening of fiber pre-forms used in the vacuum infusion fabrication of thick composite structures. Laser joining is achieved without filler materials to replace adhesives, pins or stitches used in conventional composite fabrication. A two step joining process is developed to fuse fibers within a single bundle and between multiple fiber bundles. Finite element analysis is used to investigate the joint strength with respect to joint morphology. Joint strength is found to be a function of the fiber contact angle and packing density at the joint interface. Tensile tests show that laser joined fiber bundles exhibit higher strength than comparable fastening methods. Lessons learned from the axial joining of fiber bundles are applied to joining in the radial and thickness directions of 3d pre-form architectures. Flow induced joint morphology and densification effects observed in the axial direction indicate the need for a two step joining process in the thickness direction. Fiber compaction effects on joint strength in the axial direction motivate the need for high fiber packing fraction at joint interfaces in the thickness direction

Optical constants of Ga\u3csub\u3e\u3ci\u3ex\u3c/i\u3e\u3c/sub\u3eIn\u3csub\u3e1-\u3ci\u3ex\u3c/i\u3e\u3c/sub\u3eP lattice matched to GaAs

The optical constants of Ga0.51In0.49P have been determined from 0.8 to 5.0 eV using variable-angle spectroscopic ellipsometry measurements at room temperature. The metal-organic vapor-phase-epitaxy-grown samples were x-ray analyzed to confirm lattice matching to the GaAs substrate. The effects of the native oxide were numerically removed from the data to determine the intrinsic optical constants. This is important because the optical constants reported become generally useful for modeling multiple-layer structures. A Kramers-Kronig analysis was used to reduce interference-related fluctuations in the below-gap refractive index. Near the band edge a mathematical form for excitonic absorption was included. Critical point energies were extracted using a numerical second-derivative fitting algorithm

Allee effects in marine systems

The fitness or population growth rate of populations with Allee effects increases with increasing population size or density up to a certain threshold. Allee effects are possible in marine populations, as they are less open than has been assumed and may have a metapopulation structure. We modelled the population consequences of Allee effects and show that increases in mortality interact with critical Allee thresholds, such that an Allee effect with no population consequences at low mortality can drive a population to extinction when mortality is increased. In heavily fished species, populations with strong Allee effects go extinct at lower levels of fishing mortality, or conversely as fishing mortality increases, weaker Allee effects can drive population to extinction. We found little empirical evidence in the literature for widespread Allee effects in marine populations, although we found some suggestive observations, particularly for broadcast spawners and in exploited populations This might be due to methodological problems or long time lags. Many marine species have components of their life history or ecology which could in theory generate Allee effects; however the population level consequences of these potential mechanisms remains virtually unexplored. We suggest that including Allee effects in models of vulnerable populations may be critical for the precautionary management of exploited and threatened marine species