34,621 research outputs found
Internal coating of air-cooled gas turbine blades
Four modified aluminide coatings were developed for IN-792 + Hf alloy using a powder pack method applicable to internal surfaces of air-cooled blades. The coating compositions are Ni-19Al-1Cb, Ni-19Al-3Cb, Ni-17Al-20Cr, and Ni-12Al-20Cr. Cyclic burner rig hot corrosion (900 C) and oxidation (1050 C) tests indicated that Ni-Al-Cb coatings provided better overall resistance than Ni-Al-Cr coatings. Tensile properties of Ni-19Al-1Cb and Ni-12Al-20Cr coated test bars were fully retained at room temperature and 649 C. Stress rupture results exhibited wide scatter around uncoated IN-792 baseline, especially at high stress levels. High cycle fatigue lives of Ni-19Al-1Cb and Ni-12Al-20Cr coated bars (as well as RT-22B coated IN-792) suffered approximately 30 percent decrease at 649 C. Since all test bars were fully heat treated after coating, the effects of coating/processing on IN-792 alloy were not recoverable. Internally coated Ni-19Al-1Cb, Ni-19Al-3Cb, and Ni-12Al-20Cr blades were included in 500-hour endurance engine test and the results were similar to those obtained in burner rig oxidation testing
Polyvinyl alcohol cross-linked with two aldehydes
A film forming polyvinyl alcohol resin is admixed, in aqueous solution, with a dialdehyde crosslinking agent which is capable of crosslinking the polyvinyl alcohol resin and a water soluble acid aldehyde containing a reactive aldehyde group capable of reacting with hydroxyl groups in the polyvinyl alcohol resin and an ionizable acid hydrogen atom. The dialdehyde is present in an amount sufficient to react with from 1 to 20% by weight of the theoretical amount required to react with all of the hydroxyl groups of the polyvinyl alcohol. The amount of acid aldehyde is from 1 to 50% by weight, same basis, and is sufficient to reduce the pH of the aqueous admixture to 5 or less. The admixture is then formed into a desired physical shape, such as by casting a sheet or film, and the shaped material is then heated to simultaneously dry and crosslink the article
Internally coated air-cooled gas turbine blading
Ten candidate modified nickel-aluminide coatings were developed using the slip pack process. These coatings contain additives such as silicon, chromium and columbium in a nickel-aluminum coating matrix with directionally solidified MAR-M200 + Hf as the substrate alloy. Following a series of screening tests which included strain tolerance, dynamic oxidation and hot corrosion testing, the Ni-19A1-1Cb (nominal composition) coating was selected for application to the internal passages of four first-stage turbine blades. Process development results indicate that a dry pack process is suitable for internal coating application resulting in 18 percent or less reduction in air flow. Coating uniformity, based on coated air-cooled blades, was within + or - 20 percent. Test results show that the presence of additives (silicon, chromium or columbium) appeared to improve significantly the ductility of the NiA1 matrix. However, the environmental resistance of these modified nickel-aluminides were generally inferior to the simple aluminides
Approximating random quantum optimization problems
We report a cluster of results regarding the difficulty of finding
approximate ground states to typical instances of the quantum satisfiability
problem -QSAT on large random graphs. As an approximation strategy, we
optimize the solution space over `classical' product states, which in turn
introduces a novel autonomous classical optimization problem, PSAT, over a
space of continuous degrees of freedom rather than discrete bits. Our central
results are: (i) The derivation of a set of bounds and approximations in
various limits of the problem, several of which we believe may be amenable to a
rigorous treatment. (ii) A demonstration that an approximation based on a
greedy algorithm borrowed from the study of frustrated magnetism performs well
over a wide range in parameter space, and its performance reflects structure of
the solution space of random -QSAT. Simulated annealing exhibits
metastability in similar `hard' regions of parameter space. (iii) A
generalization of belief propagation algorithms introduced for classical
problems to the case of continuous spins. This yields both approximate
solutions, as well as insights into the free energy `landscape' of the
approximation problem, including a so-called dynamical transition near the
satisfiability threshold. Taken together, these results allow us to elucidate
the phase diagram of random -QSAT in a two-dimensional
energy-density--clause-density space.Comment: 14 pages, 9 figure
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How well do CMIP5 climate simulations replicate historical trends and patterns of meteorological droughts?
Assessing the uncertainties and understanding the deficiencies of climate models are fundamental to developing adaptation strategies. The objective of this study is to understand how well Coupled Model Intercomparison-Phase 5 (CMIP5) climate model simulations replicate ground-based observations of continental drought areas and their trends. The CMIP5 multimodel ensemble encompasses the Climatic Research Unit (CRU) ground-based observations of area under drought at all time steps. However, most model members overestimate the areas under extreme drought, particularly in the Southern Hemisphere (SH). Furthermore, the results show that the time series of observations and CMIP5 simulations of areas under drought exhibit more variability in the SH than in the Northern Hemisphere (NH). The trend analysis of areas under drought reveals that the observational data exhibit a significant positive trend at the significance level of 0.05 over all land areas. The observed trend is reproduced by about three-fourths of the CMIP5 models when considering total land areas in drought. While models are generally consistent with observations at a global (or hemispheric) scale, most models do not agree with observed regional drying and wetting trends. Over many regions, at most 40% of the CMIP5 models are in agreement with the trends of CRU observations. The drying/wetting trends calculated using the 3 months Standardized Precipitation Index (SPI) values show better agreement with the corresponding CRU values than with the observed annual mean precipitation rates. Pixel-scale evaluation of CMIP5 models indicates that no single model demonstrates an overall superior performance relative to the other models
Sagnac Interferometer Enhanced Particle Tracking in Optical Tweezers
A setup is proposed to enhance tracking of very small particles, by using
optical tweezers embedded within a Sagnac interferometer. The achievable
signal-to-noise ratio is shown to be enhanced over that for a standard optical
tweezers setup. The enhancement factor increases asymptotically as the
interferometer visibility approaches 100%, but is capped at a maximum given by
the ratio of the trapping field intensity to the detector saturation threshold.
For an achievable visibility of 99%, the signal-to-noise ratio is enhanced by a
factor of 200, and the minimum trackable particle size is 2.4 times smaller
than without the interferometer
Quantitative Simulation of the Superconducting Proximity Effect
A numerical method is developed to calculate the transition temperature of
double or multi-layers consisting of films of super- and normal conductors. The
approach is based on a dynamic interpretation of Gorkov's linear gap equation
and is very flexible. The mean free path of the different metals, transmission
through the interface, ratio of specular reflection to diffusive scattering at
the surfaces, and fraction of diffusive scattering at the interface can be
included. Furthermore it is possible to vary the mean free path and the BCS
interaction NV in the vicinity of the interface. The numerical results show
that the normalized initial slope of an SN double layer is independent of
almost all film parameters except the ratio of the density of states. There are
only very few experimental investigations of this initial slope and they
consist of Pb/Nn double layers (Nn stands for a normal metal). Surprisingly the
coefficient of the initial slope in these experiments is of the order or less
than 2 while the (weak coupling) theory predicts a value of about 4.5. This
discrepancy has not been recognized in the past. The autor suggests that it is
due to strong coupling behavior of Pb in the double layers. The strong coupling
gap equation is evaluated in the thin film limit and yields the value of 1.6
for the coefficient. This agrees much better with the few experimental results
that are available.
PACS: 74.45.+r, 74.62.-c, 74.20.F
Ionized dopant concentrations at the heavily doped surface of a silicon solar cell
Data are combined with concentrations obtained by a bulk measurement method using successive layer removal with measurements of Hall effect and resistivity. From the MOS (metal-oxide-semiconductor) measurements it is found that the ionized dopant concentration N has the value (1.4 + or - 0.1) x 10 to the 20th power/cu cm at distances between 100 and 220 nm from the n(+) surface. The bulk measurement technique yields average values of N over layers whose thickness is 2000 nm. Results show that, at the higher concentrations encountered at the n(+) surface, the MOS C-V technique, when combined with a bulk measurement method, can be used to evaluate the effects of materials preparation methodologies on the surface and near surface concentrations of silicon cells
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