15,210 research outputs found
Electronic and magnetic properties of the kagome systems YBaCo4O7 and YBaCo3MO7 (M=Al, Fe)
We present a combined experimental and theoretical x-ray absorption
spectroscopy (XAS) study of the new class of cobaltates YBaCo4O7 and YBaCo3MO7
(M= Al, Fe). The focus is on the local electronic and magnetic properties of
the transition metal ions in these geometrically frustrated kagome compounds.
For the mixed valence cobaltate YBaCo4O7, both the Co2+ and Co3+ are found to
be in the high spin state. The stability of these high spin states in
tetrahedral coordination is compared with those in the more studied case of
octahedral coordination. For the new compound YBaCo3FeO7, we find exclusively
Co2+ and Fe3+ as charge states
The quantum dynamic capacity formula of a quantum channel
The dynamic capacity theorem characterizes the reliable communication rates
of a quantum channel when combined with the noiseless resources of classical
communication, quantum communication, and entanglement. In prior work, we
proved the converse part of this theorem by making contact with many previous
results in the quantum Shannon theory literature. In this work, we prove the
theorem with an "ab initio" approach, using only the most basic tools in the
quantum information theorist's toolkit: the Alicki-Fannes' inequality, the
chain rule for quantum mutual information, elementary properties of quantum
entropy, and the quantum data processing inequality. The result is a simplified
proof of the theorem that should be more accessible to those unfamiliar with
the quantum Shannon theory literature. We also demonstrate that the "quantum
dynamic capacity formula" characterizes the Pareto optimal trade-off surface
for the full dynamic capacity region. Additivity of this formula simplifies the
computation of the trade-off surface, and we prove that its additivity holds
for the quantum Hadamard channels and the quantum erasure channel. We then
determine exact expressions for and plot the dynamic capacity region of the
quantum dephasing channel, an example from the Hadamard class, and the quantum
erasure channel.Comment: 24 pages, 3 figures; v2 has improved structure and minor corrections;
v3 has correction regarding the optimizatio
Charge collective modes in an incommensurately modulated cuprate
We report the first measurement of collective charge modes of insulating
Sr14Cu24O41 using inelastic resonant x-ray scattering over the complete
Brillouin zone. Our results show that the intense excitation modes at the
charge gap edge predominantly originate from the ladder-containing planar
substructures. The observed ladder modes (E vs. Q) are found to be dispersive
for momentum transfers along the "legs" but nearly localized along the "rungs".
Dispersion and peakwidth characteristics are similar to the charge spectrum of
1D Mott insulators, and we show that our results can be understood in the
strong coupling limit (U >> t_{ladder}> t_{chain}). The observed behavior is in
marked contrast to the charge spectrum seen in most two dimensional cuprates.
Quite generally, our results also show that momentum-tunability of inelastic
scattering can be used to resolve mode contributions in multi-component
incommensurate systems.Comment: 4+ pages, 5 figure
Optoelectronic and excitonic properties of oligoacenes and one-dimensional nanostructures.
The optoelectronic and excitonic properties in a series of linear acenes are investigated using range-separated methods within time-dependent density functional theory (TDDFT). In these highly-conjugated systems, we find that the range-separated formalism provides a substantially improved description of excitation energies compared to conventional hybrid functionals, which surprisingly fail for the various low-lying valence transitions. Moreover, we find that even if the percentage of Hartree-Fock exchange in conventional hybrids is re-optimized to match wavefunction-based CC2 benchmark calculations, they still yield serious errors in excitation energy trends. Based on an analysis of electron-hole transition density matrices, we also show that conventional hybrid functionals overdelocalize excitons and underestimate quasiparticle energy gaps in the acene systems. The results of the present study emphasize the importance of a range-separated and asymptotically-correct contribution of exchange in TDDFT for investigating optoelectronic and excitonic properties, even for these simple valence excitations
Pair Analysis of Field Galaxies from the Red-Sequence Cluster Survey
We study the evolution of the number of close companions of similar
luminosities per galaxy (Nc) by choosing a volume-limited subset of the
photometric redshift catalog from the Red-Sequence Cluster Survey (RCS-1). The
sample contains over 157,000 objects with a moderate redshift range of 0.25 < z
< 0.8 and absolute magnitude in Rc (M_Rc) < -20. This is the largest sample
used for pair evolution analysis, providing data over 9 redshift bins with
about 17,500 galaxies in each. After applying incompleteness and projection
corrections, Nc shows a clear evolution with redshift. The Nc value for the
whole sample grows with redshift as (1+z)^m, where m = 2.83 +/- 0.33 in good
agreement with N-body simulations in a LCDM cosmology. We also separate the
sample into two different absolute magnitude bins: -25 < M_Rc < -21 and -21 <
M_Rc < -20, and find that the brighter the absolute magnitude, the smaller the
m value. Furthermore, we study the evolution of the pair fraction for different
projected separation bins and different luminosities. We find that the m value
becomes smaller for larger separation, and the pair fraction for the fainter
luminosity bin has stronger evolution. We derive the major merger remnant
fraction f_rem = 0.06, which implies that about 6% of galaxies with -25 < M_Rc
< -20 have undergone major mergers since z = 0.8.Comment: ApJ, in pres
Scientific basis for safely shutting in the Macondo Well after the April 20, 2010 Deepwater Horizon blowout
As part of the government response to the Deepwater Horizon blowout, a Well Integrity Team evaluated the geologic hazards of shutting in the Macondo Well at the seafloor and determined the conditions under which it could safely be undertaken. Of particular concern was the possibility that, under the anticipated high shut-in pressures, oil could leak out of the well casing below the seafloor. Such a leak could lead to new geologic pathways for hydrocarbon release to the Gulf of Mexico. Evaluating this hazard required analyses of 2D and 3D seismic surveys, seafloor bathymetry, sediment properties, geophysical well logs, and drilling data to assess the geological, hydrological, and geomechanical conditions around the Macondo Well. After the well was successfully capped and shut in on July 15, 2010, a variety of monitoring activities were used to assess subsurface well integrity. These activities included acquisition of wellhead pressure data, marine multichannel seismic pro- files, seafloor and water-column sonar surveys, and wellhead visual/acoustic monitoring. These data showed that the Macondo Well was not leaking after shut in, and therefore, it could remain safely shut until reservoir pressures were suppressed (killed) with heavy drilling mud and the well was sealed with cement
Controlling orbital moment and spin orientation in CoO layers by strain
We have observed that CoO films grown on different substrates show dramatic
differences in their magnetic properties. Using polarization dependent x-ray
absorption spectroscopy at the Co L edges, we revealed that the
magnitude and orientation of the magnetic moments strongly depend on the strain
in the films induced by the substrate. We presented a quantitative model to
explain how strain together with the spin-orbit interaction determine the 3d
orbital occupation, the magnetic anisotropy, as well as the spin and orbital
contributions to the magnetic moments. Control over the sign and direction of
the strain may therefore open new opportunities for applications in the field
of exchange bias in multilayered magnetic films
Smallpox and Dracunculiasis: The Scientific Value of Infectious Diseases That Have Been Eradicated or Targeted for Eradication. Is Schistosomiasis Next?
Observational and Dynamical Characterization of Main-Belt Comet P/2010 R2 (La Sagra)
We present observations of comet-like main-belt object P/2010 R2 (La Sagra)
obtained by Pan-STARRS 1 and the Faulkes Telescope-North on Haleakala in
Hawaii, the University of Hawaii 2.2 m, Gemini-North, and Keck I telescopes on
Mauna Kea, the Danish 1.54 m telescope at La Silla, and the Isaac Newton
Telescope on La Palma. An antisolar dust tail is observed from August 2010
through February 2011, while a dust trail aligned with the object's orbit plane
is also observed from December 2010 through August 2011. Assuming typical phase
darkening behavior, P/La Sagra is seen to increase in brightness by >1 mag
between August 2010 and December 2010, suggesting that dust production is
ongoing over this period. These results strongly suggest that the observed
activity is cometary in nature (i.e., driven by the sublimation of volatile
material), and that P/La Sagra is therefore the most recent main-belt comet to
be discovered. We find an approximate absolute magnitude for the nucleus of
H_R=17.9+/-0.2 mag, corresponding to a nucleus radius of ~0.7 km, assuming an
albedo of p=0.05. Using optical spectroscopy, we find no evidence of
sublimation products (i.e., gas emission), finding an upper limit CN production
rate of Q_CN<6x10^23 mol/s, from which we infer an H2O production rate of
Q_H2O<10^26 mol/s. Numerical simulations indicate that P/La Sagra is
dynamically stable for >100 Myr, suggesting that it is likely native to its
current location and that its composition is likely representative of other
objects in the same region of the main belt, though the relatively close
proximity of the 13:6 mean-motion resonance with Jupiter and the (3,-2,-1)
three-body mean-motion resonance with Jupiter and Saturn mean that dynamical
instability on larger timescales cannot be ruled out.Comment: 23 pages, 13 figures, accepted for publication in A
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