819 research outputs found
Analysis of Mesoscopic Structured 2-Propanol/Water Mixtures Using Pressure Perturbation Calorimetry and Molecular Dynamic Simulation
In this paper we demonstrate the application of pressure perturbation calorimetry (PPC) to the characterization of 2-propanol/water mixtures. PPC of different 2-propanol/water mixtures provides two useful measurements: (i) the change in heat (ΔQ); and (ii) the [δC¯p/δp]T[δC¯p/δp]T value. The results demonstrate that the ΔQ values of the mixtures deviate from that expected for a random mixture, with a maximum at ~20–25 mol% 2-propanol. This coincides with the concentration at which molecular dynamics (MD) simulations show a maximum deviation from random distribution, and also the point at which alcohol–alcohol hydrogen bonds become dominant over alcohol–water hydrogen bonds. Furthermore, the [δC¯p/δp]T[δC¯p/δp]T value showed transitions at 2.5 mol% 2-propanol and at approximately 14 mol% 2-propanol. Below 2.5 mol% 2-propanol the values of [δC¯p/δp]T[δC¯p/δp]T are negative; this is indicative of the presence of isolated 2-propanol molecules surrounded by water molecules. Above 2.5 mol% 2-propanol [δC¯p/δp]T[δC¯p/δp]T rises, reaching a maximum at ~14 mol% corresponding to a point where mixed alcohol–water networks are thought to dominate. The values and trends identified by PPC show excellent agreement not only with those obtained from MD simulations but also with results in the literature derived using viscometry, THz spectroscopy, NMR and neutron diffraction
Normal Forms for Symplectic Maps with Twist Singularities
We derive a normal form for a near-integrable, four-dimensional symplectic
map with a fold or cusp singularity in its frequency mapping. The normal form
is obtained for when the frequency is near a resonance and the mapping is
approximately given by the time- mapping of a two-degree-of freedom
Hamiltonian flow. Consequently there is an energy-like invariant. The fold
Hamiltonian is similar to the well-studied, one-degree-of freedom case but is
essentially nonintegrable when the direction of the singular curve in action
does not coincide with curves of the resonance module. We show that many
familiar features, such as multiple island chains and reconnecting invariant
manifolds, are retained even in this case. The cusp Hamiltonian has an
essential coupling between its two degrees of freedom even when the singular
set is aligned with the resonance module. Using averaging, we approximately
reduced this case to one degree of freedom as well. The resulting Hamiltonian
and its perturbation with small cusp-angle is analyzed in detail.Comment: LaTex, 27 pages, 21 figure
Reconstructing the 3-D Trajectories of CMEs in the Inner Heliosphere
A method for the full three-dimensional (3-D) reconstruction of the
trajectories of coronal mass ejections (CMEs) using Solar TErrestrial RElations
Observatory (STEREO) data is presented. Four CMEs that were simultaneously
observed by the inner and outer coronagraphs (COR1 and 2) of the Ahead and
Behind STEREO satellites were analysed. These observations were used to derive
CME trajectories in 3-D out to ~15Rsun. The reconstructions using COR1/2 data
support a radial propagation model. Assuming pseudo-radial propagation at large
distances from the Sun (15-240Rsun), the CME positions were extrapolated into
the Heliospheric Imager (HI) field-of-view. We estimated the CME velocities in
the different fields-of-view. It was found that CMEs slower than the solar wind
were accelerated, while CMEs faster than the solar wind were decelerated, with
both tending to the solar wind velocity.Comment: 17 pages, 10 figures, 1 appendi
Mossbauer and optical spectroscopic study of temperature and redox effects on iron local environments in a Fe-doped (0.5 mol% Fe2O3)18Na2O–72SiO2 glass
Local environments of ferric and ferrous irons were systematically studied with Mössbauer (at liquid helium temperature)and ultraviolet–visible–near infrared spectroscopic methods for various 18Na2O–72SiO2 glasses doped with 0.5 mol% Fe2O3. These were prepared at temperatures of 1300–1600 °C in ambient air or at 1500 °C under reducing conditions with oxygen partial pressures from 12.3 to 0.27 x 10-7 atmospheres. The Mössbauer spectroscopic method identified three types of local environments, which were represented by the Fe3+ sextet, the Fe3+ doublet, and the Fe2+ doublet. The Fe3+ sextet ions were assigned to “isolated” octahedral ions. Under reducing conditions, the octahedral Fe3+ ions were readily converted into octahedral ferrous ions. The Fe3+ doublet exists both in octahedral and tetrahedral environment, mainly as tetrahedral sites in the reduced samples. The tetrahedral ions were found stable against reduction to ferrous ions. The Fe2+ doublet sites existed in octahedral coordination. Combining results from both spectroscopic studies, the 1120- and 2020-nm optical bands were assigned to octahedral ferrous ions with a different degree of distortion rather than different coordinations. Further, we assigned the 375-nm band to the transition of octahedral ferric ions that are sensitive to the change of oxygen partial pressure in glass melting and 415-, 435-, and 485-nm bands to the transitions of the tetrahedral ferric ions that are insensitive to oxidation states of the melt. The effect of ferric and ferrous ions with different coordination environments on the glass immiscibility was elucidated
Strategies for the production of dsRNA biocontrols as alternatives to chemical pesticides
Current crop pest control strategies rely on insecticidal and fungicidal sprays, plant genetic resistance, transgenes and agricultural practices. However, many insects, plant viruses, and fungi have no current means of control or have developed resistance against traditional pesticides. dsRNA is emerging as a novel sustainable method of plant protection as an alternative to traditional chemical pesticides. The successful commercialisation of dsRNA based biocontrols for effective pest management strategies requires the economical production of large quantities of dsRNA combined with suitable delivery methods to ensure RNAi efficacy against the target pest. A number of methods exist for the production and delivery of dsRNA based biocontrols and here we review alternative methods currently employed and emerging new approaches for their production. Additionally, we highlight potential challenges that will need to be addressed prior to widespread adoption of dsRNA biocontrols as novel sustainable alternatives to traditional chemical pesticides
Fluctuations of an evaporating black hole from back reaction of its Hawking radiation: Questioning a premise in earlier work
This paper delineates the first steps in a systematic quantitative study of
the spacetime fluctuations induced by quantum fields in an evaporating black
hole. We explain how the stochastic gravity formalism can be a useful tool for
that purpose within a low-energy effective field theory approach to quantum
gravity. As an explicit example we apply it to the study of the
spherically-symmetric sector of metric perturbations around an evaporating
black hole background geometry. For macroscopic black holes we find that those
fluctuations grow and eventually become important when considering sufficiently
long periods of time (of the order of the evaporation time), but well before
the Planckian regime is reached. In addition, the assumption of a simple
correlation between the fluctuations of the energy flux crossing the horizon
and far from it, which was made in earlier work on spherically-symmetric
induced fluctuations, is carefully analyzed and found to be invalid. Our
analysis suggests the existence of an infinite amplitude for the fluctuations
of the horizon as a three-dimensional hypersurface. We emphasize the need for
understanding and designing operational ways of probing quantum metric
fluctuations near the horizon and extracting physically meaningful information.Comment: 10 pages, REVTeX; minor changes, a few references added and a brief
discussion of their relevance included. To appear in the proceedings of the
10th Peyresq meeting. Dedicated to Rafael Sorkin on the occasion of his 60th
birthda
Psychoanalysis as the Patient: High in Feeling, Low in Energy
This paper examines the increasingly important role that affect is assuming in psychoanalytic research and practice. This rise in the centrality of affect has been at the expense of an independent role for motivation and a dismissal of any energy concept. Difficulties with this affect-first approach are identified and an alternative offered that accords motivation an independent role and accommodates a useful energy concept. Research on esophageal atresia, addiction, and infant suckling are cited in support of this position.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66624/2/10.1177_00030651970450031101.pd
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YMP Engineered Barrier Systems Scaled Ventilation Testing
Yucca Mountain, approximately 100 miles northwest of Las Vegas, Nevada, has been selected as the site for the nation's first geologic repository for high level nuclear waste. The Yucca Mountain Project (YMP) is currently developing the design for the underground facilities. Ventilation is a key component of the design as a way to maintain the desired thermal conditions in the emplacement drifts prior to closure. As a means of determining the effects of continuous ventilation on heat removal from the emplacement drifts two series of scaled ventilation tests have been performed. Both test series were performed in the DOE/North Las Vegas Atlas facility. The tests provided scaled (nominally 25% of the full scale emplacement drift design) thermal and flow process data that will be used to validate YMP heat and mass transport codes. The Phase I Ventilation Test series evaluated the ability of ambient ventilation air to remove energy under varying flow and input power conditions. The Phase II Ventilation Test series evaluated the ability of pre-conditioned ventilation air to remove energy under varying flow, input temperature and moisture content, and simulated waste package input power conditions. Twenty-two distinct ventilation tests were run
Heat kernel regularization of the effective action for stochastic reaction-diffusion equations
The presence of fluctuations and non-linear interactions can lead to scale
dependence in the parameters appearing in stochastic differential equations.
Stochastic dynamics can be formulated in terms of functional integrals. In this
paper we apply the heat kernel method to study the short distance
renormalizability of a stochastic (polynomial) reaction-diffusion equation with
real additive noise. We calculate the one-loop {\emph{effective action}} and
its ultraviolet scale dependent divergences. We show that for white noise a
polynomial reaction-diffusion equation is one-loop {\emph{finite}} in and
, and is one-loop renormalizable in and space dimensions. We
obtain the one-loop renormalization group equations and find they run with
scale only in .Comment: 21 pages, uses ReV-TeX 3.
Life path analysis: scaling indicates priming effects of social and habitat factors on dispersal distances
1. Movements of many animals along a life-path can be separated into repetitive ones within home ranges and transitions between home ranges. We sought relationships of social and environmental factors with initiation and distance of transition movements in 114 buzzards Buteo buteo that were marked as nestlings with long-life radio tags.
2. Ex-natal dispersal movements of 51 buzzards in autumn were longer than for 30 later in their first year and than 35 extra-natal movements between home ranges after leaving nest areas. In the second and third springs, distances moved from winter focal points by birds that paired were the same or less than for unpaired birds. No post-nuptial movement exceeded 2 km.
3. Initiation of early ex-natal dispersal was enhanced by presence of many sibs, but also by lack of worm-rich loam soils. Distances travelled were greatest for birds from small broods and with relatively little short grass-feeding habitat near the nest. Later movements were generally enhanced by the absence of loam soils and short grassland, especially with abundance of other buzzards and probable poor feeding habitats (heathland, long grass).
4. Buzzards tended to persist in their first autumn where arable land was abundant, but subsequently showed a strong tendency to move from this habitat.
5. Factors that acted most strongly in ½-km buffers round nests, or round subsequent focal points, usually promoted movement compared with factors acting at a larger scale. Strong relationships between movement distances and environmental characteristics in ½-km buffers, especially during early ex-natal dispersal, suggested that buzzards became primed by these factors to travel far.
6. Movements were also farthest for buzzards that had already moved far from their natal nests, perhaps reflecting genetic predisposition, long-term priming or poor habitat beyond the study area
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