10,614 research outputs found
The why's the limit: curtailing self-enhancement with explanatory introspection
Self-enhancement is linked to psychological gains (e.g., subjective well-being, persistence in adversity) but also to intrapersonal and interpersonal costs (e.g., excessive risk taking, antisocial behavior). Thus, constraints on self-enhancement may sometimes afford intrapersonal and interpersonal advantages. We tested whether explanatory introspection (i.e., generating reasons for why one might or might not possess personality traits) constitutes one such constraint. Experiment 1 demonstrated that explanatory introspection curtails self-enhancement. Experiment 2 clarified that the underlying mechanism must (a) involve explanatory questioning rather than descriptive imagining, (b) invoke the self rather than another person, and (c) feature written expression rather than unaided contemplation. Finally, Experiment 3 obtained evidence that an increase in uncertainty about oneself mediates the effect
Stable and unstable regimes in Bose-Fermi mixture with attraction between components
A collapse of the trapped boson- fermion mixture with the attraction between
bosons and fermions is investigated in the framework of the effective
Hamiltonian for the Bose system. The properties of the Rb and K
mixture are analyzed quantitatively at . We find numerically solutions of
modified Gross- Pitaevskii equation which continuously go from stable to
unstable branch. We discuss the relation of the onset of collapse with
macroscopic properties of the system. A comparison with the case of a Bose
condensate of atomic system is given.Comment: 7 pages, 5 figure
Radical-cation salts of BEDT-TTF with lithium tris(oxalato)metallate(III)
The first radical-cation salts in the extensive family (BEDT-TTF)x[(A)M(C2O4)3]·Guest containing lithium as the counter cation have been synthesized and characterised
A non-local, Lorentz-invariant, hidden-variable interpretation of relativistic quantum mechanics based on particle trajectories
We demonstrate how to construct a lorentz-invariant, hidden-variable
interpretation of relativistic quantum mechanics based on particle
trajectories. The covariant theory that we propose employs a multi-time
formalism and a lorentz-invariant rule for the coordination of the space-time
points on the individual particle trajectories. In this way we show that there
is no contradiction between nonlocality and lorentz invariance in quantum
mechanics. The approach is illustrated for relativistic bosons, using a simple
model to discuss the individual non-locally correlated particle motion which
ensues when the wavefunction is entangled. A simple example of measurement is
described.Comment: 12 pages, 2 figure
Charge transfer complexes and radical cation salts of chiral methylated organosulfur donors
The single crystal X-ray structure of the all-axial conformer of the (R,R,R,R) enantiomer of the chiral donor tetramethyl-BEDT-TTF (TM-BEDT-TTF) was described and compared to the all-equatorial conformer. (S,S,S,S)-Tetramethyl-BEDT-TTF formed crystalline 1 : 1 complexes with TCNQ and TCNQ-F4, as well as a THF solvate of the TCNQ complex. Donors bis((2S,4S)-pentane-2,4-dithio)tetrathiafulvalene and (ethylenedithio)((2S,4S)-pentane-2,4-dithio)tetrathiafulvalene, which contain seven-membered rings bearing chirally oriented methyl groups, only formed complexes with TCNQ-F4. The TCNQ-F4 complexes contain planar organosulfur systems, in contrast to the TCNQ complexes in which there is minimal charge transfer. A variety of crystal packing modes were observed. Electrocrystallization experiments with both enantiomers and the racemic form of tetramethyl-BEDT-TTF afforded mixed valence radical cation salts with the AsF6 and SbF6 anions formulated as (TM-BEDT-TTF)2XF6 (X = As, Sb). Electrical conductivity was only found in one charge transfer complex, while the radical cation salts are all semiconducting
PRACTICAL APPLICATION OF SUSPENSION CRITERIA SCENARIOS: RADIOTHERAPY.
In 2007, the European Commission (EC) commissioned a group of experts to undertake the revision of Report RP91 'Criteria for Acceptability of Radiological (including Radiotherapy) and Nuclear Medicine Installations' written in 1997. The revised draft report was submitted to the EC in 2010, which issued it for public consultation. The EC commissioned the same group of experts to consider the comments of the public consultation for further improvement of the revised report. The EC intends to publish the final report under its Radiation Report Series as RP162. This paper presents a selection of practical applications of suspension criteria scenarios in radiotherapy, mostly in brachytherapy, with special emphasis on the critical roles and responsibilities of qualified radiotherapy staff (radiation oncologists, medical physicists and radiotherapy technicians)
Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations
The synthesis and characterization of a series of pentaborate(1�) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1�4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (<250 °C) and oxidative decomposition (250�600 °C). BET analysis of materials derived thermally from the pentaborates 1 and 2 had internal porosities of <1 m2 g�1, indicating they were non-porous. All compounds show extensive supramolecular H-bonded anionic lattices. H-bond interactions are described in detail and motifs found in these and in other pentaborate structures have been examined and modelled by DFT calculations. These calculations confirm that H-bonds interactions in pentaborates are moderately strong (ca. �10 to �21 kJ mol�1) and are likely to dominate the energetics of their templated syntheses
Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts
The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear [Fe2(oxalate)5 ]4- anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide
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