3,610 research outputs found
Magnetism, structure, and charge correlation at a pressure-induced Mott-Hubbard insulator-metal transition
We use synchrotron x-ray diffraction and electrical transport under pressure
to probe both the magnetism and the structure of single crystal NiS2 across its
Mott-Hubbard transition. In the insulator, the low-temperature
antiferromagnetic order results from superexchange among correlated electrons
and couples to a (1/2, 1/2, 1/2) superlattice distortion. Applying pressure
suppresses the insulating state, but enhances the magnetism as the
superexchange increases with decreasing lattice constant. By comparing our
results under pressure to previous studies of doped crystals we show that this
dependence of the magnetism on the lattice constant is consistent for both band
broadening and band filling. In the high pressure metallic phase the lattice
symmetry is reduced from cubic to monoclinic, pointing to the primary influence
of charge correlations at the transition. There exists a wide regime of phase
separation that may be a general characteristic of correlated quantum matter.Comment: 5 pages, 3 figure
Zener double exchange from local valence fluctuations in magnetite
Magnetite (FeO) is a mixed valent system where electronic
conductivity occurs on the B-site (octahedral) iron sublattice of the spinel
structure. Below K, a metal-insulator transition occurs which is
argued to arise from the charge ordering of 2+ and 3+ iron valences on the
B-sites (Verwey transition). Inelastic neutron scattering measurements show
that optical spin waves propagating on the B-site sublattice (80 meV) are
shifted upwards in energy above due to the occurrence of B-B
ferromagnetic double exchange in the mixed valent metallic phase. The double
exchange interaction affects only spin waves of symmetry, not all
modes, indicating that valence fluctuations are slow and the double exchange is
constrained by electron correlations above .Comment: 4 pages, 5 figure
Relation among concentrations of incorporated Mn atoms, ionized Mn acceptors, and holes in p-(Ga,Mn)As epilayers
The amount of ionized Mn acceptors in various p-type Mn-doped GaAs epilayers
has been evaluated by electrochemical capacitance-voltage measurements, and has
been compared systematically with concentrations of incorporated Mn atoms and
holes for wide range of Mn concentration (10^17 ~ 10^21 cm^-3). Quantitative
assessment of anomalous Hall effect at room temperature is also carried out for
the first time.Comment: 8 pages, 4 figures, tabl
Dynamic phenomena in superconducting oxides by ESR
Dynamic electron spin resonance (ESR) measurements compare the paramagnetic and antiferromagnetic (AF) properties of superconducting oxides in the range 4 K to room temperature, at 8 MHz and 9.36 GHz. Two are derivatives of YBa2Cu30 7: 1: Nd(Nd0.05Ba0.95 )2Cu30 7, Te0 =72 K and II: Y0.2Cao.8Sr2[Cu2(Tlo.5Pb0.5 )]07, Te0 =108 K and two are cases where AF ordering dominates the weak superconductivity: III: Nb01.1\u3e 1. 25 ~Teo~ 10 K and IV: La2Ni04.00, 70 K :::: Teo:::: 40 K. At temperatures 298:::: T:::: 64 K, the ESR absorption by I indicates orthorhombic symmetry. The peaks at Ke =2.06, gb =2.13, and Ka =2.24 are identified with the presence of 5% Nd3+( 41912 ) in the Ba layer because the characteristic Cu2+ impurity hyperfine structure is absent and the ESR signal disappears several degrees below Te. Near Te the ESR absorption is reduced by two orders of magnitude. Proximity effects give rise to interference fringes with period r1 ( T) independent of the field B and the rate of sweep dBzldt. ESR is observed below Te because flux penetrates the superconductor. The temperature dependence of r1 leads to an activation energy for the flux motion E0 (1)/R ~ 16 K and Ea (111)/R ~3 K =Te /4. In the superconducting state a coherent flux expulsion response to a change in B. from 500 mT to zero is observed in times T, = 8 to 10 s. The inverse rate of noise spikes due to flux expulsion, when the samples are cooled through Te in a magnetic field, varies from Tnoise=3.5 s for III to 21 s for IV. The microwave absorption spectra identify three temperature regimes: (i) For 3.5 K \u3c T \u3c T m T* \u3c Teo superconducting behavior was confirmed by the energy loss near zero magnetic field and the kinetics of high-field noise due to flux expulsion. Near g =2.00 ESR absorption is observed for all materials. A broad absorption near 50 to 100 mT at 9.36 GHz has been attributed to AF resonance. (ii) T m T* ~ T ~ Te identifies the range where flux motion gives rise to interference fringes in the ESR absorption. (iii) ESR and AF resonance are observed immediately after warming above Tc
Modus Vivendi Beyond the Social Contract: Peace, Justice, and Survival in Realist Political Theory
This essay examines the promise of the notion of modus vivendi for realist political theory. I interpret recent theories of modus vivendi as affirming the priority of peace over justice, and explore several ways of making sense of this idea. I proceed to identify two key problems for modus vivendi theory, so conceived. Normatively speaking, it remains unclear how this approach can sustain a realist critique of Rawlsian theorizing about justice while avoiding a Hobbesian endorsement of absolutism. And conceptually, the theory remains wedded to a key feature of social contract theory: political order is conceived as based on agreement. This construes the horizontal tensions among individual or group agents in society as prior to the vertical, authoritative relations between authorities and their subjects. Political authority thereby appears from the start as a solution to societal conflict, rather than a problem in itself. I argue that this way of framing the issue abstracts from political experience. Instead I attempt to rethink the notion of modus vivendi from within the lived experience of political conflict, as oriented not primarily toward peace, but political survival. With this shift of perspective, the idea of modus vivendi shows us, pace Bernard Williams, that the “first political question” is not how to achieve order and stability, but rather: what can I live with
Verwey transition in FeO at high pressure: quantum critical behavior at the onset of metallization
We provide evidence for the existence of a {\em quantum critical point} at
the metallization of magnetite FeO at an applied pressure of GPa. We show that the present ac magnetic susceptibility data
support earlier resistivity data. The Verwey temperature scales with pressure
, with . The resistivity data shows a
temperature dependence , with above and
2.5 at the critical pressure, respectively. This difference in with
pressure is a sign of critical behavior at . The magnetic susceptibility
is smooth near the critical pressure, both at the Verwey transition and near
the ferroelectric anomaly. A comparison with the critical behavior observed in
the Mott-Hubbard and related systems is made.Comment: 5 pages, 5 figure
Brillouin scattering studies in FeO across the Verwey transition
Brillouin scattering studies have been carried out on high quality single
crystals of FeO with [100] and [110] faces in the temperature range of
300 to 30 K. The room temperature spectrum shows a surface Rayleigh wave (SRW)
mode at 8 GHz and a longitudinal acoustic (LA) mode at 60 GHz. The SRW mode
frequency shows a minimum at the Verwey transition temperature of 123 K.
The softening of the SRW mode frequency from about 250 K to can be
quantitatively understood as a result of a decrease in the shear elastic
constant C, arising from the coupling of shear strain to charge
fluctuations. On the other hand, the LA mode frequency does not show any
significant change around , but shows a large change in its intensity. The
latter shows a maximum at around 120 K in the cooling run and at 165 K in the
heating run, exhibiting a large hysteresis of 45 K. This significant change in
intensity may be related to the presence of stress-induced ordering of
Fe and Fe at the octahedral sites, as well as to stress-induced
domain wall motion.Comment: 14 pages, 3 figures, accepted in Physical Review B 200
Investigation of the presence of charge order in magnetite by measurement of the spin wave spectrum
Inelastic neutron scattering results on magnetite (Fe3O4) show a large splitting in the acoustic spin wave branch, producing a 7 meV gap midway to the Brillouin zone boundary at q=(0,0,1∕2) and ℏω=43 meV. The splitting occurs below the Verwey transition temperature, where a metal-insulator transition occurs simultaneously with a structural transformation, supposedly caused by the charge ordering on the iron sublattice. The wavevector (0,0,1∕2) corresponds to the superlattice peak in the low symmetry structure. The dependence of the magnetic superexchange on changes in the crystal structure and ionic configurations that occur below the Verwey transition affect the spin wave dispersion. To better understand the origin of the observed splitting, several Heisenberg models intended to reproduce the pair-wise variation of the magnetic superexchange arising from both small crystalline distortions and charge ordering were studied. None of the models studied predicts the observed splitting, whose origin may arise from charge-density wave formation or magnetoelastic coupling.Work is supported by the U. S. Department of Energy Office of Science under the following
contracts; Ames Laboratory under Contract No. W-7405-ENG-82, Oak Ridge National Laboratory, which is managed by UT-Batelle LLC, under Contract No. DE-AC00OR22725
and Brookhaven National Laboratory under Contract DEAC02-98CH10886
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