486 research outputs found
Orthogonal Polynomial Projectors for the Projector Augmented Wave Method of Electronic Structure Calculations
The projector augmented wave (PAW) method for electronic structure calculations developed by Blochl [Phys. Rev. B 50, 17 953 (1994)] has been very successfully used for density functional studies. It has the numerical advantages of pseudopotential techniques while retaining the physics of all-electron formalisms. We describe a method for generating the set of atom-centered projector and basis functions that are needed for the PAW method. This scheme chooses the shapes of the projector functions from a set of orthogonal polynomials multiplied by a localizing weight factor. Numerical benefits of the scheme result from having direct control of the shape of the projector functions and from the use of a simple repulsive local potential term to eliminate ââghost stateââ problems, which can plague calculations of this kind. Electronic density of states results are presented for the mineral powellite (CaMoO4)
Comparison of the Projector Augmented-Wave, Pseudopotential, and Linearized Augmented-Plane-Wave Formalisms for Density-Functional Calculations of Solids
The projector augmented-wave (PAW) method was developed by Blöchl as a method to accurately and efficiently calculate the electronic structure of materials within the framework of density-functional theory. It contains the numerical advantages of pseudopotential calculations while retaining the physics of all-electron calculations, including the correct nodal behavior of the valence-electron wave functions and the ability to include upper core states in addition to valence states in the self-consistent iterations. It uses many of the same ideas developed by Vanderbilt in his soft pseudopotential\u27\u27 formalism and in earlier work by Blöchl in his generalized separable potentials,\u27\u27 and has been successfully demonstrated for several interesting materials. We have developed a version of the PAW formalism for general use in structural and dynamical studies of materials. In the present paper, we investigate the accuracy of this implementation in comparison with corresponding results obtained using pseudopotential and linearized augmented-plane-wave (LAPW) codes. We present results of calculations for the cohesive energy, equilibrium lattice constant, and bulk modulus for several representative covalent, ionic, and metallic materials including diamond, silicon, SiC, CaF2, fcc Ca, and bcc V. With the exception of CaF2, for which core-electron polarization effects are important, the structural properties of these materials are represented equally well by the PAW, LAPW, and pseudopotential formalisms
FĂRSTER TRANSFER CALCULATIONS BASED ON CRYSTAL STRUCTURE DATA FROM Agmenellum quadruplicatum C-PHYCOCYANIN
Excitation energy transfer in C-phycocyanin is modeled using the Forster inductive resonance mechanism. Detailed calculations are carried out using coordinates and orientations of the chromophores derived from X-ray crystallographic studies of C-phycocyanin from two different species (Schirmer et al, J. Mol. Biol. 184, 257â277 (1985) and ibid., 188, 651-677 (1986)). Spectral overlap integrals are estimated from absorption and fluorescence spectra of C-phycocyanin of Mastigocladus laminosus and its separated subunits. Calculations are carried out for the ÎČ-subunit, αÎČ-monomer, (αÎČ)3-trimer and (αÎČ)0-hexamer species with the following chromophore assignments: ÎČ155 = 'sâ(sensitizer), ÎČ84 =âf (fluorescer) and α84 =âmâ(intermediate):]:. The calculations show that excitation transfer relaxation occurs to 3=98% within 200 ps in nearly every case; however, the rates increase as much as 10-fold for the higher aggregates. Comparison with experimental data on fluorescence decay and depolarization kinetics from the literature shows qualitative agreement with these calculations. We conclude that Forster transfer is sufficient to account for all of the observed fluorescence properties of C-phycocyanin in aggregation states up to the hexamer and in the absence of linker polypeptides
PHOTOCHEMISTRY OF PHYCOBILIPROTEINS
Native PEC from the cyanobacterium, Mastigocladus laminosus, and its isolated α-subunit show photoreversibly photochromic reactions with difference-maxima around 502 and 570 nm in the spectral region of the α-84 phycoviolobilin chromophore. (b) Native PEC and its ÎČ-subunit show little if any reversible photochemistry in the 600â620 nm region, where the phycocyanobilin chromophores on the ÎČ-subunit absorb maximally, (c) Reversible photochemistry is retained in ureadenatured PEC at pH = 7.0 or pH †3. The difference maxima are shifted to 510 and 600 nm, and the amplitudes are decreased. An irreversible absorbance increase occurs around 670 nm (pH †3). (d) The amplitude of the reversible photoreaction difference spectrum is maximum in the presence of 4â5 M urea or 1 M KSCN, conditions known to dissociate phycobiliprotein aggregates into monomers. At the same time, the phycocyanobilin chromophore(s) are bleached irreversibly, (e) The amplitude becomes very small in high aggregates, e.g. in phycobilisomes. (f) In a reciprocal manner, the phototransformation of native PEC leads to a reversible shift of its aggregation equilibrium between trimer and monomer. The latter is favored by orange, the former by green light, (g) It is concluded that the phycoviolobilin chromophore of PEC is responsible for reversible photochemistry in PEC, and that there is not only an influence of aggregation state on photochemistry, but also vice versa an effect of the status of the chromophore on aggregation state. This could constitute a primary signal in the putative function as sensory pigment, either directly, or indirectly via the release of other polypeptides, via photodynamic effects, or the like
THERMAL DENATURATION OF MONOMERIC AND TRIMERIC PHYCOCYANINS STUDIED BY STATIC AND SPECTROSCOPY POLARIZED TIME-RESOLVED FLUORESCENCE
C-Phycocyanin (PC) and allophycocyanin (APC). as well as the a-subunit of PC. have been
isolated from the blue-green alga (cyanobacterium). Spirulina platensis. The effects of partial thermal
denaturation of PC and of its state of aggregation have been studied by ps time-resolved, polarized
fluorescence spectroscopy. All measurements have been performed under low photon fluxes (< 10â â
photonsipulse x cmâ) to minimize singlet-singlet annihilation processes. A complex decay is obtained
under most conditions, which can be fitted satisfactorily with a bi-exponential (7â = 70400 ps. T? =
1000-3000 ps) for both the isotropic and the polarized part, but with different intensities and time
constants for the two decay curves. The data are interpreted in the frameworkof the model first developed
by Teak and Dale (Biochern. J. 116, 161 (1970)], which divides the spectroscopically different
chromophores in (predominantly) sensitizing (s) and fluorescing U, ones. If one assumes temperature
dependent losses in the energy transfer from the s to the f and between f chromophores. both the
biexponential nature of the isotropic fluorescence decay and the polarization data can be rationalized. In
the isotropic emission (corresponding to the population of excited states) the short lifetime is related to the
s-,f transfer. the longer one to the âfreeâ decay of the final acceptor(s) (= f). The polarized part is
dominated by an extremely short decay time. which is related to s+f transfer, as well as to resonance
transfer between the f-chromophores
Electro-Magnetic Nucleon Form Factors and their Spectral Functions in Soliton Models
It is demonstrated that in simple soliton models essential features of the
electro-magnetic nucleon form factors observed over three orders of magnitude
in momentum transfer are naturally reproduced. The analysis shows that
three basic ingredients are required: an extended object, partial coupling to
vector mesons, and relativistic recoil corrections. We use for the extended
object the standard skyrmion, one vector meson propagator for both isospin
channels, and the relativistic boost to the Breit frame. Continuation to
timelike leads to quite stable results for the spectral functions in the
regime from the 2- or 3-pion threshold to about two rho masses. Especially the
onset of the continuous part of the spectral functions at threshold can be
reliably determined and there are strong analogies to the results imposed on
dispersion theoretic approaches by the unitarity constraint.Comment: 24 pages, (RevTeX), 5 PS-figures; Data points in fig.2 and
corresponding references added. Final version, to be published in Z.Physik
Consistent off-shell vertex and nucleon self-energy
We present a consistent calculation of half-off-shell form factors in the
pion-nucleon vertex and the nucleon self-energy. Numerical results are
presented. Near the on-shell point the pion-nucleon vertex is dominated by the
pseudovector coupling, while at large nucleon invariant masses we find a
sizable pseudoscalar admixture.Comment: 23 pages, 7 figures, REVTeX, submitted to Phys. Rev. C, replaced with
corrected versio
New Limits to the Drift of Fundamental Constants from Laboratory Measurements
We have remeasured the absolute - transition frequency in atomic hydrogen. A comparison with the result of the previous
measurement performed in 1999 sets a limit of Hz for the drift of
with respect to the ground state hyperfine splitting in Cs. Combining this result with the recently published
optical transition frequency in Hg against and a
microwave Rb and Cs clock comparison, we deduce separate limits
on yr and the
fractional time variation of the ratio of Rb and Cs nuclear magnetic moments
equal to
yr. The latter provides information on the temporal behavior of the
constant of strong interaction.Comment: 4 pages, 3 figures, LaTe
The Space Optical Clocks Project: Development of high-performance transportable and breadboard optical clocks and advanced subsystems
The use of ultra-precise optical clocks in space ("master clocks") will allow
for a range of new applications in the fields of fundamental physics (tests of
Einstein's theory of General Relativity, time and frequency metrology by means
of the comparison of distant terrestrial clocks), geophysics (mapping of the
gravitational potential of Earth), and astronomy (providing local oscillators
for radio ranging and interferometry in space). Within the ELIPS-3 program of
ESA, the "Space Optical Clocks" (SOC) project aims to install and to operate an
optical lattice clock on the ISS towards the end of this decade, as a natural
follow-on to the ACES mission, improving its performance by at least one order
of magnitude. The payload is planned to include an optical lattice clock, as
well as a frequency comb, a microwave link, and an optical link for comparisons
of the ISS clock with ground clocks located in several countries and
continents. Undertaking a necessary step towards optical clocks in space, the
EU-FP7-SPACE-2010-1 project no. 263500 (SOC2) (2011-2015) aims at two
"engineering confidence", accurate transportable lattice optical clock
demonstrators having relative frequency instability below 1\times10^-15 at 1 s
integration time and relative inaccuracy below 5\times10^-17. This goal
performance is about 2 and 1 orders better in instability and inaccuracy,
respectively, than today's best transportable clocks. The devices will be based
on trapped neutral ytterbium and strontium atoms. One device will be a
breadboard. The two systems will be validated in laboratory environments and
their performance will be established by comparison with laboratory optical
clocks and primary frequency standards. In this paper we present the project
and the results achieved during the first year.Comment: Contribution to European Frequency and Time Forum 2012, Gothenburg,
Swede
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