1,305 research outputs found

    Intermittency and non-Gaussian fluctuations of the global energy transfer in fully developed turbulence

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    We address the experimentally observed non-Gaussian fluctuations for the energy injected into a closed turbulent flow at fixed Reynolds number. We propose that the power fluctuations mirror the internal kinetic energy fluctuations. Using a stochastic cascade model, we construct the excess kinetic energy as the sum over the energy transfers at different levels of the cascade. We find an asymmetric distribution that strongly resembles the experimental data. The asymmetry is an explicit consequence of intermittency and the global measure is dominated by small scale events correlated over the entire system. Our calculation is consistent with the statistical analogy recently made between a confined turbulent flow and a critical system of finite size.Comment: To appear in Physical Review Letter

    The effects of nonvascularized versus vascularized bone grafting on calvarial defect healing.

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    It remains unknown whether bone graft vascularity influences calvarial healing. The purposes of this study were (1) to develop a model to study nonvascularized and vascularized calvarial grafts as well as (2) to compare effects of bone graft vascularity on calvarial healing. Bilateral calvarial defects were created in 26 Wistar rats. The defects were left empty within 1 parietal region. On the contralateral side, the defects were partially closed with native parietal bone (control group, n = 6), nonvascularized (N-V, n = 10), or vascularized bone grafts (VAS, n = 10). The vascularized grafts were supplied by perforating dural arterioles. Bone mineralization and healing patterns from serial microcomputed tomographic scans were compared within and across the groups using parametric and nonparametric tests. Differences in bone mineral content across sides were significant between the groups at weeks 6 (P = 0.016) and 12 (P = 0.025). Bone formation was greater within both the control and VAS groups versus the N-V group at weeks 6 and 12 (P \u3c 0.05). Healing patterns differed between the groups (P \u3c 0.05), progressing through islands of new bone formation within the control and VAS groups while limited to defect margins on the N-V graft side. In conclusion, a bilateral calvarial defect model was established to study bone graft vascularity. Bone quantity and healing patterns differed in the presence of the nonvascularized versus vascularized grafts. Although the calvarial defect model is often applied within the plastic surgery literature to study bone substitutes, greater understanding of basic mechanisms influencing calvarial healing is first needed to avoid confounding results

    Spin-wave analysis of the transverse-field Ising model on the checkerboard lattice

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    The ground state properties of the S=1/2 transverse-field Ising model on the checkerboard lattice are studied using linear spin wave theory. We consider the general case of different couplings between nearest neighbors (J1) and next-to-nearest neighbors (J2). In zero field the system displays a large degeneracy of the ground state, which is exponential in the system size (for J1=J2) or in the system's linear dimensions (for J2>J1). Quantum fluctuations induced by a transverse field are found to be unable to lift this degeneracy in favor of a classically ordered state at the harmonic level. This remarkable fact suggests that a quantum-disordered ground state can be instead promoted when non-linear fluctuations are accounted for, in agreement with existing results for the isotropic case J1=J2. Moreover spin-wave theory shows sizable regions of instability which are further candidates for quantum-disordered behavior.Comment: 12 pages, 13 figure

    Catalytic conversion of glycerol to polymers in the presence of ammonia

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    In this contribution, the development of a process for the synthesis of potentially highly valuable polymeric products from the reaction of waste glycerol with ammonia is reported for the first time. The polymers were the result of a single step, continuous gas phase process, catalysed by an alumina-supported iron catalyst, operating under relatively mild reaction conditions. The solid product was characterised using 1D and 2D NMR spectroscopy, FTIR spectroscopy, qualitative chemical tests and elemental analysis. Characterisation revealed building blocks with unsaturated, amido and ester functionalities shaping a mixture of polymers. Nitrogen atoms were present in the main chain of the resultant polymers. NMR analyses of the polymer denotes the formation of structural defects such as unsaturation and branching; whilst the partial solubility of the polymer in solvents such as CDCl3 and THF is indicative of the formation of cross-linked structures. Insights into the mechanism of formation of these functional groups were based on the liquid and gas phase product distribution. Polymers with chain structures similar to those synthesised in this work are currently manufactured from fossil fuels and are widely used in biomedical applications not only because of their architecture but also due to their response to changes in pH and temperature

    A revised age, structural model and origin for the North Pennine Orefield in the Alston Block, northern England: intrusion (Whin Sill)-related base metal (Cu–Pb–Zn–F) mineralization

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    Mineralization and associated fluid migration events in the c. 1500 km2 North Pennine Orefield (NPO) are known to be associated with tectonic activity, but the age of these tectonic events and origins of the base metal sulfide mineralization remain unresolved. New fieldwork in the Alston Block shows that mineralization post-dates a weakly developed phase of north–south shortening consistent with far-field Variscan basin inversion during the late Carboniferous. New observations of field relationships, coupled with microstructural observations and stress inversion analyses, together with Re–Os sulfide geochronology show that the vein-hosted mineralization (apart from barium minerals) was synchronous with a phase of north–south extension and east–west shortening coeval with emplacement of the Whin Sill (c. 297–294 Ma). Thus the development of the NPO was related to an early Permian regional phase of transtensional deformation, mantle-sourced hydrothermal mineralization and magmatism in northern Britain. Previously proposed Mississippi Valley Type models, or alternatives relating mineralization to the influx of Mesozoic brines, can no longer be applied to the development of the NPO in the Alston Block. Our findings also mean that existing models for equivalent base metal sulfide fields worldwide (e.g. Zn–Pb districts of Silesia, Poland and Tennessee, USA) may need to be reassessed

    Report on Transfer Tax Restructuring

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    This report is submitted to the Council of the Section of Taxation, American Bar Association as a proposed response to the request of the Treasury Department for suggestions for reform of the Federal transfer taxes (the estate, gift, and generation-skipping transfer taxes). That request was contained in a letter dated November 19, 1985, from Ronald A. Pearlman, the Assistant Secretary (Tax Policy), to Hugh Calkins, then Section Chair.\u27 After receiving individual comment papers on the subject from members of the Section\u27s Committee on Estate and Gift Taxes, Mr. Calkins, on April 14, 1986, created this Task Force and asked it to prepare a more fundamental response

    HD 24355 observed by the Kepler K2 mission: a rapidly oscillating Ap star pulsating in a distorted quadrupole mode

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    We present an analysis of the first Kepler K2 mission observations of a rapidly oscillating Ap (roAp) star, HD 24355 (V = 9.65). The star was discovered in SuperWASP broad-band photometry with a frequency of 224.31 d−1 (2596.18 μHz; P = 6.4 min) and an amplitude of 1.51 mmag, with later spectroscopic analysis of low-resolution spectra showing HD 24355 to be an A5 Vp SrEu star. The high-precision K2 data allow us to identify 13 rotationally split sidelobes to the main pulsation frequency of HD 24355. This number of sidelobes combined with an unusual rotational phase variation show this star to be the most distorted quadrupole roAp pulsator yet observed. In modelling this star, we are able to reproduce well the amplitude modulation of the pulsation, and find a close match to the unusual phase variations. We show this star to have a pulsation frequency higher than the critical cut-off frequency. This is currently the only roAp star observed with the Kepler spacecraft in short cadence mode that has a photometric amplitude detectable from the ground, thus allowing comparison between the mmag amplitude ground-based targets and the μmag spaced-based discoveries. No further pulsation modes are identified in the K2 data, showing this star to be a single-mode pulsator

    Universal Fluctuations of the Danube Water Level: a Link with Turbulence, Criticality and Company Growth

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    A global quantity, regardless of its precise nature, will often fluctuate according to a Gaussian limit distribution. However, in highly correlated systems, other limit distributions are possible. We have previously calculated one such distribution and have argued that this function should apply specifically, and in many instances, to global quantities that define a steady state. Here we demonstrate, for the first time, the relevance of this prediction to natural phenomena. The river level fluctuations of the Danube are observed to obey our prediction, which immediately establishes a generic statistical connection between turbulence, criticality and company growth statistics.Comment: 5 pages, 1 figur
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