Recent advances in low oxidation state aluminium chemistry

Documenting the synthesis and isolation of novel low oxidation state aluminium (Al) compounds, which until recently has seen relatively slow progress over the 30 years since such species were first isolated

Aluminum Amidinates: Insights into Alkyne Hydroboration.

The mechanism of the aluminum-mediated hydroboration of terminal alkynes was investigated using a series of novel aluminum amidinate hydride and alkyl complexes bearing symmetric and asymmetric ligands. The new aluminum complexes were fully characterized and found to facilitate the formation of the (E)-vinylboronate hydroboration product, with rates and orders of reaction linked to complex size and stability. Kinetic analysis and stoichiometric reactions were used to elucidate the mechanism, which we propose to proceed via the initial formation of an Al-borane adduct. Additionally, the most unstable complex was found to promote decomposition of the pinacolborane substrate to borane (BH3), which can then proceed to catalyze the reaction. This mechanism is in contrast to previously reported aluminum hydride-catalyzed hydroboration reactions, which are proposed to proceed via the initial formation of an aluminum acetylide, or by hydroalumination to form a vinylboronate ester as the first step in the catalytic cycle

Detection of Cosmic Microwave Background Structure in a Second Field with the Cosmic Anisotropy Telescope

We describe observations at frequencies near 15 GHz of the second 2x2 degree field imaged with the Cambridge Cosmic Anisotropy Telescope (CAT). After the removal of discrete radio sources, structure is detected in the images on characteristic scales of about half a degree, corresponding to spherical harmonic multipoles in the approximate range l= 330--680. A Bayesian analysis confirms that the signal arises predominantly from the cosmic microwave background (CMB) radiation for multipoles in the lower half of this range; the average broad-band power in a bin with centroid l=422 (theta = 51') is estimated to be Delta_T/T=2.1^{+0.4}_{-0.5} x 10^{-5}. For multipoles centred on l=615 (theta =35'), we find contamination from Galactic emission is significant, and constrain the CMB contribution to the measured power in this bin to be Delta_T/T <2.0 x 10^{-5} (1-sigma upper limit). These new results are consistent with the first detection made by CAT in a completely different area of sky. Together with data from other experiments, this new CAT detection adds weight to earlier evidence from CAT for a downturn in the CMB power spectrum on scales smaller than 1 degree. Improved limits on the values of H_0 and Omega are determined using the new CAT data.Comment: 5 pages, 5 figures (gif), submitted to MNRA

Trust and Risk Relationship Analysis on a Workflow Basis: A Use Case

Trust and risk are often seen in proportion to each other; as such, high trust may induce low risk and vice versa. However, recent research argues that trust and risk relationship is implicit rather than proportional. Considering that trust and risk are implicit, this paper proposes for the first time a novel approach to view trust and risk on a basis of a W3C PROV provenance data model applied in a healthcare domain. We argue that high trust in healthcare domain can be placed in data despite of its high risk, and low trust data can have low risk depending on data quality attributes and its provenance. This is demonstrated by our trust and risk models applied to the BII case study data. The proposed theoretical approach first calculates risk values at each workflow step considering PROV concepts and second, aggregates the final risk score for the whole provenance chain. Different from risk model, trust of a workflow is derived by applying DS/AHP method. The results prove our assumption that trust and risk relationship is implicit

Cerclage outcome by the type of suture material (COTS): study protocol for a pilot and feasibility randomised controlled trial

BACKGROUND: Cervical incompetence is one of the causes of preterm birth and mid-trimester pregnancy loss. Cervical cerclage is a surgical procedure to treat cervical incompetence. Cervical cerclage reduces the incidence of preterm birth in women at risk of recurrent preterm birth, without a statistically significant reduction in perinatal mortality or neonatal morbidity. Multifilament/braided sutures such as Mersilene tape have been traditionally used for cervical cerclage. Braided sutures, particularly mesh-like non-absorbable sutures, have been associated with an increased risk of infection and, hence, some obstetricians prefer to use monofilament/non-braided sutures. However, these claims are not substantiated by any scientific or clinical evidence. We propose a pilot/feasibility study which will provide the necessary information for planning a definitive trial investigating the clinical effectiveness of monofilament non-braided suture materials in reducing pregnancy loss rate following cervical cerclage compared to the traditional multifilament braided sutures. METHODS/DESIGN: Women eligible for elective or ultrasound-indicated cerclage at 12 to 21 + 6 weeks of gestation will be randomised to having the procedure using either a monofilament non-braided suture (Ethilon) or a Multifilament braided suture (Mersilene tape) inserted using a McDonald technique. Consent for participation in the Cerclage outcome by the type of suture (COTS) study will be obtained from each eligible participant. CLINICAL TRIALS REGISTRATION: COTS is registered with the International Standard Research for Clinical Trials (ISRCTN17866773). Registered on 27 March 2013

Dust Attenuation in Late-Type Galaxies. I. Effects on Bulge and Disk Components

We present results of new Monte Carlo calculations made with the DIRTY code of radiative transfer of stellar and scattered radiation for a dusty giant late-type galaxy like the Milky Way, which illustrate the effect of the attenuation of stellar light by internal dust on the integrated photometry of the individual bulge and disk components. Here we focus on the behavior of the attenuation function, the color excess, and the fraction of light scattered or directly transmitted towards the outside observer as a function of the total amount of dust and the inclination of the galaxy, and the structure of the dusty interstellar medium (ISM) of the disk. We confirm that dust attenuation produces qualitatively and quantitatively different effects on the integrated photometry of bulge and disk, whatever the wavelength. In addition, we find that the structure of the dusty ISM affects more sensitively the observed magnitudes than the observed colors of both bulge and disk. Finally, we show that the contribution of the scattered radiation to the total monochromatic light received by the outside observer is significant, particularly at UV wavelengths, even for a two-phase, clumpy, dusty ISM. Thus understanding dust scattering properties is fundamental for the interpretation of extragalactic observations in the rest-frame UV.Comment: 62 pages, 28 eps-figures, 1 table, accepted for publication in ApJ Main Journa

A spectral method for elliptic equations: the Dirichlet problem

An elliptic partial differential equation Lu=f with a zero Dirichlet boundary condition is converted to an equivalent elliptic equation on the unit ball. A spectral Galerkin method is applied to the reformulated problem, using multivariate polynomials as the approximants. For a smooth boundary and smooth problem parameter functions, the method is proven to converge faster than any power of 1/n with n the degree of the approximate Galerkin solution. Examples in two and three variables are given as numerical illustrations. Empirically, the condition number of the associated linear system increases like O(N), with N the order of the linear system.Comment: This is latex with the standard article style, produced using Scientific Workplace in a portable format. The paper is 22 pages in length with 8 figure

MHD Turbulence as a Foreground for CMB Studies

Measurements of intensity and polarization of diffuse Galactic synchrotron emission as well as starlight polarization reveal power law spectra of fluctuations. We show that these fluctuations can arise from magnetohydrodynamic (MHD) turbulence in the Galactic disk and halo. To do so we take into account the converging geometry of lines of sight for the observations when the observer is within the turbulent volume. Assuming that the intensity of turbulence changes along the line of sight, we get a reasonable fit to the observed synchrotron data. As for the spectra of polarized starlight we get a good fit to the observations taking into account the fact that the observational sample is biased toward nearby stars.Comment: 10 pages, 6 figures, Astrophyscal J., submitte