Designed supramolecular assemblies for biosensors and photoactive devices. LDRD final report

The objective of this project is the development of a new class of supramolecular assemblies for applications in biosensors and biodevices. The supramolecular assemblies are based on membranes and Langmuir-Blodgett (LB) films composed of naturally-occurring or synthetic lipids, which contain electrically and/or photochemically active components. The LB films are deposited onto electrically-active materials (metal, semiconductors). The active components film components (lipo-porphyrins) at the surface function as molecular recognition sites for sensing proteins and other biomolecules, and the porphyrins and other components (e.g., fullerenes) incorporated into the films serve as photocatalysts and vectorial electron-transport agents. Computer-aided molecular design (CAMD) methods are used to tailor the structure of these film components to optimize function. Molecular modeling is also used to predict the location, orientation, and motion of these molecular components within the films. The result is a variety of extended, self-assembled molecular structures that serve as devices for sensing proteins and biochemicals or as other bioelectronic devices

Influence of enhanced melt supply on upper crustal structure at a mid-ocean ridge discontinuity: A three-dimensional seismic tomographic study of 9°N East Pacific Rise

We present a three-dimensional upper crustal model of the 9°03′N overlapping spreading center (OSC) on the East Pacific Rise that assists in understanding the relationship between melt sills and upper crustal structure at a ridge discontinuity with enhanced melt supply at crustal levels. Our P wave velocity model obtained from tomographic inversion of ∼70,000 crustal first arrival travel times suggests that the geometry of extrusive emplacement are significantly different beneath the overlapping spreading limbs. Extrusive volcanic rocks above the western melt sill are inferred to be thin (∼250 m). More extensive accumulation of extrusives is inferred to the west than to the east of the western melt sill. The extrusive layer inferred above the eastern melt sill thickens from ∼350 (at the neovolcanic axis) to 550 m (to the west of the melt sill). Volcanic construction is likely to be significant in the formation of ridge crest morphology at the OSC, particularly at the tip of the eastern limb. On the basis of our interpretation of the velocity model, we propose that enhanced magma supply at crustal levels at the OSC may provide an effective mechanism for the migration of ridge discontinuities. This “dynamic magma supply model” may explain the commonly observed nonsteady migration pattern of ridge discontinuities by attributing this to the temporal fluctuations in melt availability to the overlapping spreading limbs

The Appearance and Disappearance of Ship Tracks on Large Spatial Scales

The 1-km advanced very high resolution radiometer observations from the morning, NOAA-12, and afternoon, NOAA-11, satellite passes over the coast of California during June 1994 are used to determine the altitudes, visible optical depths, and cloud droplet effective radii for low-level clouds. Comparisons are made between the properties of clouds within 50 km of ship tracks and those farther than 200 km from the tracks in order to deduce the conditions that are conducive to the appearance of ship tracks in satellite images. The results indicate that the low-level clouds must be sufficiently close to the surface for ship tracks to form. Ship tracks rarely appear in low-level clouds having altitudes greater than 1 km. The distributions of visible optical depths and cloud droplet effective radii for ambient clouds in which ship tracks are embedded are the same as those for clouds without ship tracks. Cloud droplet sizes and liquid water paths for low-level clouds do not constrain the appearance of ship tracks in the imagery. The sensitivity of ship tracks to cloud altitude appears to explain why the majority of ship tracks observed from satellites off the coast of California are found south of 358N. A small rise in the height of low-level clouds appears to explain why numerous ship tracks appeared on one day in a particular region but disappeared on the next, even though the altitudes of the low-level clouds were generally less than 1 km and the cloud cover was the same for both days. In addition, ship tracks are frequent when lowlevel clouds at altitudes below 1 km are extensive and completely cover large areas. The frequency of imagery pixels overcast by clouds with altitudes below 1 km is greater in the morning than in the afternoon and explains why more ship tracks are observed in the morning than in the afternoon. If the occurrence of ship tracks in satellite imagery data depends on the coupling of the clouds to the underlying boundary layer, then cloud-top altitude and the area of complete cloud cover by low-level clouds may be useful indices for this coupling.This work was supported in part by the Office of Naval Research and by the National Science Foundation through the Center for Clouds, Chemistry and Climate at the Scripps Institution of Oceanography, an NSF Science and Technology Center

Itinerant ferromagnetism in half-metallic CoS_2

We have investigated electronic and magnetic properties of the pyrite-type CoS_2 using the linearized muffin-tin orbital (LMTO) band method. We have obtained the ferromagnetic ground state with nearly half-metallic nature. The half-metallic stability is studied by using the fixed spin moment method. The non-negligible orbital magnetic moment of Co 3d electrons is obtained as $\mu_L = 0.06 \mu_B$ in the local spin density approximation (LSDA). The calculated ratio of the orbital to spin angular momenta / = 0.15 is consistent with experiment. The effect of the Coulomb correlation between Co 3d electrons is also explored with the LSDA + U method. The Coulomb correlation at Co sites is not so large, $U \lesssim 1$ eV, and so CoS_2 is possibly categorized as an itinerant ferromagnet. It is found that the observed electronic and magnetic behaviors of CoS_2 can be described better by the LSDA than by the LSDA + U.Comment: 4 pages, 3 postscript figure

Isolation predicts compositional change after discrete disturbances in a global meta-study

Globally, anthropogenic disturbances are occurring at unprecedented rates and over extensive spatial and temporal scales. Human activities also affect natural disturbances, prompting shifts in their timing and intensities. Thus, there is an urgent need to understand and predict the response of ecosystems to disturbance. In this study, we investigated whether there are general determinants of community response to disturbance across different community types, locations, and disturbance events. We compiled 14 case studies of community response to disturbance from four continents, twelve aquatic and terrestrial ecosystem types, and eight different types of disturbance. We used community compositional differences and species richness to indicate community response. We used mixed-effects modeling to test the relationship between each of these response metrics and four potential explanatory factors: regional species pool size, isolation, number of generations passed, and relative disturbance intensity. We found that compositional similarity was higher between pre- and post-disturbance communities when the disturbed community was connected to adjacent undisturbed habitat. The number of generations that had passed since the disturbance event was a significant, but weak, predictor of community compositional change; two communities were responsible for the observed relationship. We found no significant relationships between the factors we tested and changes in species richness. To our knowledge, this is the first attempt to search for general drivers of community resilience from a diverse set of case studies. The strength of the relationship between compositional change and isolation suggests that it may be informative in resilience research and biodiversity management

The long and the short of it: Mechanisms of synchronous and compensatory dynamics across temporal scales

Synchronous dynamics (fluctuations that occur in unison) are universal phenomena with widespread implications for ecological stability. Synchronous dynamics can amplify the destabilizing effect of environmental variability on ecosystem functions such as productivity, whereas the inverse, compensatory dynamics, can stabilize function. Here we combine simulation and empirical analyses to elucidate mechanisms that underlie patterns of synchronous versus compensatory dynamics. In both simulated and empirical communities, we show that synchronous and compensatory dynamics are not mutually exclusive but instead can vary by timescale. Our simulations identify multiple mechanisms that can generate timescale-specific patterns, including different environmental drivers, diverse life histories, dispersal, and non-stationary dynamics. We find that traditional metrics for quantifying synchronous dynamics are often biased toward long-term drivers and may miss the importance of short-term drivers. Our findings indicate key mechanisms to consider when assessing synchronous versus compensatory dynamics and our approach provides a pathway for disentangling these dynamics in natural systems

Neutron Star Superfluidity, Dynamics and Precession

Basic rotational and magnetic properties of neutron superfluids and proton superconductors in neutron stars are reviewed. The modes of precession of the neutron superfluid are discussed in detail. We emphasize that at finite temperature, pinning of superfluid vortices does not offer any constraint on the precession. Any pinning energies can be surmounted by thermal activation and there exists a dynamical steady state in which the superfluid follows the precession of the crust at a small lag angle between the crust and superfluid rotation velocity vectors. At this small lag the system is far from the critical conditions for unpinning, even if the observed precession of the crust may entail a large angle between the figure axis and the crust's rotation velocity vector. We conclude that if long period modulations of pulse arrival times and pulse shapes observed in a pulsar like the PSR B1828-11 are due to the precession of the neutron star, this does not have any binding implications about the existence of pinning by flux lines or the existence of Type II superconductivity in the neutron star.Comment: 21 pages, one figure, to appear in the Proceedings of the NATO-ASI "The Electromagnetic Spectrum of Neutron Stars" held in Marmaris, Turkey, June 2004, eds. A. Baykal, S.K. Yerli, C. Inam and S. Grebene

A novel length back-calculation approach accounting for ontogenetic changes in the fish length – otolith size relationship during the early life of sprat (Sprattus sprattus)

(Sprattus sprattus), accounting for ontogenetic changes in the relationship between fish length and otolith length. In sprat, metamorphosis from larvae to juveniles is characterized by the coincidence of low length growth, strong growth in body height, and maximal otolith growth. Consequently, the method identifies a point of metamorphosis for an individual as the otolith radius at maximum increment widths. By incorporating this information in our back-calculation method, estimated length growth for the early larval stage was more than 60% higher compared with the result of the biological intercept model. After minimal length growth during metamorphosis, we found the highest increase in length during the early juvenile stage. We thus located the strongest growth potential in the early juvenile stage, which is supposed to be critical in determining recruitment strength in Baltic sprat

A dynamical model of lipoprotein metabolism

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