The random phase approximation applied to ice

Standard density functionals without van der Waals interactions yield an unsatisfactory description of ice phases, specifically, high density phases occurring under pressure are too unstable compared to the common low density phase I$_h$ observed at ambient conditions. Although the description is improved by using functionals that include van der Waals interactions, the errors in relative volumes remain sizable. Here we assess the random phase approximation (RPA) for the correlation energy and compare our results to experimental data as well as diffusion Monte Carlo data for ice. The RPA yields a very balanced description for all considered phases, approaching the accuracy of diffusion Monte Carlo in relative energies and volumes. This opens a route towards a concise description of molecular water phases on surfaces and in cavities

Cohesion of BaReH9_9 and BaMnH9_9: Density Functional Calculations and Prediction of (MnH9)2−_9)^{2-} Salts

Density functional calculations are used to calculate the structural and electronic properties of BaReH$_9$ and to analyze the bonding in this compound. The high coordination in BaReH$_9$ is due to bonding between Re 5$d$ states and states of $d$-like symmetry formed from combinations of H $s$ orbitals in the H$_9$ cage. This explains the structure of the material, its short bond lengths and other physical properties, such as the high band gap. We compare with results for hypothetical BaMnH$_9$, which we find to have similar bonding and cohesion to the Re compound. This suggests that it may be possible to synthesize (MnH$_9)^{2-}$ salts. Depending on the particular cation, such salts may have exceptionally high hydrogen contents, in excess of 10 weight

Radio observations of two intermittent pulsars: PSRs J1832+0029 and J1841-0500

We present long-term observations of two intermittent pulsars, PSRs~J1832+0029 and J1841$-$0500 using the Parkes 64\,m radio telescope. The radio emission for these pulsars switches "off" for year-long durations. Our new observations have enabled us to improve the determination of the on-off timescales and the spin down rates during those emission states. In general our results agree with previous studies of these pulsars, but we now have significantly longer data spans. We have identified two unexpected signatures in the data. Weak emission was detected in a single observation of PSR~J1832$+$0029 during an "off" emission state. For PSR~J1841$-$0500, we identified a quasi-periodic fluctuation in the intensities of the detectable single pulses, with a modulation period between 21 and 36 pulse periods.Comment: 7 pages, 7 figures, accepted for publication in Ap

PSR J1016-5857: a young radio pulsar with possible supernova remnant, X-ray, and gamma-ray associations

We report the discovery of a young and energetic pulsar in the Parkes multibeam survey of the Galactic plane. PSR J1016-5857 has a rotation period of 107 ms and period derivative of 8e-14, implying a characteristic age of 21 kyr and spin-down luminosity of 2.6e36 erg/s. The pulsar is located just outside, and possibly interacting with, the shell supernova remnant G284.3-1.8. Archival X-ray data show a source near the pulsar position which is consistent with emission from a pulsar wind nebula. The pulsar is also located inside the error box of the unidentified EGRET source 3EG J1013-5915, for which it represents a plausible counterpart.Comment: 5 pages, 3 included figures, accepted for publication by ApJ Letter

Interaction of quasilocal harmonic modes and boson peak in glasses

The direct proportionality relation between the boson peak maximum in glasses, $\omega_b$, and the Ioffe-Regel crossover frequency for phonons, $\omega_d$, is established. For several investigated materials $\omega_b = (1.5\pm 0.1)\omega_d$. At the frequency $\omega_d$ the mean free path of the phonons $l$ becomes equal to their wavelength because of strong resonant scattering on quasilocal harmonic oscillators. Above this frequency phonons cease to exist. We prove that the established correlation between $\omega_b$ and $\omega_d$ holds in the general case and is a direct consequence of bilinear coupling of quasilocal oscillators with the strain field.Comment: RevTex, 4 pages, 1 figur

Observations of radio pulses from CU Virginis

The magnetic chemically peculiar star CU Virginis is a unique astrophysical laboratory for stellar magnetospheres and coherent emission processes. It is the only known main sequence star to emit a radio pulse every rotation period. Here we report on new observations of the CU Virginis pulse profile in the 13 and 20\,cm radio bands. The profile is known to be characterised by two peaks of 100$\%$ circularly polarised emission that are thought to arise in an electron-cyclotron maser mechanism. We find that the trailing peak is stable at both 13 and 20\,cm, whereas the leading peak is intermittent at 13\,cm. Our measured pulse arrival times confirm the discrepancy previously reported between the putative stellar rotation rates measured with optical data and with radio observations. We suggest that this period discrepancy might be caused by an unknown companion or by instabilities in the emission region. Regular long-term pulse timing and simultaneous multi-wavelength observations are essential to clarify the behaviour of this emerging class of transient radio source.Comment: Accepted by MNRAS Letters; 5 pages, 2 figures, 3 table

Abrupt grain boundary melting in ice

The effect of impurities on the grain boundary melting of ice is investigated through an extension of Derjaguin-Landau-Verwey-Overbeek theory, in which we include retarded potential effects in a calculation of the full frequency dependent van der Waals and Coulombic interactions within a grain boundary. At high dopant concentrations the classical solutal effect dominates the melting behavior. However, depending on the amount of impurity and the surface charge density, as temperature decreases, the attractive tail of the dispersion force interaction begins to compete effectively with the repulsive screened Coulomb interaction. This leads to a film-thickness/temperature curve that changes depending on the relative strengths of these interactions and exhibits a decrease in the film thickness with increasing impurity level. More striking is the fact that at very large film thicknesses, the repulsive Coulomb interaction can be effectively screened leading to an abrupt reduction to zero film thickness.Comment: 8 pages, 1 figur

Detecting the stochastic gravitational wave background using pulsar timing

The direct detection of gravitational waves is a major goal of current astrophysics. We provide details of a new method for detecting a stochastic background of gravitational waves using pulsar timing data. Our results show that regular timing observations of 40 pulsars each with a timing accuracy of 100 nano-seconds will be able to make a direct detection of the predicted stochastic background from coalescing black holes within five years. With an improved pre-whitening algorithm, or if the background is at the upper end of the predicted range, a significant detection should be possible with only 20 pulsars.Comment: Accepted by ApJ Letter

Lithium-6: A Probe of the Early Universe

I consider the synthesis of 6Li due to the decay of relic particles, such as gravitinos or moduli, after the epoch of Big Bang Nucleosynthesis. The synthesized 6Li/H ratio may be compared to 6Li/H in metal-poor stars which, in the absence of stellar depletion of 6Li, yields significantly stronger constraints on relic particle densities than the usual consideration of overproduction of 3He. Production of 6Li during such an era of non-thermal nucleosynthesis may also be regarded as a possible explanation for the relatively high 6Li/H ratios observed in metal-poor halo stars.Comment: final version, Physical Review Letters, additional figure giving limits on relic decaying particle