Effect of processing parameters on the morphology development during extrusion of polyethylene tape: an in-line Small-Angle X-ray Scattering (SAXS) study

The in-line development of crystalline morphology and orientation during melt extrusion of low density polyethylene (LDPE) tape at nil and low haul-off speeds has been investigated using Small-Angle X-Ray Scattering (SAXS). The processing parameters, namely haul-off speed and distance down the tape-line have been varied and the resulting crystalline morphology is described from detailed analysis of the SAXS data. Increasing haul-off speed increased orientation in the polymer tape and the resulting morphology could be described in terms of regular lamellar stacking perpendicular to the elongation direction. In contrast, under nil haul-off conditions the tape still showed some orientation down the tape-line, but a shish-kebab structure prevails. The final lamellae thickness (~50 Å) and bulk crystallinity (~20%), were low for all processing conditions investigated, which is attributed to the significant short-chain branching in the polymer acting as point defects limiting lamellae crystal growth

Isospecific Polymerization of Racemic Epoxides: a Catalyst System for the Synthesis of Highly Isotactic Polyethers

A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers.We acknowledge the NSF (CHE-0809778) and the King Abdullah University of Science and Technology (KAUST; Award No. KUS-C1-018-02) for support of this research. The authors are grateful for the help of T. Mourey at Kodak for polymer molecular weight determinatio