L-band, 1.2 m parabolic antenna-noise temperature measurement

Extensive antenna-noise temperature measurements at 1.6 GHz (L-band) were made using a 1.2 m (4 ft. diameter) parabolic dish antenna mounted on the flying bridge of a modern 15,690-ton, commercial-container ship. Both in-harbor and at-sea radiometer measurements were made that indicated a steady background, antenna-noise temperature value slightly less than 70 degrees Kelvin (K) at elevation angles of 5 percent, and greater, at 1.6 GHz. A comparison of theoretical and measured values indicate excellent agreement within about 5K for at-sea data. These measurements are helpful to RF equipment designers of maritime, L-band shipboard terminals for operation with the two, geostationary, maritime satellites, Marisat-A and -B

Aircraft measurement of radio frequency noise at 121.5 MHz, 243 MHz and 406 MHz

An airborne survey measurement of terrestrial radio-frequency noise over U.S. metropolitan areas was carried out at 121.5, 243 and 406 MHz with horizontal-polarization monopole antennas. Flights were at 25,000 feet altitude. Radio-noise measurements, expressed in equivalent antenna-noise temperature, indicate a steady-background noise temperature of 572,000 K, at 121.5 MHz, during daylight over New York City. This data is helpful in compiling radio-noise temperature maps; in turn useful for designing satellite-aided, emergency-distress search and rescue communication systems

Airborne urban/suburban noise measurements at 121.5/243 MHz

An airborne measurement of the terrestrial, radio-frequency (RF) noise environment over U.S. metropolitan urban/suburban areas has been made at the 121.5/243 MHz emergency-distress search and rescue (S&R) communications frequencies. Profile contour plots of antenna-noise temperature for U.S.A. East Coast and mid-west urban/suburban areas is presented for daytime/nighttime observations at 121.5/243 MHz. These plots are helpful for compiling radio-noise environment maps; in turn useful for designing satellite-aided, emergency-distress search and rescue communication systems

Dispersion of biased swimming microorganisms in a fluid flowing through a tube

Classical Taylor-Aris dispersion theory is extended to describe the transport of suspensions of self-propelled dipolar cells in a tubular flow. General expressions for the mean drift and effective diffusivity are determined exactly in terms of axial moments, and compared with an approximation a la Taylor. As in the Taylor-Aris case, the skewness of a finite distribution of biased swimming cells vanishes at long times. The general expressions can be applied to particular models of swimming microorganisms, and thus be used to predict swimming drift and diffusion in tubular bioreactors, and to elucidate competing unbounded swimming drift and diffusion descriptions. Here, specific examples are presented for gyrotactic swimming algae.Comment: 20 pages, 4 figures. Published version available at http://rspa.royalsocietypublishing.org/content/early/2010/02/09/rspa.2009.0606.short?rss=

CO2 reduction with protons and electrons at a boron-based reaction center.

Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparation of borohydrides starting from alkali metals precludes large scale implementation of these latter uses. One potential solution to this issue is the direct synthesis of borohydrides from the protonation of reduced boron compounds. We herein report reactions of the redox series [Au(B2P2)] n (n = +1, 0, -1) (B2P2, 9,10-bis(2-(diisopropylphosphino)phenyl)-9,10-dihydroboranthrene) and their conversion into corresponding mono- and diborohydride complexes. Crucially, the monoborohydride can be accessed via protonation of [Au(B2P2)]-, a masked borane dianion equivalent accessible at relatively mild potentials (-2.05 V vs. Fc/Fc+). This species reduces CO2 to produce the corresponding formate complex. Cleavage of the formate complex can be achieved by reduction (ca. -1.7 V vs. Fc/Fc+) or by the addition of electrophiles including H+. Additionally, direct reaction of [Au(B2P2)]- with CO2 results in reductive disproportion to release CO and generate a carbonate complex. Together, these reactions constitute a synthetic cycle for CO2 reduction at a boron-based reaction center that proceeds through a B-H unit generated via protonation of a reduced borane with weak organic acids

Methods for evaluating the performance of volume phase holographic gratings for the VIRUS spectrograph array

The Visible Integral Field Replicable Unit Spectrograph (VIRUS) is an array of at least 150 copies of a simple, fiber-fed integral field spectrograph that will be deployed on the Hobby-Eberly Telescope (HET) to carry out the HET Dark Energy Experiment (HETDEX). Each spectrograph contains a volume phase holographic grating as its dispersing element that is used in first order for 350 nm to 550 nm. We discuss the test methods used to evaluate the performance of the prototype gratings, which have aided in modifying the fabrication prescription for achieving the specified batch diffraction efficiency required for HETDEX. In particular, we discuss tests in which we measure the diffraction efficiency at the nominal grating angle of incidence in VIRUS for all orders accessible to our test bench that are allowed by the grating equation. For select gratings, these tests have allowed us to account for > 90% of the incident light for wavelengths within the spectral coverage of VIRUS. The remaining light that is unaccounted for is likely being diffracted into reflective orders or being absorbed or scattered within the grating layer (for bluer wavelengths especially, the latter term may dominate the others). Finally, we discuss an apparatus that will be used to quickly verify the first order diffraction efficiency specification for the batch of at least 150 VIRUS production gratings.Comment: 18 pages, 11 figures. To be published in Proc. SPIE, 2012, "Ground-Based and Airborne Instrumentation for Astronomy IV", 8446-20

Atomic spectrometry update. Clinical and biological materials, foods and beverages

This review discusses developments in elemental mass spectrometry, atomic absorption, emission and fluorescence, XRF and LIBS, as applied to the analysis of specimens of clinical interest, foods and beverages. Sample preparation procedures and quality assurance are also included.</p