9,306 research outputs found

    The effect of tip shields on a horizontal tail surface

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    A series of experiments made in the wind tunnel of the Daniel Guggenheim School of Aeronautics, New York University, on the effect of tip shields on a horizontal tail surface are described and discussed. It was found that some aerodynamic gain can be obtained by the use of tip shields though it is considered doubtful whether their use would be practical

    Ultrafast dynamics in the presence of antiferromagnetic correlations in electron-doped cuprate La2−x_{2-x}Cex_xCuO4±δ_{4\pm\delta}

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    We used femtosecond optical pump-probe spectroscopy to study the photoinduced change in reflectivity of thin films of the electron-doped cuprate La2−x_{2-x}Cex_xCuO4_4 (LCCO) with dopings of x==0.08 (underdoped) and x==0.11 (optimally doped). Above Tc_c, we observe fluence-dependent relaxation rates which onset at a similar temperature that transport measurements first see signatures of antiferromagnetic correlations. Upon suppressing superconductivity with a magnetic field, it is found that the fluence and temperature dependence of relaxation rates is consistent with bimolecular recombination of electrons and holes across a gap (2ΔAF\Delta_{AF}) originating from antiferromagnetic correlations which comprise the pseudogap in electron-doped cuprates. This can be used to learn about coupling between electrons and high-energy (ω>2ΔAF\omega>2\Delta_{AF}) excitations in these compounds and set limits on the timescales on which antiferromagnetic correlations are static

    Mesophase formation in two-component cylindrical bottle-brush polymers

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    When two types of side chains (A,B) are densely grafted to a (stiff) backbone and the resulting bottle-brush polymer is in a solution under poor solvent conditions, an incompatibility between A and B leads to microphase separation in the resulting cylindrical brush. The possible types of ordering are reminiscent of the ordering of block copolymers in cylindrical confinement. Starting from this analogy, Leibler's theory of microphase separation in block copolymer melts is generalized to derive a description of the system in the weak segregation limit. Also molecular dynamics simulation results of a corresponding coarse-grained bead-spring model are presented. Using side chain lengths up to N = 50 effective monomers, the ratio of the Lennard-Jones energy parameter between unlike monomers (ϵAB)(\epsilon_{AB}) and monomers of the same kind (ϵAA=ϵBB)(\epsilon _{AA} = \epsilon_{BB}) is varied. Various correlation functions are analyzed to study the conditions when (local) Janus cylinder-type ordering and when (local) microphase separation in the direction along the cylinder axis occurs. Both the analytical theory and the simulations give evidence for short range order due to a tendency towards microphase separation in the axial direction, with a wavelength proportional to the side chain gyration radius, irrespective of temperature and grafting density, for a wide range of these parameters.Comment: 26 pages, 19 figure

    A simplified picture for Pi electrons in conjugated polymers : from PPP Hamiltonian to an effective molecular crystal approach

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    An excitonic method proper to study conjugated oligomers and polymers is described and its applicability tested on the ground state and first excited states of trans-polyacetylene, taken as a model. From the Pariser-Parr-Pople Hamiltonian, we derive an effective Hamiltonian based on a local description of the polymer in term of monomers; the relevant electronic configurations are build on a small number of pertinent local excitations. The intuitive and simple microscopic physical picture given by our model supplement recent results, such as the Rice and Garstein ones. Depending of the parameters, the linear absorption appears dominated by an intense excitonic peak.Comment: 41 Pages, 6 postscript figure

    Understanding how new evidence influences practitioners' beliefs regarding dry cow therapy: A Bayesian approach using probabilistic elicitation.

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    This study used probabilistic elicitation and a Bayesian framework to quantitatively explore how logically practitioners' update their clinical beliefs after exposure to new data. The clinical context was the efficacy of antibiotics versus teat sealants for preventing mammary infections during the dry period. While most practitioners updated their clinical expectations logically, the majority failed to draw sufficient strength from the new data so that their clinical confidence afterwards was lower than merited. This study provides quantitative insight into how practitioners' update their beliefs. We discuss some of the psychological issues that may be faced by practitioners when interpreting new data. The results have important implications for evidence-based practice and clinical research in terms of the impact that new data may bring to the clinical community

    Slow plasmon modes in polymeric salt solutions

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    The dynamics of polymeric salt solutions are presented. The salt consists of chains A\rm A and B\rm B, which are chemically different and interact with a Flory-interaction parameter χ\chi, the A\rm A chain ends carry a positive charge whereas the B\rm B chain ends are modified by negative charges. The static structure factor shows a peak corresponding to a micro phase separation. At low momentum transfer, the interdiffusion mode is driven by electrostatics and is of the plasmon-type, but with an unusually low frequency, easily accessible by experiments. This is due to the polymer connectivity that introduces high friction and amplifies the charge scattering thus allowing for low charge densities. The interdiffusion mode shows a minimum (critical slowing down) at finite kk when the interaction parameter increases we find then a low kk frequency quasi-plateau.Comment: accepted in Europhys. Let

    XY checkerboard antiferromagnet in external field

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    Ordering by thermal fluctuations is studied for the classical XY antiferromagnet on a checkerboard lattice in zero and finite magnetic fields by means of analytical and Monte Carlo methods. The model exhibits a variety of novel broken symmetries including states with nematic ordering in zero field and with triatic order parameter at high fields.Comment: 6 page

    Increased L-ornithine production by an arg mutant of Acinetobacter lwoffi

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    The metabolic production of L-ornithine by an arg mutant of Acinetobacter Iwoffi using n-hexadecane as sole carbon source was studied. Time course experiments under optimised conditions showed that L-ornithine production was growth related, with maximum concentrations (10.5gl-1) accumulating in the late exponential phase of growth
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