Band-Gap Engineering of NaNbO 3

A new visible light response photocatalyst has been developed for H2 evolution from methanol solution by elemental doping. With lanthanum and cobalt dopants, the photoabsorption edge of NaNbO3 was effectively shifted to the visible light region. It is also found that the photoabsorption edge is effectively controlled by the dopant concentration. Under visible light irradiation, H2 was successfully generated over the doped NaNbO3 samples and a rate of 12 μmol·h−1 was achieved over (LaCo)0.03(NaNb)0.97O3. Densityfunctional theory calculations show that Co-induced impurity states are formed in the band gap of NaNbO3 and this is considered to be the origin of visible-light absorption upon doping with La and Co

エイゴ ボイン ノ コクサイ ヒョウジュン ヒョウキ ニツイテ

本稿は、現代英語の主要方言と非母語話者の母音の特徴を取り上げ、内在する音韻構造を論じながら、発音指導における標準表記の可能性を考察する試論である。英語は今や全世界に通用する国際化した言語としての側面と、世界の各地でそれぞれの地域の文化を背負いながら特殊化し自立した英語としての側面を併せ持っていることに鑑み、わが国の英語教育、とりわけ発音指導におけるモデルとしては、主要方言のいずれか一つを規範とするのではなく、英語母音に関わる音韻構造の分析に基づいた標準表記がより妥当であることを提案する。　This article tries to identify what all second language varieties of English already have in common, and to establish the shared component as an International English. This line of inquiry enables us to establish a single phonological system shared by all speakers of English around the world, regardless of whether their English is a first, second, and subsequent language. The vowel system of the international norm is based on a set of 13 vowels, consisting of 5 economically spaced peripheral positions, and 3 true diphthongs

Electrical transport properties of bulk MgB2 materials synthesized by the electrolysis on fused mixtures of MgCl2, NaCl, KCl and MgB2O4

Electrolysis was carried out on fused mixtures of MgCl2, NaCl, KCl and MgB2O4 under an Ar flow at 600C. Electrical resistivity measurements for the grown deposits show an onset of superconducting transition at 37 K in the absence of applied magnetic field. The resistivity decreases down to zero below 32 K. From an applied-field dependence of resistivity, an upper critical field and a coherence length were calculated to be 9.7 T and 5.9 nm at 0 K, respectively

Hydrogen-assisted fabrication of spherical gold nanoparticles through sonochemical reduction of tetrachloride gold(III) ions in water

Spherical gold nanoparticles (AuNPs) were selectively synthesized through sonochemical reduction of tetrachloride gold(III) ions ([AuCl4](-)) in an aqueous solution of hydrogen tetrachloroaurate(III) tetrahydrate (HAuCl4.H2O) with the aid of hydrogen (H-2) gas in the absence of any additional capping agents. On the other hand, various shaped-AuNPs such as spherical nanoparticles, triangular and hexagonal plates were formed from sonochemical reduction of [AuCl4](-) in argon (Ar)-, nitrogen (N-2)- or oxygen (O-2)-purged aqueous [AuCl4](-) solutions. The selective fabrication of spherical AuNPs assisted by H-2 gas is most likely attributed to the generation of hydrogen radicals (H center dot) promoted by the reaction of H-2 introduced and hydrogen oxide radicals (center dot OH) produced by sonolysis of water.ArticleULTRASONICS SONOCHEMISTRY. 21(3):946-950 (2014)journal articl

Void-induced cross slip of screw dislocations in fcc copper

Pinning interaction between a screw dislocation and a void in fcc copper is investigated by means of molecular dynamics simulation. A screw dislocation bows out to undergo depinning on the original glide plane at low temperatures, where the behavior of the depinning stress is consistent with that obtained by a continuum model. If the temperature is higher than 300 K, the motion of a screw dislocation is no longer restricted to a single glide plane due to cross slip on the void surface. Several depinning mechanisms that involve multiple glide planes are found. In particular, a depinning mechanism that produces an intrinsic prismatic loop is found. We show that these complex depinning mechanisms significantly increase the depinning stress

Astrometric Image Centroid Displacements due to Gravitational Microlensing by the Ellis Wormhole

Continuing work initiated in an earlier publication (Abe, ApJ, 725 (2010) 787), we study the gravitational microlensing effects of the Ellis wormhole in the weak-field limit. First, we find a suitable coordinate transformation, such that the lens equation and analytic expressions of the lensed image positions can become much simpler than the previous ones. Second, we prove that two images always appear for the weak-field lens by the Ellis wormhole. By using these analytic results, we discuss astrometric image centroid displacements due to gravitational microlensing by the Ellis wormhole. The astrometric image centroid trajectory by the Ellis wormhole is different from the standard one by a spherical lensing object that is expressed by the Schwarzschild metric. The anomalous shift of the image centroid by the Ellis wormhole lens is smaller than that by the Schwarzschild lens, provided that the impact parameter and the Einstein ring radius are the same. Therefore, the lensed image centroid by the Ellis wormhole moves slower. Such a difference, though it is very small, will be in principle applicable for detecting or constraining the Ellis wormhole by using future high-precision astrometry observations. In particular, the image centroid position gives us an additional information, so that the parameter degeneracy existing in photometric microlensing can be partially broken. The anomalous shift reaches the order of a few micro arcsec. if our galaxy hosts a wormhole with throat radius larger than $10^5$ km. When the source moves tangentially to the Einstein ring for instance, the maximum position shift of the image centroid by the Ellis wormhole is 0.18 normalized by the Einstein ring radius. For the same source trajectory, the maximum difference between the centroid displacement by the Ellis wormhole lens and that by the Schwarzschild one is -0.16 in the units of the Einstein radius.Comment: 29 pages, 6 figures, 2 tables, accepted by Ap

Surfactant- and reducer-free synthesis of gold nanoparticles in aqueous solutions

We report here the surfactant- and reducer-free synthesis of gold nanoparticles from an aqueous hydrogen tetrachloroaurate (III) tetrahydrate (HAuCl(4)center dot 4H(2)O) solution using a high-frequency (950 kHz) ultrasound (in the absence of any stabilizing, capping and reducing agents). In particular, size, shape and stability of gold nanoparticles prepared by the 950 kHz ultrasound irradiation (sonication) for 8 min in the surfactant-free aqueous solutions were examined in terms of AuCl(4)(-) concentration (in the range of 0.01-0.1 mM), additional salts (NaCl, HCl and NaOH) and temperature (in the range of 4-60 degrees C). We found that higher AuCl(4)(-) concentration promoted particle growth (size increase) and plate formation. In addition, the plate formation was enhanced with the addition of NaCl or HCl (but not NaOH). This is most likely due to the AuCl(4)(-) reduction on a certain crystal facets (e.g. (1 1 0) facets) caused by the adsorption of Cl(-) ions on specific crystal facets (e.g. (1 1 1) facets). Furthermore, we revealed that the temperature elevated above 50 degrees C led to the formation of spherical gold nanoparticles with the diameter of 20-60 nm from a 0.1 mM AuCl(4)(-) aqueous solution while triangular plates formed coexisting with spherical nanoparticles below 50 degrees C.ArticleCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS. 347(1-3):18-26 (2009)journal articl