Phenalene-phosphazene complexes: effect of exocyclic charge densities on the cyclotriphosphazene ring system

The synthesis and properties of a new series of 1,9-diamino-substituted phenalene complexes of the cyclotriphosphazene ring system is described. One of the compounds is shown to be amphoteric, and this behavior allows an examination of the response of the phosphazene linkage to variations in exocyclic charge density at the spiro center in a plane perpendicular to the cyclotriphosphazene ring system. ^(31)P NMR spectroscopy indicates that substituent lone pairs with this orientation are not effective in long-range delocalization within the phosphazene linkage (in accord with our theoretical model of spiro delocalization). An X-ray crystal structure of one compound (7) identifies the presence of clathrated molecules of chloroform together with doubly hydrogen-bonded pairs of the phenalene-phosphazene complexes in the lattice. Crystal data for 7 (C_(13)H_8Cl_4N_5P_3•CHCl_3): monoclinic space group P2_1/c, a = 12.401 (4) Å, b = 28.404 (6) Å, c = 12.962 (3) Å, β = 91.76 (2)°, V = 4564 (2) Å^3, Z = 8, R = 0.050 for 4525 reflections

Free Speech: Why the Philosophy Matters

Artykuł jest osobistym spojrzeniem na kulturowe, a zwłaszcza filozoficzne zmagania obrońców wolności słowa i jej wrogów. Przyznając, że wolność słowa była i jest zagrożona zarówno przez prawicowe, jak i lewicowe autorytaryzmy, autor stwierdza, że współczesne zagrożenia pochodzą głównie ze strony postmodernistycznej skrajnej lewicy. Przywołując wielkie postaci obrońców wolności słowa, Galileusza, F. Bacona, J. Locke’a i J. S. Milla, przypomina o znaczeniu tej wolności dla rozwoju wiedzy i postępu społecznego. Pokazuje, że wolność słowa jest nierozerwalnie związana z wolnością myśli i wolnością działania. Powracając do losów wybranych przedstawicieli starożytnej filozofii greckiej, sugeruje, że tam, gdzie kończy się wolność słowa, zaczyna się upadek kultury i społecznej żywotności

Decolouring bloodmeal: Consumption and potential recycling of peracetic acid

A method of deodorizing and decolouring bloodmeal using an equilibrium mixture of peracetic acid, hydrogen peroxide, acetic acid and water has been developed to improve its marketability as a source of protein for bioplastics. The objective of this study was to determine what quantity of peracetic acid is required to give reasonable bleaching of the bloodmeal and determine whether there is potential for the wastewater to be recycled. This was carried out by measuring the quantity of chemical species in the initial equilibrium mixture and the resulting wastewater upon bleaching using volumetric analysis. Bleaching efficacy was determined after exposing 100 g bloodmeal to 1.1, 2.5, 3.6, 4.5 and 5.6 wt% peracetic acid solutions as either 300 g total solution or a constant molar equivalent of 2.2 mmol peracetic acid/g bloodmeal and using a chromameter to measure colour change. Addition of 300 g 5.6 wt% peracetic acid solution resulted in effective bleaching. This represented a ratio of 2.20 mmol peracetic acid/g bloodmeal of which 1.4 mmol peracetic acid/g bloodmeal was consumed (63%). If 300 g 300 g of <2.5 wt% solution is added such that there is still 2.2 mmol peracetic acid/g bloodmeal, bleaching is still insufficient. These results suggest that an excess of peracetic is required for bleaching to occur, and that its concentration is paramount to bleaching efficacy. Due to the excess of peracetic acid used in the bleaching process, there is potential for wastewater recycling to be carried out provided that the wastewater is not diluted

Effect of oxidative treatment on the secondary structure of decoloured bloodmeal

Bloodmeal can be decoloured using peracetic acid resulting in a material with a pale-yellow colour which only needs sodium dodecyl sulphate, water and triethylene glycol to extrude into a semi-transparent bioplastic. Fourier-transform infrared (FTIR) spectroscopy using Synchrotron light was used to investigate the effect of peracetic acid treatment at various concentrations on the spatial distribution of secondary structures within particles of bloodmeal. Oxidation caused aggregation of helical structures into sheets and acetic acid suppressed sheet formation. Decolouring with peracetic acid led to particles with a higher degree of disorder at the outer edges and higher proportions of ordered structures at the core, consistent with the expected diffusion controlled heterogeneous phase decolouring reaction. The degradation of stabilizing intra- and intermolecular interactions and the presence of acetate ions results in increased chain mobility and greater amorphous content in the material, as evidenced by reduction in Tg and greater enthalpy of relaxation with increasing PAA concentration

Assessing Gear Modifications Needed to Optimize Yields in a Heavily Exploited, Multi-Species, Seagrass and Coral Reef Fishery

Effective management is necessary if small-scale fisheries, such as those found in mixed habitats including seagrass and coral reefs, are to continue providing food for many of the poorest communities of the world. Gear-based management, although under represented and under studied, has the potential to be adaptive, address multiple objectives, and be crafted to the socio-economic setting. Management effectiveness in seagrass and coral reef fisheries has generally been evaluated at the scale of the fish community. However, community level indicators can mask species-specific declines that provide significant portions of the fisheries yields and income. Using a unique dataset, containing ten years of species level length frequency catch data from a multi-gear, multi-species seagrass and coral reef fishery in Kenya, we evaluate species specific fishery statuses, compare gear use to gear regulations and estimate the potential needs for further gear restrictions. Despite the high diversity of the fishery, fifteen species represented over 90% of the catch, and only three species represented 60% of the catch. The three most abundant species in the catch, Lethrinus lentjan (Lacepède), Siganus sutor (Valenciennes) and Leptoscarus vaigiensis (Quoy & Gaimard) all showed evidence of growth overfishing. Lethrinus lentjan, with an exploitation rate of 0.82, also shows evidence of recruitment overfishing. Current legal but weakly enforced gear restrictions are capable of protecting a significant portion of the catch up to maturity but optimization of yield will require that the current mesh size be increased from 6.3 to 8.8 and 9.2 cm to increase yields of L. lentjan and S. sutor, respectively. Given the difficulties of enforcing mesh size, we recommend that the economic benefits of these larger mesh sizes be communicated and enforced through co-management. This abstract is also available in Kiswahili (Abstract S1)

Retrodirective transponder feasibility experiment

Test program on feasibility of digital phase measuring subsystem of pulse-coherent retrodirective transponde