Interstellar water chemistry: from laboratory to observations

Water is observed throughout the universe, from diffuse interstellar clouds to protoplanetary disks around young stars, and from comets in our own solar system and exoplanetary atmospheres to galaxies at high redshifts. This review summarizes the spectroscopy and excitation of water in interstellar space as well as the basic chemical processes that form and destroy water under interstellar conditions. Three major routes to water formation are identified: low temperature ion-molecule chemistry, high-temperature neutral-neutral chemistry and gas-ice chemistry. The rate coefficients of several important processes entering the networks are discussed in detail; several of them have been determined only in the last decade through laboratory experiments and theoretical calculations. Astronomical examples of each of the different chemical routes are presented using data from powerful new telescopes, in particular the Herschel Space Observatory. Basic chemical physics studies remain critically important to analyze astronomical data.Comment: Authors' manuscript 138 pages, 34 figures, 4 tables, published in a Thematic Issue "Astrochemistry" in Chemical Reviews (December 2013), volume 113, 9043-9085 following peer review by the American Chemical Society. The published paper is available as open access at http://pubs.acs.org/doi/abs/10.1021/cr400317

LIINUS/SERPIL: a design study for interferometric imaging spectroscopy at the LBT

LIINUS/SERPIL is a design study to augment LBTs interferometric beam combiner camera LINC-NIRVANA with imaging spectroscopy. The FWHM of the interferometric main beam at 1.5 micron will be about 10 mas, offering unique imaging and spectroscopic capabilities well beyond the angular resolution of current 8-10m telescopes. At 10 mas angular scale, e.g., one resolution element at the distance of the Galactic Center corresponds to the average diameter of the Pluto orbit (79 AU), hence the size of the solar system. Taking advantage of the LBT interferometric beam with an equivalent maximum diameter of 23 m, LIINUS/SERPIL is an ideal precursor instrument for (imaging) spectrographs at extremely large full aperture telescopes. LIINUS/SERPIL will be built upon the LINC-NIRVANA hardware and LIINUS/SERPIL could potentially be developed on a rather short timescale. The study investigates several concepts for the optical as well as for the mechanical design. We present the scientific promises of such an instrument together with the current status of the design study.Comment: 12 pages, SPIE conference proceeding, Orlando, 200

Sensitivity of the deuteron form factor to nucleon resonances

The sensitivity of the deuteron form factor to contributions from the excited states of the nucleon is explored using a simple model of the nucleon-nucleon interaction which employs a tower of charged nucleon resonances. The model is manifestly covariant, analytically solvable, and gauge invariant. The consequences of this model are studied in the simplest possible framework. We assume that all particles have spin zero and that the tower has only three charged members, which consist of the proton, the Roper, and a higher state in the vicinity of the $D_{13}$. Nucleon-nucleon S-wave phase shifts and the deuteron form factor are calculated using this three member tower, and the results are compared to similar calculations using the proton ground state only. We conclude that the deuteron form factor is insensitive to the presence of excited states of the proton unless those states are of sufficiently low mass to produce strong inelasticities in $NN$ scattering channels

Electron-attachment rates for carbon-rich molecules in protoplanetary atmospheres: the role of chemical differences

The formation of anionic species in the interstellar medium from interaction of linear molecules containing carbon, nitrogen and hydrogen as atomic components (polyynes) with free electrons in the environment is modelled via a quantum treatment of the collision dynamics. The ensuing integral cross sections are employed to obtain the corresponding attachment rates over a broad range of temperatures for the electrons. The calculations unequivocally show that a parametrization form often employed for such rates yields a broad range of values that turn out to be specific for each molecular species considered, thus excluding using a unique set for the whole class of polyynes.Comment: accepted to be published on MNRA

Electron attachment rates for PAH anions in the ISM and dark molecular clouds: dependence on their chemical properties

CONTEXT: The attachment of free electrons to polycondensed aromatic ring molecules (PAHs) is studied for the variety of these molecules with different numbers of condensed rings and over a broad range of electron temperatures, using a multichannel quantum scattering approach. The calculations of the relevant cross sections are used in turn to model the corresponding attachment rates for each of the systems under study, and these rates are parametrized as a function of temperature using a commonly employed expression for two-body processes in the interstellar medium (ISM). AIM: The scope of this work is to use first principles to establish the influence of chemical properties on the efficiency of the electron-attachment process for PAHs. METHODS: Quantum multichannel scattering methods are employed to generate the relevant cross sections, hence the attachment rates, using integral elastic cross sections computed over a broad range of relevant energies, from threshold up to 1000 K and linking the attachment to low-energy resonant collisions. RESULTS: The rates obtained for the present molecules are found to markedly vary within the test ensemble of the present work and to be lower than the earlier values used for the entire class of PAHs anions, when modelling their evolutions in ISM environments. The effects of such differences on the evolutions of chemical networks that include both PAH and PAH- species are analysed in some detail and related to previous calculations.Comment: accepted to be published on A&

Reoperation After Cholecystectomy. The Role of the Cystic Duct Stump

The so-called “Postcholecystectomy Syndrome” may be due to various pathological biliary causes. The aim of this study was to evaluate the significance of the cystic duct stump syndrome and if so, how often a long (>1.5 cm) cystic duct stump was an indication for reoperation on the bile ducts after cholecystectomy in our patients. Three hundred and twenty two patients underwent a second operation on the bile ducts after cholecystectomy in the last ten years. In 35 patients (10.8%) a striking finding was a long cystic duct stump (>1.5 cm). In 24 of these patients, a pathological finding, in addition to the long cystic duct stump, was found on exploration. Out of these 24 patients there were 14 with common bile duct stones; 6 with stenosis of the sphincter of Oddi; 3 with chronic pancreatitis and in one patient hepatitis was the cause of the symptoms. From the remaining 11 patients 8 had a stone in a partial gall bladder or cystic duct stump. One patient had a fistula between the cystic duct stump and duodenum and one a suture granuloma. There was only one patient where a 1.5 cm long cystic duct stump remnant was the only pathological finding. Four years after reoperation this patient is still suffering from the same intermittent gastrointestinal symptoms. We conclude that the cystic duct stump is hardly ever a cause for recurrent symptoms in itself. Total excision of the cystic duct does not eliminate the existence of postcholecystectomy symptoms

A Variational Approach to the Spinless Relativistic Coulomb Problem

By application of a straightforward variational procedure we derive a simple, analytic upper bound on the ground-state energy eigenvalue of a semirelativistic Hamiltonian for (one or two) spinless particles which experience some Coulomb-type interaction.Comment: 7 pages, HEPHY-PUB 606/9

Relativistic Coulomb Problem: Analytic Upper Bounds on Energy Levels

The spinless relativistic Coulomb problem is the bound-state problem for the spinless Salpeter equation (a standard approximation to the Bethe--Salpeter formalism as well as the most simple generalization of the nonrelativistic Schr\"odinger formalism towards incorporation of relativistic effects) with the Coulomb interaction potential (the static limit of the exchange of some massless bosons, as present in unbroken gauge theories). The nonlocal nature of the Hamiltonian encountered here, however, renders extremely difficult to obtain rigorous analytic statements on the corresponding solutions. In view of this rather unsatisfactory state of affairs, we derive (sets of) analytic upper bounds on the involved energy eigenvalues.Comment: 12 pages, LaTe

Rotational modulation of X-ray emission in Orion Nebula young stars

We investigate the spatial distribution of X-ray emitting plasma in a sample of young Orion Nebula Cluster stars by modulation of their X-ray light-curves due to stellar rotation. The study, part of the Chandra Orion Ultradeep Project (COUP), is made possible by the exceptional length of the observation: 10 days of ACIS integration during a time span of 13 days, yielding a total of 1616 detected sources in the 17x17 arcmin field of view. We here focus on a subsample of 233 X-ray-bright stars with known rotational periods. We search for X-ray modulation using the Lomb Normalized Periodogram method. X-ray modulation related to the rotation period is detected in at least 23 stars with periods between 2 and 12 days and relative amplitudes ranging from 20% to 70%. In 16 cases, the X-ray modulation period is similar to the stellar rotation period while in seven cases it is about half that value, possibly due to the presence of X-ray emitting structures at opposite stellar longitudes. These results constitute the largest sample of low mass stars in which X-ray rotational modulation has been observed. The detection of rotational modulation indicates that the X-ray emitting regions are distributed inhomogeneneously in longitude and do not extend to distances significantly larger than the stellar radius. Modulation is observed in stars with saturated activity levels (L_X/L_bol ~ 10^(-3)) showing that saturation is not due to the filling of the stellar surface with X-ray emitting regions.Comment: 41 pages, 15 figures, ApJS in press. Figure 15 (34 panels) is an on-line only figure and is not included. A pdf file which includes figure 15 as well as full resolution versions of figure 10 and 11 is available at: http://www.astropa.unipa.it/~ettoref/COUP_RotMod.pd