Characteristics of Non-Allophanic Andisols derived from Low Activity Clay Regoliths in Nilgiri Hills (Southern India)

19International audienceLow activity clay soils on old planation surfaces of the tropics are generally considered as stable end points of soil formation. It is therefore surprising to find Andosols on them. We characterised the properties of six profiles representative of these soils in the Western part of Nilgiri Hills (2000–2500 m above mean sea level), Southern India, where the present climatic conditions are cool (mean annual temperature 15°C) and humid (mean annual rainfall 2500 mm). Thick (50–80 cm) dark–reddish brown topsoil overlies strongly desilicated yellowish–red materials. This horizon has andic properties to a sufficient depth and the carbon content requirement of the melanic epipedon to place these soils in the Andisol order. Our data as well as the history of the Nilgiri Hills suggest that the formation of these non-allophanic Andisols result from the succession of two main steps. First, a ‘lateritic' weathering cycle led to the relative accumulation of secondary Al and Fe oxides. Later, the accumulation of organic matter favoured by a more recent climatic change induced complexation by organic acids of Al and Fe oxides, and the production of enough metal–humus complexes to give rise to andic properties. Such soils, in which secondary Al and Fe oxides, generally considered as indicators of an advanced weathering stage, are involved in a new cycle of soil formation, are original Andisols

Ion exchange equilibria involving aluminum in a kaolinitic Ultisol

Cation exchange equilibria in an acid Ultisol profile involving K-Al, Ca-Al, K-Ca, Na-K, and Na-Ca exchanges were studied. Selectivity coefficients, surface activity coefficients and free energy changes were computed using the thermodynamic formulations. In exchange equilibria involving Al, the magnitude of selectivity coefficients Kc, was affected by pH, surface composition, and hydrolysis of Al. In equilibria not involving Al, good reversibility for K-Ca, Na-K and Na-Ca exchanges was obtained. Potassium was selectively adsorbed in all horizons of the profile. The over-all selectively sequence follows the order of K>Al>Ca≈Na

From Plinthic Acrisols to Plinthosols and Gleysols: iron and groundwater dynamics in the tertiary sediments of the upper Amazon basin

International audienceopography has been reported to be the major factor ruling the spatial distribution of Acrisols, Plinthosols and Gleysols on the seasonally flooded, low elevation plateaux of the upper Amazon basin occupied by Tertiary (Icxa & Solimo ̃es) sediments. In this study, detailed morphological and mineralogical investiga- tions conducted in a representative 25-ha site were combined with hydro-geochemical data to relate the vertical and lateral soil differentiations observed to the hydro-geological history of that part of the basin. As a result of the uplift of the Andes, several cuts in the extensive Tertiary marshlands have formed, at first, slightly incised plateaux of low elevation. There, weathering under hot and humid climates would have generated a reddish, freely drained and bioturbated topsoil layer and the vertical differentiation in subsoil sediments of a plinthite over an iron-depleted mottled clay. The second episode of soil differen- tiation is linked to the replacement of the forest by a savannah under the drier climates of the late Pleistocene, which favours surface runoff and the infill of the incisions by fine particles. This infill, combined with the return to the present humid climate, has then enabled the local groundwater to rise on the plateaux and to generate episaturation at the topsoil/subsoil transition close to the depressions. Nowadays, ferrous iron is released from the partly iron-depleted topsoil weathering front at high water levels during the rainy seasons. It moves from footslope to low-lying positions and from top to bottom in the soil profile according to the groundwater dynamics. The present general trend is thus to the lateral export of iron at high water levels due to subsurface and overland flows, its vertical transfer during the recession of the groundwater and accumulation in a nodular plinthite. In the latter, ferrous iron is adsorbed onto its softest iron masses where it feeds the neoformation of ferrihydrite that rapidly dehydrates into haematite