Geological controls on focused fluid flow through the gas hydrate stability zone on the southern Hikurangi Margin of New Zealand, evidenced from multi-channel seismic data

Highly concentrated gas hydrate deposits are likely to be associated with geological features that promote increased fluid flux through the gas hydrate stability zone (GHSZ). We conduct conventional seismic processing techniques and full-waveform inversion methods on a multi-channel seismic line that was acquired over a 125 km transect of the southern Hikurangi Margin off the eastern coast of New Zealand’s North Island. Initial processing, employed with an emphasis on preservation of true amplitude information, was used to identify three sites where structures and stratal fabrics likely encourage focused fluid flow into and through the GHSZ. At two of the sites, Western Porangahau Trough and Eastern Porangahau Ridge, sub-vertical blanking zones occur in regions of intensely deformed sedimentary layering. It is interpreted that increased fluid flow occurs in these regions and that fluids may dissipate upwards and away from the deformed zone along layers that trend towards the seafloor. At Eastern Porangahau Ridge we also observe a coherent bottom simulating reflection (BSR) that increases markedly in intensity with proximity to the centre of the anticlinal ridge. 1D full-waveform inversions conducted at eight points along the BSR reveal much more pronounced low-velocity zones near the centre of the ridge, indicating a local increase in the flux of gas-charged fluids into the anticline. At another anticline, Western Porangahau Ridge, a dipping high-amplitude feature extends from the BSR upwards towards the seafloor within the regional GHSZ. 1D full-waveform inversions at this site reveal that the dipping feature is characterised by a high-velocity zone overlying a low-velocity zone, which we interpret as gas hydrates overlying free gas. These results support a previous interpretation that this high-amplitude feature represents a local “up-warping” of the base of hydrate stability in response to advective heat flow from upward migrating fluids. These three sites provide examples of geological frameworks that encourage prolific localised fluid flow into the hydrate system where it is likely that gas-charged fluids are converting to highly concentrated hydrate deposits

Origin of blocky aragonite cement in Cenozoic glaciomarine sediments, McMurdo Sound, Antarctica

Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio‐chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from the CIROS‐1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore‐filling blocky fabric throughout the core. Oxygen isotope compositions (δ18O = −30·0 to −8·6‰ Vienna Pee‐Dee Belemnite) and clumped isotope temperatures (TΔ47 = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ18Ow) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluid δ18Ow values are consistent with those of pore water, previously identified as cryogenic brine in the nearby AND‐2A core. Petrographic and geochemical data suggest that aragonite cement in the CIROS‐1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in the CIROS‐1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought