Spin glass freezing and superconductivity in YBa2(Cu(1-x)Fe(x))3O7 alloys

The dynamics were studied of the iron spins in superconducting YBa2(Cu(0.94)Fe(0.06))3O7 by neutron time of flight measurements. Two samples were studied with slightly different characteristics, as shown by resistivity and neutron diffraction measurements. The same dynamical anomalies are observed by neutrons in both samples. Differences appear qualitative but not quantitative. In the whole temperature range, the q-dependence of the magnetic intensity mainly reflects the magnetic form factor of iron which shows that the iron spins are almost uncorrelated. The elastic and quasielastic intensities strongly vary with temperature. A spin glass like freezing is revealed at low temperature by a sharp decrease of the quasielastic intensity, an increase of the 'elastic' or resolution limited intensity and a minimum in the quasielastic width. The freezing temperature (T sub f - 18 K) corresponds to that already determined by a magnetic splitting in Mossbauer experiments. Above T sub f, the relaxation of the iron spins in the paramagnetic state is modified by the occurrence of superconductivity. An increase was observed of the quasielastic intensity and of the quasielastic width at the superconducting transition

High-field AFMR in single-crystalline La_{0.95}Sr_{0.05}MnO_3: Experimental evidence for the existence of a canted magnetic structure

High-field antiferromagnetic-resonance (AFMR) spectra were obtained in the frequency range 60 GHz < \nu < 700 GHz and for magnetic fields up to 8 T in twin-free single crystals of La_{0.95}Sr_{0.05}MnO_3. At low temperatures two antiferromagnetic modes were detected, which reveal different excitation conditions and magnetic field dependencies. No splitting of these modes was observed for any orientation of the static magnetic field excluding the phase-separation scenario for this composition. Instead, the full data set including the anisotropic magnetization can be well described using a two-sublattice model of a canted antiferromagnetic structure.Comment: 4 pages, 3 figure

Approach to the metal-insulator transition in La(1-x)CaxMnO3 (0<x<.2): magnetic inhomogeneity and spin wave anomaly

We describe the evolution of the static and dynamic spin correlations of La$_{1-x}$Ca$_x$MnO$_3$, for x=0.1, 0.125 and 0.2, where the system evolves from the canted magnetic state towards the insulating ferromagnetic state, approaching the metallic transition (x=0.22). In the x=0.1 sample, the observation of two spin wave branches typical of two distinct types of magnetic coupling, and of a modulation in the elastic diffuse scattering characteristic of ferromagnetic inhomogeneities, confirms the static and dynamic inhomogeneous features previously observed at x$<$0.1. The anisotropic q-dependence of the intensity of the low-energy spin wave suggests a bidimensionnal character for the static inhomogeneities. At x=0.125, which corresponds to the occurence of a ferromagnetic and insulating state, the two spin wave branches reduce to a single one, but anisotropic. At this concentration, an anomaly appears at {\bf q$_0$}=(1.25,1.25,0), that could be related to an underlying periodicity, as arising from (1.5,1.5,0) superstructures. At x=0.2, the spin-wave branch is isotropic. In addition to the anomaly observed at q$_0$, extra magnetic excitations are observed at larger q, forming an optical branch. The two dispersion curves suggest an anti-crossing behavior at some {\bf q$_0$'} value, which could be explained by a folding due to an underlying perodicity involving four cubic lattice spacings

Lattice dynamics of mixed semiconductors (Be,Zn)Se from first-principles calculations

Vibration properties of Zn(1-x)Be(x)Se, a mixed II-VI semiconductor haracterized by a high contrast in elastic properties of its pure constituents, ZnSe and BeSe, are simulated by first-principles calculations of electronic structure, lattice relaxation and frozen phonons. The calculations within the local density approximation has been done with the Siesta method, using norm-conserving pseudopotentials and localized basis functions; the benchmark calculations for pure endsystems were moreover done also by all-electron WIEN2k code. An immediate motivation for the study was to analyze, at the microscopic level, the appearance of anomalous phonon modes early detected in Raman spectra in the intermediate region (20 to 80%) of ZnBe concentration. This was early discussed on the basis of a percolation phenomenon, i.e., the result of the formation of wall-to-wall --Be--Se-- chains throughout the crystal. The presence of such chains was explicitly allowed in our simulation and indeed brought about a softening and splitting off of particular modes, in accordance with experimental observation, due to a relative elongation of Be--Se bonds along the chain as compared to those involving isolated Be atoms. The variation of force constants with interatomic distances shows common trends in relative independence on the short-range order.Comment: 11 pages, 10 figures, to be published in Phys. Rev.

Spin-polarized oxygen hole states in cation deficient La(1-x)CaxMnO(3+delta)

When holes are doped into a Mott-Hubbard type insulator, like lightly doped manganites of the La(1-x)CaxMnO3 family, the cooperative Jahn-Teller distortions and the appearance of orbital ordering require an arrangement of Mn(3+)/Mn(4+) for the establishment of the insulating canted antiferromagnetic (for x<=0.1), or of the insulating ferromagnetic (for 0.1<x<= 0.2) ground state. In the present work we provide NMR evidence about a novel and at the same time puzzling effect in La(1-x)CaxMnO(3+delta) systems with cation deficience. We show that in the low Ca-doping regime, these systems exhibit a very strong hyperfine field at certain La nuclear sites, which is not present in the stoichiometric compounds. Comparison of our NMR results with recent x-ray absorption data at the Mn K edge, suggests the formation of a spin-polarized hole arrangement on the 2p oxygen orbitals as the origin of this effect.Comment: 10 pages, 4 Figures, submitted to PR

Evidence of anisotropic magnetic polarons in la0.94_{0.94}Sr0.06_{0.06}MnO3_3 by neutron scattering and comparison with Ca-doped manganites

Elastic and inelastic neutron scattering experiments have been performed in a La$_{0.94}$Sr$_{0.06}$MnO$_3$ untwinned crystal, which exhibits an antiferromagnetic canted magnetic structure with ferromagnetic layers. The elastic small q scattering exhibits a modulation with an anisotropic q-dependence. It can be pictured by ferromagnetic inhomogeneities or polarons with a platelike shape, the largest size ($\approx17\AA$) and largest inter-polaron distance ($\approx$ 38$\AA$) being within the ferromagnetic layers. Comparison with observations performed on Ca-doped samples, which show the growth of the magnetic polarons with doping, suggests that this growth is faster for the Sr than for the Ca substitution. Below the gap of the spin wave branch typical of the AF layered magnetic structure, an additional spin wave branch reveals a ferromagnetic and isotropic coupling, already found in Ca-doped samples. Its q-dependent intensity, very anisotropic, closely reflects the ferromagnetic correlations found for the static clusters. All these results agree with a two-phase electronic segregation occurring on a very small scale, although some characteristics of a canted state are also observed suggesting a weakly inhomogeneous state.Comment: 11 pages, 11 figure

Theoretical and experimental evidence of level repulsion states and evanescent modes in sonic crystal stubbed waveguides

The complex band structures calculated using the Extended Plane Wave Expansion (EPWE) reveal the presence of evanescent modes in periodic systems, never predicted by the classical \omega(\vec{k}) methods, providing novel interpretations of several phenomena as well as a complete picture of the system. In this work we theoretically and experimentally observe that in the ranges of frequencies where a deaf band is traditionally predicted, an evanescent mode with the excitable symmetry appears changing drastically the interpretation of the transmission properties. On the other hand, the simplicity of the sonic crystals in which only the longitudinal polarization can be excited, is used to interpret, without loss of generality, the level repulsion between symmetric and antisymmetric bands in sonic crystals as the presence of an evanescent mode connecting both repelled bands. These evanescent modes, obtained using EPWE, explain both the attenuation produced in this range of frequencies and the transfer of symmetry from one band to the other in good agreement with both experimental results and multiple scattering predictions. Thus, the evanescent properties of the periodic system have been revealed necessary for the design of new acoustic and electromagnetic applications based on periodicity

Low energy magnetic excitations of the Mn_{12}-acetate spin cluster observed by neutron scattering

We performed high resolution diffraction and inelastic neutron scattering measurements of Mn_{12}-acetate. Using a very high energy resolution, we could separate the energy levels corresponding to the splitting of the lowest S multiplet. Data were analyzed within a single spin model (S=10 ground state), using a spin Hamiltonian with parameters up to 4^{th} order. The non regular spacing of the transition energies unambiguously shows the presence of high order terms in the anisotropy (D= -0.457(2) cm^{-1}, B_4^0 = -2.33(4) 10^{-5}cm^{-1}). The relative intensity of the lowest energy peaks is very sensitive to the small transverse term, supposed to be mainly responsible for quantum tunneling. This allows an accurate determination of this term in zero magnetic field (B_4^4 = \pm 3.0(5) 10^{-5} cm^{-1}). The neutron results are discussed in view of recent experiments and theories.Comment: 4 pages ? 3 figures, submitted to Physical Review Lette

Resistivity and 1/f Noise in Non-Metallic Phase Separated Manganites

A simple model is proposed to calculate resistivity, magnetoresistance, and noise spectrum in non-metallic phase-separated manganites containing small metallic droplets (magnetic polarons). The system is taken to be far from the percolation transition into a metallic state. It is assumed that the charge transfer occurs due to electron tunneling from one droplet to another through the insulating medium. As a result of this tunneling, the droplets acquire or lose extra electrons forming metastable two-electron and empty states. In the framework of this model, explicit expressions for dc conductivity and noise power of the system are derived. It is shown that the noise spectrum has 1/f form in the low-frequency range.Comment: 6 pages, 1 fugure include