32,439 research outputs found
On the contact values of the density profiles in an electric double layer using density functional theory
A recently proposed local second contact value theorem [Henderson D., Boda
D., J. Electroanal. Chem., 2005, 582, 16] for the charge profile of an electric
double layer is used in conjunction with the existing Monte Carlo data from the
literature to assess the contact behavior of the electrode-ion distributions
predicted by the density functional theory. The results for the contact values
of the co- and counterion distributions and their product are obtained for the
symmetric valency, restricted primitive model planar double layer for a range
of electrolyte concentrations and temperatures. Overall, the theoretical
results satisfy the second contact value theorem reasonably well, the agreement
with the simulations being semi-quantitative or better. The product of the co-
and counterion contact values as a function of the electrode surface charge
density is qualitative with the simulations with increasing deviations at
higher concentrations.Comment: 10 pages, 8 figure
Pathogen burden and cortisol profiles over the day
Hypothalamic-pituitary-adrenocortical (HPA) regulation in adults is influenced by early psychosocial adversity, but the role of infectious disease history is poorly understood. We studied the association between cumulative pathogen burden and cortisol profile over the day in a sample of 317 healthy men and women aged 51-72 years. Cumulative pathogen burden was defined as positive serostatus for Chlamydia pneumoniae, cytomegalovirus (CMV) and herpes simplex virus 1 (HSV-1). Salivary cortisol was sampled repeatedly over the day. The cortisol slope was defined as the decrease across the day and evening. Age, gender, grade of employment, body mass index, smoking status, self-rated health, cardiovascular medication, depressed mood and time of waking were included as covariates. The pathogen burden averaged 1.76 (S.D. = 0.92). The cortisol slope was inversely associated with pathogen burden after controlling for covariates. When individual pathogens were studied, only CMV was associated with flatter cortisol rhythms in isolation. We conclude that pathogen burden is independently associated with flatter cortisol slopes over the day, and may contribute to disturbed neuroendocrine regulation
Circularly polarized microwaves for magnetic resonance study in the GHz range: application to nitrogen-vacancy in diamonds
The ability to create time-dependent magnetic fields of controlled
polarization is essential for many experiments with magnetic resonance. We
describe a microstrip circuit that allows us to generate strong magnetic field
at microwave frequencies with arbitrary adjusted polarization. The circuit
performance is demonstrated by applying it to an optically detected magnetic
resonance and Rabi nutation experiments in nitrogen-vacancy color centers in
diamond. Thanks to high efficiency of the proposed microstrip circuit and
degree of circular polarization of 85% it is possible to address the specific
spin states of a diamond sample using a low power microwave generator.Comment: 4 pages, 7 figures, nitrogen-vacancy, microwave circular
polarization, spin-state addressin
Adaptive Simulation Using Perfect Control Variates
Adaptive Simulation Using Perfect Control Variate
Influence of anisotropic ion shape, asymmetric valency, and electrolyte concentration on structural and thermodynamic properties of an electric double layer
Grand canonical Monte Carlo simulation results are reported for an electric
double layer modelled by a planar charged hard wall, anisotropic shape cations,
and spherical anions at different electrolyte concentrations and asymmetric
valencies. The cations consist of two tangentially tethered hard spheres of the
same diameter, . One sphere is charged while the other is neutral. Spherical
anions are charged hard spheres of diameter . The ion valency asymmetry 1:2
and 2:1 is considered, with the ions being immersed in a solvent mimicked by a
continuum dielectric medium at standard temperature. The simulations are
carried out for the following electrolyte concentrations: 0.1, 1.0 and 2.0 M.
Profiles of the electrode-ion, electrode-neutral sphere singlet distributions,
the average orientation of dimers, and the mean electrostatic potential are
calculated for a given electrode surface charge, , while the contact
electrode potential and the differential capacitance are presented for varying
electrode charge. With an increasing electrolyte concentration, the shape of
differential capacitance curve changes from that with a minimum surrounded by
maxima into that of a distorted single maximum. For a 2:1 electrolyte, the
maximum is located at a small negative value while for 1:2, at a small
positive value.Comment: 10 pages, 6 figure
Double layer for hard spheres with an off-center charge
Simulations for the density and potential profiles of the ions in the planar
electrical double layer of a model electrolyte or an ionic liquid are reported.
The ions of a real electrolyte or an ionic liquid are usually not spheres; in
ionic liquids, the cations are molecular ions. In the past, this asymmetry has
been modelled by considering spheres that are asymmetric in size and/or valence
(viz., the primitive model) or by dimer cations that are formed by tangentially
touching spheres. In this paper we consider spherical ions that are asymmetric
in size and mimic the asymmetrical shape through an off-center charge that is
located away from the center of the cation spheres, while the anion charge is
at the center of anion spheres. The various singlet density and potential
profiles are compared to (i) the dimer situation, that is, the constituent
spheres of the dimer cation are tangentially tethered, and (ii) the standard
primitive model. The results reveal the double layer structure to be
substantially impacted especially when the cation is the counterion. As well as
being of intrinsic interest, this off-center charge model may be useful for
theories that consider spherical models and introduce the off-center charge as
a perturbation.Comment: 11 pages, 7 figure
An extended model of the quantum free-electron laser
Previous models of the quantum regime of operation of the Free Electron Laser
(QFEL) have performed an averaging and the application of periodic boundary
conditions to the coupled Maxwell - Schrodinger equations over short, resonant
wavelength intervals of the interaction. Here, an extended, one-dimensional
model of the QFEL interaction is presented in the absence of any such averaging
or application of periodic boundary conditions, the absence of the latter
allowing electron diffusion processes to be modeled throughout the pulse. The
model is used to investigate how both the steady-state (CW) and pulsed regimes
of QFEL operation are affected. In the steady-state regime it is found that the
electrons are confined to evolve as a 2-level system, similar to the previous
QFEL models. In the pulsed regime Coherent Spontaneous Emission (CSE) due to
the shape of the electron pulse current distribution is shown to be present in
the QFEL regime for the first time. However, unlike the classical case, CSE in
the QFEL is damped by the effects of quantum diffusion of the electron
wavefunction. Electron recoil from the QFEL interaction can also cause a
diffusive drift between the recoiled and non-recoiled parts of the electron
pulse wavefunction, effectively removing the recoiled part from the primary
electron-radiation interaction.Comment: Submitted to Optics Expres
A Spatio-Temporal Point Process Model for Ambulance Demand
Ambulance demand estimation at fine time and location scales is critical for
fleet management and dynamic deployment. We are motivated by the problem of
estimating the spatial distribution of ambulance demand in Toronto, Canada, as
it changes over discrete 2-hour intervals. This large-scale dataset is sparse
at the desired temporal resolutions and exhibits location-specific serial
dependence, daily and weekly seasonality. We address these challenges by
introducing a novel characterization of time-varying Gaussian mixture models.
We fix the mixture component distributions across all time periods to overcome
data sparsity and accurately describe Toronto's spatial structure, while
representing the complex spatio-temporal dynamics through time-varying mixture
weights. We constrain the mixture weights to capture weekly seasonality, and
apply a conditionally autoregressive prior on the mixture weights of each
component to represent location-specific short-term serial dependence and daily
seasonality. While estimation may be performed using a fixed number of mixture
components, we also extend to estimate the number of components using
birth-and-death Markov chain Monte Carlo. The proposed model is shown to give
higher statistical predictive accuracy and to reduce the error in predicting
EMS operational performance by as much as two-thirds compared to a typical
industry practice
Spitzer Microlensing Parallax for OGLE-2016-BLG-1067: A Sub-Jupiter Orbiting an M Dwarf in the Disk
We report the discovery of a sub-Jupiter-mass planet orbiting beyond the snow line of an M dwarf most likely in the Galactic disk as part of the joint Spitzer and ground-based monitoring of planetary microlensing anomalies toward the Galactic bulge. Most of the microlensing parameters are strongly constrained by the light-curve modeling, and in particular there is a Spitzer-based measurement of the microlens parallax, π E. However, there are no caustic crossings, so the angular Einstein radius has only an upper limit based on the light-curve modeling alone. Additionally, the analysis leads us to identify eight degenerate configurations: the fourfold microlensing parallax degeneracy being doubled by a degeneracy in the caustic structure present at the level of the ground-based solutions. To calculate the physical parameters, and at the same time to break the parallax degeneracy, we make use of a series of arguments: the χ 2 hierarchy, the Rich argument (stating that the small-parallax solution is more likely), and a prior Galactic model. The preferred configuration, favored by a likelihood ratio of at least 4000, is for a host at D_L = 3.73^(+0.66)_(-0.67) kpc with mass M_L = 0.30^(+0.15)_(-0.12) M⊙, orbited by a Saturn-like planet with M_(planet) = 0.43^(+0.21)_(-0.17) M_(Jup) at projected separation a = 1.70^(+0.38)_(-0.39) au, about 2.1 times beyond the system snow line. Therefore, it adds to the growing population of sub-Jupiter planets orbiting beyond the snow line of M dwarfs discovered by microlensing. Based on the rules of the real-time protocol for the selection of events to be followed up with Spitzer, this planet will not enter the sample for measuring the Galactic distribution of planets
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