162 research outputs found

    Die Wirkung von Düngerart und Düngermenge auf die Partitionierung von Kohlenstoff und Stickstoff in Pools mit unterschiedlichem Umsatz

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    Type and rate of fertilizer influence the level of organic carbon and total nitrogen in the soil markedly, but the effect on different pools is open to question. Soil samples were taken from a sandy Cambisol at Darmstadt, Germany, after 27 years of different fertilization treatments. The six treatments were: straw incorporation plus application of mineral fertilizer (MSI) and application of farmyard manure (FYM) each at high (140 – 150 kg N ha-1 year-1), medium (100 kg N ha-1 year-1) and low (50 – 60 kg N ha-1 year-1) rates. After 266 days of incubation (10°C, 50% water-filled pore space) mineralization of C (1130 – 1820 kg ha-1) and N (90 – 125 kg ha-1) depended on the rate and not on the type of fertilizer. Very labile and labile pools were obtained by fitting a two-pool model on the mineralization data. The very labile pool (turnover: 17 days, C/N ratio: 23) was unaffected by treatments. Storage of C (1.8 – 3.2 t ha-1) in the labile pool (turnover 462 days, C/N ratio: 22) increased significantly with the rate of fertilizer. The size of the intermediate pool was significantly higher in FYM (15 -18 t ha-1) than in MSI treatments (12- 14 t ha-1). A passive pool, obtained by oxidation with Na2S2O8, was independent of treatments. Our study shows that labile and intermediate pools were affected differently by fertilization

    Experimental Measurements of Binder Wave Speeds using Wavenumber Decomposition

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    Prior work has provided few wave speed measurements for the binder materials commonly used with plastic- bonded energetics. Furthermore, those measurements that have been reported are largely based upon rudimentary, \u27pitch and catch\u27 methodologies, which involve sending a pulse from one transducer to another transducer at a set distance apart and measuring the time of flight. Given this, a more rigorous method for determining longitudinal and shear wave speeds in this important class of materials was desired. In this work, material wave speeds are recovered by measuring the vibrational response of a 2D line across the surface of a beam in response to a mechanical excitation and analyzing the data in the frequency-wavenumber domain

    Degradation mechanisms and consequences for SOC stocks for the world's largest alpine pastoral ecosystem on the Tibetan Plateau

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    Approximately 1.5 million km² of the Tibetan Plateau are covered with grasslands. Thereof one third is occupied by the world’s largest pastoral alpine ecosystem (Kobresia pastures). Paleo-records indicate the grazing-induced origin of this ecosystem since more than 8000 years or at least since yak domestication since 4000 years. Long-term moderate grazing by yak and sheep increased belowground C allocation of Kobresia pygmaea, caused the development of dense root-mats and finally lead to an accumulation of soil organic carbon (SOC) and nutrients such as nitrogen (N) and phosphorus (P) in the topsoil. These pastures, however, are increasingly affected by large-scale degradation caused by overgrazing of these highly sensitive ecosystems. Loss of the topsoil threatens several ecosystem functions: i.e. SOC and nutrient storage, biodiversity, provision of grazing-ground and supply of clean water for large parts of SE-Asia. Here, we present a conceptual model and results of degradation processes combining anthropogenic and natural amplifications. To evaluate losses of SOC and nutrients we synthesize field observations and surveys in the highlands and validates this with own analyses in the Kobresia core area. We show that drought- and frost-induced polygonal cracking opens the root-mats, already weakened by overgrazing. This initiates a dying of the Kobresia turf, extends the surface cracks, triggers soil erosion and promotes SOC mineralization and leaching losses. Soil erosion caused further high losses of SOC and nutrients from the topsoil (i.e. 0-10 cm: ~5.1 kg C m-2), whereas SOC loss beneath the surface cracks was primary caused by both, decreasing C-input and SOC mineralization (mineralization-derived SOC loss: ~2.5 kg C m-2). The root biomass decreased with intensity of pasture degradation and lower C input constrains the ecosystem recovery. A negative δ13C shift of SOC reflected intensive decomposition and corresponded to a relative enrichment of 13C depleted lignin components. In sum, degradation triggered high SOC loss (up to 70% of intact soil in 0-30 cm: ~7.6 kg C m-2) from this ecosystem with profound consequences for carbon sequestration, atmospheric CO2, water quality and ecosystem stability

    Nitrogen Uptake in an Alpine Kobresia Pasture on the Tibetan Plateau: Localization by <sup>15</sup>N Labeling and Implications for a Vulnerable Ecosystem

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    © 2015, Springer Science+Business Media New York. Grasslands are very important regionally and globally because they store large amounts of carbon (C) and nitrogen (N) and provide food for grazing animals. Intensive degradation of alpine grasslands in recent decades has mainly impacted the upper root-mat/soil horizon, with severe consequences for nutrient uptake in these nutrient-limited ecosystems. We used 15N labeling to identify the role of individual soil layers for N-uptake by Kobresia pygmaea—the dominating plant in the degraded Tibetan pasture ecosystems. We hypothesized a very efficient N-uptake corresponding mainly to the vertical distribution of living roots (topsoil > subsoil). We assume that K. pygmaea develops a very dense root-mat, which has to be maintained by small aboveground biomass, to enable this efficient N-uptake. Consequently, a higher N-investment into roots compared to shoots was hypothesized. The 15N recovery in whole plants (~70%) indicated very efficient N-uptake from the upper injection depths (0–5 cm). The highest 15N amounts were recovered in root biomass, whereby 15N recovery in roots strongly decreased with depth. In contrast, 15N recovery in shoots was generally low (~18%) and independent of the 15N injection depth. This clearly shows that the low N demand of Kobresia shoots can be easily covered by N-uptake from any depth. Less living root biomass in lower versus upper soil was compensated by a higher specific activity of roots for N-uptake. The 15N allocation into roots was on average 1.7 times higher than that into shoots, which agreed well with the very high R/S ratio. Increasing root biomass is an efficient strategy of K. pygmaea to compete for belowground resources at depths and periods with available resources. This implies high C-costs to maintain root biomass (~6.0 kg DM m−2), which must be covered by a very low amount of photosynthetically active shoots (0.3 kg DM m−2). It also suggests that Kobresia grasslands react extremely sensitively toward changes in climate and management that disrupt this above-/belowground trade-off mechanism

    Primary progressive aphasia: a clinical approach

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    This work was supported by the Alzheimer’s Society (AS-PG-16-007), the National Institute for Health Research University College London Hospitals Biomedical Research Centre and the UCL Leonard Wolfson Experimental Neurology Centre (PR/ylr/18575). Individual authors were supported by the Leonard Wolfson Foundation (Clinical Research Fellowship to CRM), the National Institute for Health Research (NIHR Doctoral Training Fellowship to AV), the National Brain Appeal–Frontotemporal Dementia Research Fund (CNC) and the Medical Research Council (PhD Studentships to CJDH and RLB, MRC Research Training Fellowship to PDF, MRC Clinician Scientist to JDR). MNR and NCF are NIHR Senior Investigators. SJC is supported by Grants from ESRC-NIHR (ES/L001810/1), EPSRC (EP/M006093/1) and Wellcome Trust (200783). JDW was supported by a Wellcome Trust Senior Research Fellowship in Clinical Science (091673/Z/10/Z)

    Exploring Asymmetric Aza-Cycloaddition Reactions in the Synthesis of Biologically Intriguing Small Molecules

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