Rotationally resolved collisional transfer rates in OH

Fluorescence lidar measurements of the hydroxyl radical require detailed information concerning collision induced processes in order to deduce the radical number density from a lidar return. The Goddard SFC OH lidar currently utilizes a broadband detector which precludes the necessity of fully understanding collisional redistribution of rotational energy within the excited state. Numerous advantages result however from the inclusion of a detector with a bandpass only slightly larger that the Doppler width of a rotational line. This however places more stringent requirements on the spectroscopy. Measurements were accordingly made of rotationally resolved quenching rates for collisions with O2, N2, and H2O. Rotational transfer rates were also measured for the same colliders. Quenching rates were measured using a Nd-YAG pumped Rh6G dye laser doubled into the UV. The OH lifetimes were measured as a function of pressure of quenching gas at total pressures of between 50 and 250 microns. Rotational transfer rates were measured by recording the emission spectrum on an intensified diode array and integrating over 10.000 laser shots

Improvements in the Goddard balloon-borne lidar

The Goddard balloon-borne lidar system for the measurement of stratospheric ozone and the hydroxyl radical has made three additional flights since the last laser radar conference. On September 27, 1984, a flight was made from Palestine, Texas obtaining a measurement of hydroxyl diurnal variation at 36 km. These data are presented on the plot which shows hydroxyl concentration as a function of GMT for the range cell closest to the instrument. Local noon corresponds to 18 hours on the plot. The rapid drop in concentration after noon is not predicted by models of stratospheric chemistry. It may represent the effects of contamination of the sample volume by hydrocarbons outgassed from the balloon. The more recent flights on June 30, 1985, and December 6, 1985, focussed on measurements of concentration in the lower stratosphere (less than 30 km). The June flight succeeded in obtaining an average concentration measurement (1.8 + or - 0.0000018 molecules/cubic cm) over the altitude range 21 to 26 km. The December flight obtained measurements down to 24 km with a better signal-to-noise ratio than that obtained in June. Prospects for further improvement in sensitivity and absolute calibration will be discussed

A Broad Bank Lidar for Precise Atmospheric CO2 Column Absorption Measurement from Space

Accurate global measurement of carbon dioxide column with the aim of discovering and quantifying unknown sources and sinks has been a high priority for the last decade. In order to uncover the "missing sink" that is responsible for the large discrepancies in the budget the critical precision for a measurement from space needs to be on the order of 1 ppm. To better understand the CO2 budget and to evaluate its impact on global warming the National Research Council (NRC) in its recent decadal survey report (NACP) to NASA recommended a laser based total CO2 mapping mission in the near future. That's the goal of Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission - to significantly enhance the understanding of the role of CO2 in the global carbon cycle. Our current goal is to develop an ultra precise, inexpensive new lidar system for column measurements of CO2 changes in the lower atmosphere that uses a Fabry-Perot interferometer based system as the detector portion of the instrument and replaces the narrow band laser commonly used in lidars with a high power broadband source. This approach reduces the number of individual lasers used in the system and considerably reduces the risk of failure. It also tremendously reduces the requirement for wavelength stability in the source putting this responsibility instead on the Fabry- Perot subsystem

Robust IR Remote Sensing Technique of the Total Column of Trace Gases Including Carbon Dioxide and Methane

Progress on the development of a differential radiometer based upon the Fabry-Perot interferometer (FPI) for methane (CH4) and carbon dioxide (C02) detection in the atmosphere is presented. Methane measurements are becoming increasingly important as a component of NASA's programs to understand the global carbon cycle and quantifY the threat of global warming. Methane is the third most important greenhouse gas in the Earth's radiation budget (after water vapor and carbon dioxide) and the second most important anthropogenic contributor to global warming. The importance of global warming and air quality to society caused the National Research Council to recommend that NASA develop the following missions [1]: ASCENDS (Active Sensing of C02 Emissions over Nights, Days, and Seasons), GEOCAPE (Geostationary Coastal and Air Pollution Events), and GACM (Global Atmosphere Composition Mission). Though methane measurements are not specifically called out in these missions, ongoing environmental changes have raised the importance of understanding the methane budget. In the decadal survey is stated that "to close the carbon budget, we would also address methane, but the required technology is not obvious at this time. If appropriate and cost-effective methane technology becomes available, we strongly recommend adding a methane capability". In its 2007 report the International Panel on Climate Change identified methane as a key uncertainty in our understanding saying that the causes of recent changes in the growth rate of atmospheric CH4 are not well understood. What we do know is that methane arises from a number of natural sources including wet lands and the oceans plus man made sources from agriculture, as well as coal and petroleum production and distribution. It has recently been pointed out that large amount of methane are frozen in the permafrost of Canada and Siberia. There is a fear that melting of this permafrost driven by global warming may release large amounts of methane very suddenly further exacerbating climate change [2]. Last year our group began a joint effort with Johns Hopkins Applied Physics Laboratory to investigate the possibility of developing a small unmanned aerial vehicle (UAV) equipped to measure greenhouse gases-particularly methane. Although we are targeting our system for smaller UAV's the instrument will be directly applicable to missions involving larger NASA UAV's such as Global Hawk or even on missions utilizing manned aircraft. Because of its small size, inherent ruggedness and simplicity some version of our proposed instrument may find a role as a satellite instrument for NASA or NOAA

A New Remote Sensing Filter Radiometer Employing a Fabry-Perot Etalon and a CCD Camera for Column Measurements of Methane in the Earth Atmosphere

A portable remote sensing system for precision column measurements of methane has been developed, built and tested at NASA GSFC. The sensor covers the spectral range from 1.636 micrometers to 1.646 micrometers, employs an air-gapped Fabry-Perot filter and a CCD camera and has a potential to operate from a variety of platforms. The detector is an XS-1.7-320 camera unit from Xenics Infrared solutions which combines an uncooled InGaAs detector array working up to 1.7 micrometers. Custom software was developed in addition to the graphical user basic interface X-Control provided by the company to help save and process the data. The technique and setup can be used to measure other trace gases in the atmosphere with minimal changes of the etalon and the prefilter. In this paper we describe the calibration of the system using several different approaches

Variation of the Diameter of the Sun as Measured by the Solar Disk Sextant (SDS)

The balloon-borne Solar Disk Sextant (SDS) experiment has measured the angular size of the Sun on seven occasions spanning the years 1992 to 2011. The solar half-diameter -- observed in a 100-nm wide passband centred at 615 nm -- is found to vary over that period by up to 200 mas, while the typical estimated uncertainty of each measure is 20 mas. The diameter variation is not in phase with the solar activity cycle; thus, the measured diameter variation cannot be explained as an observational artefact of surface activity. Other possible instrument-related explanations for the observed variation are considered but found unlikely, leading us to conclude that the variation is real. The SDS is described here in detail, as is the complete analysis procedure necessary to calibrate the instrument and allow comparison of diameter measures across decades.Comment: 41 pages; appendix and 2 figures added plus some changes in text based on referee's comments; to appear in MNRA

Dip coating process: Silicon sheet growth development for the large-area silicon sheet task of the low-cost silicon solar array project

The research program to investigate the technical and economic feasibility of producing solar-cell-quality sheet silicon by dip-coating one surface of carbonized ceramic substrates with a thin layer of large-grain polycrystalline silicon is reported. The initial effort concentrated on the design and construction of the experimental dip-coating facility. The design was completed and its experimental features are discussed. Current status of the program is reported, including progress toward solar cell junction diffusion and miscellaneous ceramic substrate procurement

Trends in stratospheric minor constituents

Photochemical models predict that increasing source gas concentrations are also expected to lead to changes in the concentrations of both catalytically active radical species (such as NO2, ClO, and OH) and inactive reservoir species (such as HNO3, HCl, and H2O). For simplicity, we will refer to all these as trace species. Those species that are expected to have increasing concentration levels are investigated. Additionally, the trace species concentration levels are monitored for unexpected changes on the basis of the measure increase in source gases. Carrying out these investigations is difficult due to the limited data base of measurements of stratospheric trace species. In situ measurements are made only infrequently, and there are few satelliteborne measurements, most over a time space insufficient for trend determination. Instead, ground-based measurements of column content must be used for many species, and interpretation is complicated by contributions from the troposphere or mesosphere or both. In this chapter, we examine existing measurements as published or tabulated