1,295 research outputs found
Orbital Dimer Model for Spin-Glass State in YMoO
The formation of a spin glass usually requires both structural disorder and
frustrated magnetic interactions. Consequently, the origin of spin-glass
behaviour in YMoO in which magnetic Mo ions occupy a
frustrated pyrochlore lattice with minimal compositional disorder has been
a longstanding question. Here, we use neutron and X-ray pair-distribution
function (PDF) analysis to develop a disorder model that resolves apparent
incompatibilities between previously-reported PDF, EXAFS and NMR studies and
provides a new and physical mechanism for spin-glass formation. We show that
Mo ions displace according to a local "2-in/2-out" rule on each Mo
tetrahedron, driven by orbital dimerisation of Jahn-Teller active Mo
ions. Long-range orbital order is prevented by the macroscopic degeneracy of
dimer coverings permitted by the pyrochlore lattice. Cooperative O
displacements yield a distribution of MoOMo angles, which in turn
introduces disorder into magnetic interactions. Our study demonstrates
experimentally how frustration of atomic displacements can assume the role of
compositional disorder in driving a spin-glass transition.Comment: 6 pages, 3 figure
Evidence of paracrystalline cation order in the Ruddlesden-Popper phase LaSr3NiRuO8 through total scattering techniques
Cation ordering in perovskite-derived phases can lead to a wealth of tunable physical properties. Ordering is typically driven by a large difference between the cation size and charge, but many Ruddlesden–Popper phases An+1BnO3n+1 appear to lack such B-site ordering, even when these differences are present. One such example is the “double” Ruddlesden–Popper n = 1 composition LaSr3NiRuO8. In this material, a lack of B-site ordering is observed through traditional crystallographic techniques, but antiferromagnetic ordering in the magnetism data suggests that B-site cation ordering is indeed present. Neutron total scattering, particularly analysis of the neutron pair distribution function, reveals that the structure is locally B-site-ordered below 6 Å but becomes slightly disordered in the midrange structure around 12 Å. This provides evidence for paracrystalline order in this material: cation ordering within a single perovskite sheet that lacks perfect registry within the three-dimensional stack of sheets. This work highlights the importance of employing a structural technique that can probe both the local and midrange order in addition to the crystallographic structure and provides a structural origin to the observed magnetic properties of LaSr3NiRuO8. Further, it is proposed that paracrystalline order is likely to be common among these layered-type oxides
The Gemini NICI Planet-Finding Campaign: The Offset Ring of HR 4796 A
We present J, H, CH_4 short (1.578 micron), CH_4 long (1.652 micron) and
K_s-band images of the dust ring around the 10 Myr old star HR 4796 A obtained
using the Near Infrared Coronagraphic Imager (NICI) on the Gemini-South 8.1
meter Telescope. Our images clearly show for the first time the position of the
star relative to its circumstellar ring thanks to NICI's translucent focal
plane occulting mask. We employ a Bayesian Markov Chain Monte Carlo method to
constrain the offset vector between the two. The resulting probability
distribution shows that the ring center is offset from the star by 16.7+/-1.3
milliarcseconds along a position angle of 26+/-3 degrees, along the PA of the
ring, 26.47+/-0.04 degrees. We find that the size of this offset is not large
enough to explain the brightness asymmetry of the ring. The ring is measured to
have mostly red reflectivity across the JHK_s filters, which seems to indicate
micron-sized grains. Just like Neptune's 3:2 and 2:1 mean-motion resonances
delineate the inner and outer edges of the classical Kuiper Belt, we find that
the radial extent of the HR 4796 A and Fomalhaut rings could correspond to the
3:2 and 2:1 mean-motion resonances of hypothetical planets at 54.7 AU and 97.7
AU in the two systems, respectively. A planet orbiting HR 4796 A at 54.7 AU
would have to be less massive than 1.6 Mjup so as not to widen the ring too
much by stirring.Comment: Accepted to A&A for publication on April 23, 2014 (15 pages, 9
figures, 4 tables
Competition between Anion-Deficient Oxide and Oxyhydride Phases during the Topochemical Reduction of LaSrCoRuO 6
Binary metal hydrides can act as low-temperature reducing agents for complex oxides in the solid state, facilitating the synthesis of anion-deficient oxide or oxyhydride phases. The reaction of LaSrCoRuO6, with CaH2 in a sealed tube yields the face-centered cubic phase LaSrCoRuO3.2H1.9. The reaction with LiH under similar conditions converts LaSrCoRuO6 to a mixture of tetragonal LaSrCoRuO4.8H1.2 and cubic LaSrCoRuO3.3H2.13. The formation of the LaSrCoRuO x H y oxyhydride phases proceeds directly from the parent oxide, with no evidence for anion-deficient LaSrCoRuO6–x intermediates, in contrast with many other topochemically synthesized transition-metal oxyhydrides. However, the reaction between LaSrCoRuO6 and LiH under flowing argon yields a mixture of LaSrCoRuO5 and the infinite layer phase LaSrCoRuO4. The change to all-oxide products when reactions are performed under flowing argon is attributed to the lower hydrogen partial pressure under these conditions. The implications for the reaction mechanism of these topochemical transformations is discussed along with the role of the hydrogen partial pressure in oxyhydride synthesis. Magnetization measurements indicate the LaSrCoRuO x H y phases exhibit local moments on Co and Ru centers, which are coupled antiferromagnetically. In contrast, LaSrCoRuO4 exhibits ferromagnetic behavior with a Curie temperature above 350 K, which can be rationalized on the basis of superexchange coupling between the Co1+ and Ru2+ centers
NICI: combining coronagraphy, ADI, and SDI
The Near-Infrared Coronagraphic Imager (NICI) is a high-contrast AO imager at
the Gemini South telescope. The camera includes a coronagraphic mask and dual
channel imaging for Spectral Differential Imaging (SDI). The instrument can
also be used in a fixed Cassegrain Rotator mode for Angular Differential
Imaging (ADI). While coronagraphy, SDI, and ADI have been applied before in
direct imaging searches for exoplanets. NICI represents the first time that
these 3 techniques can be combined. We present preliminary NICI commissioning
data using these techniques and show that combining SDI and ADI results in
significant gains.Comment: Proc. SPIE, Vol. 7014, 70141Z (2008
Informal Caregiving for Diabetes and Diabetic Complications Among Elderly Americans
Objectives: Little is known regarding the amount of time spent by unpaid caregivers providing help to elderly individuals for disabilities associated with diabetes mellitus (DM). We sought to obtain nationally representative estimates of the time, and associated cost, of informal caregiving provided to the elderly with diabetes, and to determine the complications of DM that contribute most significantly to the subsequent need for informal care. Methods: We estimated multivariable regression models using data from the 1993 Asset and Health Dynamics (AHEAD) Study, a nationally representative survey of people aged 70 or older (N=7,443), to determine the weekly hours of informal caregiving and imputed cost of caregiver time for community-dwelling elderly with and without a diagnosis of DM. Results: Those without DM received an average of 6.1 hours per week of informal care, those with DM taking no medications received 10.5 hours, those with DM taking oral medications received 10.1 hours, and those with DM taking insulin received 14.4 hours of care (P
The crystal and defect structures of polar KBiNb2O7
Funding: Experiments at the Diamond Light Source were performed as part of the Block Allocation Group award “Oxford/Warwick Solid State Chemistry BAG to probe composition-structure– property relationships in solids” (CY25166). Experiments at the ISIS pulsed neutron facility were supported by a beam time allocation from the STFC (RB 2000148). SM thanks Somerville College for an Oxford Ryniker Lloyd scholarship. ‘PSH and WZ thank the National Science Foundation (DMR-2002319) and Welch Foundation (Grant E-1457) for support.KBiNb2O7 was prepared from RbBiNb2O7 by a sequence of cation exchange reactions which first convert RbBiNb2O7 to LiBiNb2O7, before KBiNb2O7 is formed by a further K-for-Li cation exchange. A combination of neutron, synchrotron X-ray and electron diffraction data reveal that KBiNb2O7 adopts a polar, layered, perovskite structure (space group A11m) in which the BiNb2O7 layers are stacked in a (0, ½, z) arrangement, with the K+ cations located in half of the available 10-coordinate interlayer cation sites. The inversion symmetry of the phase is broken by a large displacement of the Bi3+ cations parallel to the y-axis. HAADF-STEM images reveal that KBiNb2O7 exhibits frequent stacking faults which convert the (0, ½, z) layer stacking to (½, 0, z) stacking and vice versa, essentially switching the x- and y-axes of the material. By fitting the complex diffraction peak shape of the SXRD data collected from KBiNb2O7 it is estimated that each layer has approximately a 9% chance of being defective-a high level which is attributed to the lack of cooperative NbO6 tilting in the material, which limits the lattice strain associated with each fault.Publisher PDFPeer reviewe
Cometary Dust in the Debris Disks of HD 31648 and HD 163296: Two ``Baby'' beta Pics
The debris disks surrounding the pre-main sequence stars HD 31648 and HD
163296 were observed spectroscopically between 3 and 14 microns. Both possess a
silicate emission feature at 10 microns which resembles that of the star beta
Pictoris and those observed in solar system comets. The structure of the band
is consistent with a mixture of olivine and pyroxene material, plus an
underlying continuum of unspecified origin. The similarity in both size and
structure of the silicate band suggests that the material in these systems had
a processing history similar to that in our own solar system prior to the time
that the grains were incorporated into comets.Comment: 17 pages, AASTeX, 5 eps figures, accepted for publication in Ap.
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