Advancing the time of ripeness of grapes by the application of methyl 2-(ureidooxy) propionate (a growth retardant)

Methyl 2-(ureidooxy) propionate (MUP), a plant growth retardant, hastened the ripening of grape berries of Vitis vinifera L. cultivars Mataro and Sultana by about 2 weeks and 1 week, respectively. The vines were sprayed with 0.1 % solution of MUP about halfway :through the first rapid growth phase of the fruit and again 2 weeks later. Terminal and lateral shoot growth was inhibited. Ripening of berries was advanced as measured by development of colour, and changes in titratable acid and reducing sugar content. The earlier ripening of the berries may have been due to hormonal changes but the advancement was much greater than that found previously with abscisic acid or ethylene applied during the slow growth stage of berry development.Die Beschleunigung des Reifezeitpunktes von Trauben durch die Anwendung vonMethyl-2-(ureidooxy)-Propionat, einen WachstumsdämpferMethyl-2-(ureidooxy)-Propionat (MUP), welches das Pflanzenwachstum verlangsamt, beschleunigte bei den Vitis-vinifera-Sorten Mataro und Sultana die Beerenreife um etwa 2 Wochen bzw. 1 Woche. Die Reben wurden etwa in der Mitte der ersten raschen Wachstumsphase der Beeren und ein weiteres Mal 2 Wochen später mit einer 0,1%igen MUP-Lösung besprüht. Das terminale und laterale Triebwachstum war gehemmt. Die Beerenreife war beschleunigt, wie die Entwicklung der Beerenfarbe und die Veränderungen im Gehalt an titrierbarer Säure und reduzierenden Zuckern zeigten. Die frühzeitigere Beerenreife könnte auf hormonale Veränderungen zurückgehen; allerdings war die Reife viel stärker beschleunigt als im Fall früherer Versuche, in denen während der langen Wachstumsphase der Beerenentwicklung Abscisinsäure oder Äthylen angewandt worden waren

The pathway to net zero heating in the UK

This is the final version. Available from UKERC via the DOI in this record. The heating of homes is a major contributor to the UK’s greenhouse gas emissions accounting for 13% of total emissions.  This is comparable to the carbon emissions of all petrol and diesel cars in the UK. 2 Meeting the UK government’s net zero emissions goal for 2050 will only be possible by complete decarbonisation of the building stock (both existing and new). While emissions from heating have fallen by 11% since 1990, much of which was driven by efficiency programmes and regulation in the period 2002-2012 3, continuing decarbonisation at this pace would get us to zero emissions from buildings in 235 years and fall far short of meeting the 2050 target

Folding of a donor–acceptor polyrotaxane by using noncovalent bonding interactions

Mechanically interlocked compounds, such as bistable catenanes and bistable rotaxanes, have been used to bring about actuation in nanoelectromechanical systems (NEMS) and molecular electronic devices (MEDs). The elaboration of the structural features of such rotaxanes into macromolecular materials might allow the utilization of molecular motion to impact their bulk properties. We report here the synthesis and characterization of polymers that contain π electron-donating 1,5-dioxynaphthalene (DNP) units encircled by cyclobis(paraquat-p-phenylene) (CBPQT4+), a π electron-accepting tetracationic cyclophane, synthesized by using the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC). The polyrotaxanes adopt a well defined “folded” secondary structure by virtue of the judicious design of two DNP-containing monomers with different binding affinities for CBPQT4+. This efficient approach to the preparation of polyrotaxanes, taken alongside the initial investigations of their chemical properties, sets the stage for the preparation of a previously undescribed class of macromolecular architectures

Gluon distributions in nucleons and pions at a low resolution scale

In this paper we study the gluon distribution functions in nucleons and pions at a low resolution $Q^2$ scale. This is an important issue since parton densities at low $Q^2$ have always been taken as an external input which is adjusted through DGLAP evolution to fit the experimental data at higher scales. Here, in the framework of a model recently developed, it is shown that the hypothetical cloud of {\it neutral} pions surrounding nucleons and pions appears to be responsible for the characteristic valence-like gluon distributions needed at the inital low scale. As an additional result, we get the remarkable prediction that neutral and charged pions have different intrinsic sea flavor contents.Comment: final version to appear in Phys. Rev. D. Discussion on several points enlarge

Feel My Pain: Design and Evaluation of Painpad, a Tangible Device for Supporting Inpatient Self-Logging of Pain

Monitoring patients' pain is a critical issue for clinical caregivers, particularly among staff responsible for providing analgesic relief. However, collecting regularly scheduled pain readings from patients can be difficult and time-consuming for clinicians. In this paper we present Painpad, a tangible device that was developed to allow patients to engage in self-logging of their pain. We report findings from two hospital-based field studies in which Painpad was deployed to a total of 78 inpatients recovering from ambulatory surgery. We find that Painpad results in improved frequency and compliance with pain logging, and that self-logged scores may be more faithful to patients' experienced pain than corresponding scores reported to nurses. We also show that older adults may prefer tangible interfaces over tablet-based alternatives for reporting their pain, and we contribute design lessons for pain logging devices intended for use in hospital settings

Understanding the pain experience in hip and knee osteoarthritis – an OARSI/OMERACT initiative

SummaryObjectiveTo examine the pain experience of people with hip or knee osteoarthritis (OA), particularly changes over time and most distressing features.MethodFocus groups in individuals aged 40+ years with painful hip or knee OA obtained detailed descriptions of OA pain from early to late disease. A modified Patient Generated Index (PGI) was used to assess the features of OA pain that participants found most distressing. Content analysis was performed to examine response patterns; descriptive statistics were used to summarize PGI responses.ResultsMean age of the 143 participants (52 hip OA; 91 knee OA) was 69.5 years (47–92 years); 60.8% were female and 93.7% Caucasian. Participants described two distinct types of pain – a dull, aching pain, which became more constant over time, punctuated increasingly with short episodes of a more intense, often unpredictable, emotionally draining pain. The latter, but not the former, resulted in significant avoidance of social and recreational activities. From PGI responses, distressing pain features were: the pain itself (particularly intense and unpredictable pain) and the pain's impact on mobility, mood and sleep.ConclusionsTwo distinct pain types were identified. Intermittent intense pain, particularly when unpredictable, had the greatest impact on quality of life

An Alternative Method to Obtain the Quark Polarization of the Nucleon

An alternate method is described to extract the quark contribution to the spin of the nucleon directly from the first moment of the deuteron structure function, $g^d_1$. It is obtained without recourse to the use of input on the nucleon wave function from hyperon decays involving the flavor symmetry parameters, F and D. The result for the quark polarization of the nucleon, $\Delta\Sigma_ N,$ is in good agreement with the values of the singlet axial current matrix element, $a_0$, obtained from recent next-to-leading order analyses of current proton, neutron and deuteron data.Comment: 7 pages, 1 figur

Flavor and Charge Symmetry in the Parton Distributions of the Nucleon

Recent calculations of charge symmetry violation(CSV) in the valence quark distributions of the nucleon have revealed that the dominant symmetry breaking contribution comes from the mass associated with the spectator quark system.Assuming that the change in the spectator mass can be treated perturbatively, we derive a model independent expression for the shift in the parton distributions of the nucleon. This result is used to derive a relation between the charge and flavor asymmetric contributions to the valence quark distributions in the proton, and to calculate CSV contributions to the nucleon sea. The CSV contribution to the Gottfried sum rule is also estimated, and found to be small