Research on digital transducer principles. Volume 8 - Electrical conduction mechanisms in metal-semiconductor-polymer thin film structures, 1 July - 30 June 1968

Charge transport mechanism in metal semiconductor polymer thin film

Constraining the primordial initial mass function with stellar archaeology

We present a new near-field cosmological probe of the initial mass function (IMF) of the first stars. Specifically, we constrain the lower-mass limit of the Population III (Pop III) IMF with the total number of stars in large, unbiased surveys of the Milky Way. We model the early star formation history in a Milky Way-like halo with a semi-analytic approach, based on Monte-Carlo sampling of dark matter merger trees, combined with a treatment of the most important feedback mechanisms. Assuming a logarithmically flat Pop III IMF and varying its low mass limit, we derive the number of expected survivors of these first stars, using them to estimate the probability to detect any such Pop III fossil in stellar archaeological surveys. Following our analysis, the most promising region to find possible Pop III survivors is the stellar halo of the Milky Way, which is the best target for future surveys. We find that if no genuine Pop III survivor is detected in a sample size of $4 \times 10^6$ ($2 \times 10^7$) halo stars with well-controlled selection effects, then we can exclude the hypothesis that the primordial IMF extended down below $0.8 M_\odot$ at a confidence level of 68% (99%). With the sample size of the Hamburg/ESO survey, we can tentatively exclude Pop III stars with masses below $0.65 M_\odot$ with a confidence level of 95%, although this is subject to significant uncertainties. To fully harness the potential of our approach, future large surveys are needed that employ uniform, unbiased selection strategies for high-resolution spectroscopic follow-up.Comment: 19 pages, 14 figures, published in MNRA

The Coniston killings

"Mr. Frederick Brooks, a prospector, was murdered by blacks early in August of last year at a lonely spot 80 miles north of Alice Springs and later an attack was made by blacks on a station owner, Mr. William Morton. Mr. Brooks was assailed with spears, tomahawks and boomerangs. Police went in pursuit and in a series of violent encounters 31 blacks were killed.

How an improved implementation of H2 self-shielding influences the formation of massive stars and black holes

High redshift quasars at z>6 have masses up to ~$10^9$ M$_\odot$. One of the pathways to their formation includes direct collapse of gas, forming a supermassive star, precursor of the black hole seed. The conditions for direct collapse are more easily achievable in metal-free haloes, where atomic hydrogen cooling operates and molecular hydrogen (H2) formation is inhibited by a strong external UV flux. Above a certain value of UV flux (J_crit), the gas in a halo collapses isothermally at ~$10^4$ K and provides the conditions for supermassive star formation. However, H2 can self-shield, reducing the effect of photodissociation. So far, most numerical studies used the local Jeans length to calculate the column densities for self-shielding. We implement an improved method for the determination of column densities in 3D simulations and analyse its effect on the value of J_crit. This new method captures the gas geometry and velocity field and enables us to properly determine the direction-dependent self-shielding factor of H2 against photodissociating radiation. We find a value of J_crit that is a factor of two smaller than with the Jeans approach (~2000 J_21 vs. ~4000 J_21). The main reason for this difference is the strong directional dependence of the H2 column density. With this lower value of J_crit, the number of haloes exposed to a flux >J_crit is larger by more than an order of magnitude compared to previous studies. This may translate into a similar enhancement in the predicted number density of black hole seeds.Comment: 14 pages, 12 figures, published in MNRA

Moore-Penrose invertibility in involutory rings: the case aa+=bb+

In this article, we consider Moore-Penrose invertibility in rings with a general involution. Given two von Neumann regular elements a, b in a general ring with an arbitrary involution, we aim to give necessary and sufficient conditions to aa† = bb†. As a special case, EP elements are considered.Fundação para a Ciência e a Tecnologia (FCT)POCT

On the Detection of Supermassive Primordial Stars. II. Blue Supergiants

Supermassive primordial stars in hot, atomically-cooling haloes at $z \sim$ 15 - 20 may have given birth to the first quasars in the universe. Most simulations of these rapidly accreting stars suggest that they are red, cool hypergiants, but more recent models indicate that some may have been bluer and hotter, with surface temperatures of 20,000 - 40,000 K. These stars have spectral features that are quite distinct from those of cooler stars and may have different detection limits in the near infrared (NIR) today. Here, we present spectra and AB magnitudes for hot, blue supermassive primordial stars calculated with the TLUSTY and CLOUDY codes. We find that photometric detections of these stars by the James Webb Space Telescope (JWST) will be limited to $z \lesssim$ 10 - 12, lower redshifts than those at which red stars can be found, because of quenching by their accretion envelopes. With moderate gravitational lensing, Euclid and the Wide-Field Infrared Space Telescope (WFIRST) could detect blue supermassive stars out to similar redshifts in wide-field surveys.Comment: 9 pages, 5 figures, accepted by MNRA

Predicting the locations of possible long-lived low-mass first stars: Importance of satellite dwarf galaxies

The search for metal-free stars has so far been unsuccessful, proving that if there are surviving stars from the first generation, they are rare, they have been polluted, or we have been looking in the wrong place. To predict the likely location of Population~III (Pop~III) survivors, we semi-analytically model early star formation in progenitors of Milky Way-like galaxies and their environments. We base our model on merger trees from the high-resolution dark matter only simulation suite \textit{Caterpillar}. Radiative and chemical feedback are taken into account self-consistently, based on the spatial distribution of the haloes. Our results are consistent with the non-detection of Pop III survivors in the Milky Way today. We find that possible surviving Population III stars are more common in Milky Way satellites than in the main Galaxy. In particular, low mass Milky Way satellites contain a much larger fraction of Pop~III stars than the Milky Way. Such nearby, low mass Milky Way satellites are promising targets for future attempts to find Pop~III survivors, especially for high-resolution, high signal-to-noise spectroscopic observations. We provide the probabilities for finding a Pop~III survivor in the red giant branch phase for all known Milky Way satellites to guide future observations.Comment: 17 pages, 12 figures, 1 table, submitted to MNRA

Identification of Dialect for Eastern and Southwestern Ojibwe Words Using a Small Corpus

The Ojibwe language has several dialects that vary to some degree in both spoken and written form. We present a method of using support vector machines to classify two different dialects (Eastern and Southwestern Ojibwe) using a very small corpus of text. Classification accuracy at the sentence level is 90% across a five-fold cross validation and 72% when the sentence-trained model is applied to a data set of individual words. Our code and the word level data set are released openly at https://github.com/evanperson/OjibweDialect

A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins.

We report an approach to conducting the hydroaminomethylation of diverse α-olefins with a wide range of alkyl, aryl, and heteroarylamines at relatively low temperatures (70-80 °C) and pressures (1.0-3.4 bar) of synthesis gas. This approach is based on simultaneously using two distinct catalysts that are mutually compatible. The hydroformylation step is catalyzed by a rhodium diphosphine complex, and the reductive amination step, which is conducted as a transfer hydrogenation with aqueous, buffered sodium formate as the reducing agent, is catalyzed by a cyclometallated iridium complex. By adjusting the ratio of CO to H2 , we conducted the reaction at one atmosphere of gas with little change in yield. A diverse array of olefins and amines, including hetreroarylamines that do not react under more conventional conditions with a single catalyst, underwent hydroaminomethylation with this new system, and the pharmaceutical ibutilide was prepared in higher yield and under milder conditions than with a single catalyst