Investigations of excitation energy transfer and intramolecular interactions in a nitrogen corded distrylbenzene dendrimer system.

The photophysics of an amino-styrylbenzene dendrimer (A-DSB) system is probed by time-resolved and steady state luminescence spectroscopy. For two different generations of this dendrimer, steady state absorption, emission, and photoluminescence excitation spectra are reported and show that the efficiency of energy transfer from the dendrons to the core is very close to 100%. Ultrafast time-resolved fluorescence measurements at a range of excitation and detection wavelengths suggest rapid (and hence efficient) energy transfer from the dendron to the core. Ultrafast fluorescence anisotropy decay for different dendrimer generations is described in order to probe the energy migration processes. A femtosecond time-scale fluorescence depolarization was observed with the zero and second generation dendrimers. Energy transfer process from the dendrons to the core can be described by a Förster mechanism (hopping dynamics) while the interbranch interaction in A-DSB core was found to be very strong indicating the crossover to exciton dynamics

J.S. Harter K1862 Photo Album

https://digital.kenyon.edu/scrapbooks/1061/thumbnail.jp

The poetic is political….and other notes on engaged scholarship

Instrumental and objectivist logics maintain a hegemonic place in Western scholarship, reasoning skills powerfully equipped to address certain dilemmas even as they may obscure other ways of knowing. In this chapter, we enlarge dominant notions of rationality by offering an aesthetic view of knowledge as vital for engaged communication scholarship. Our interest in aesthetic logics parallels concerns that have led scholars to develop feminist practices of inquiry (e.g., Harding, 1998; Hesse-Biber, 2007), interrogate the aesthetics of representations in West-centric knowledge structures from postcolonial and Subaltern Studies standpoints (e.g., Broadfoot & Munshi, 2007; Dutta, 2007, 2008), focus on autoethnographic and poetic accounts ( e.g., Carr, 2003; Ellingson, 2009), introduce reflexivity and the politics of personhood in the scholarly process ( e.g., Harding, 1991; Reinharz, 1992), and adopt narrative and dialogic understandings of knowledge constructions (e.g., Frank, 2005; Harter, 2005). Loosely coupled, these research trajectories advance alternative rationalities for witnessing and answering salient social issues. We argue for the theoretical and practical incorporation of aesthetic rationalities in engaged scholarship-logics of poss ibility that cultivate individuals \u27 capacities to imagine otherwise. Reimagining scholarly inquiry to reflect and embrace aesthetic logics requires us to rethink our methods of data collection, analysis, and representation and our own roles as researchers and writers . When we resist the art/science dichotomy, opportunities abound for sensemaking and representation that embody aesthetic ways of knowing. Furthermore, rejection of dichotomous thinking opens up possibilities for listening to ways of knowing that lie beyond the realm of Eurocentric knowledge structures (Dutta, in press). Even after the interpretive turn, instrumental and objectivist logics often underlie and sometimes constrain the processes and products of social scientific research (Denzin & Lincoln, 2005). Traditional structures and modes of research offer important but limited conceptualizations of knowing. We can open ourselves to other ways of asking questions that include overt attention to aesthetic sensibilities . We need not reject or abandon traditional modes of research. Instead, we can enlarge the realm of possibilities for what counts as accepted research practices and advance methods for studying the aesthetic nature of communal life (Ellingson, 2009). In this chapter, we develop an understanding of rationality that incorporates imagination, and we explore methodologies that draw on creative sensibilities. We then articul ate the salience of creativity for rendering credible previously subjugated voices, and we articulate its value for engaged communication theory and research

Probabilistic models of information retrieval based on measuring the divergence from randomness

We introduce and create a framework for deriving probabilistic models of Information Retrieval. The models are nonparametric models of IR obtained in the language model approach. We derive term-weighting models by measuring the divergence of the actual term distribution from that obtained under a random process. Among the random processes we study the binomial distribution and Bose--Einstein statistics. We define two types of term frequency normalization for tuning term weights in the document--query matching process. The first normalization assumes that documents have the same length and measures the information gain with the observed term once it has been accepted as a good descriptor of the observed document. The second normalization is related to the document length and to other statistics. These two normalization methods are applied to the basic models in succession to obtain weighting formulae. Results show that our framework produces different nonparametric models forming baseline alternatives to the standard tf-idf model

Antiferromagnetic correlations and impurity broadening of NMR linewidths in cuprate superconductors

We study a model of a d-wave superconductor with strong potential scatterers in the presence of antiferromagnetic correlations and apply it to experimental nuclear magnetic resonance (NMR) results on Zn impurities in the superconducting state of YBCO. We then focus on the contribution of impurity-induced paramagnetic moments, with Hubbard correlations in the host system accounted for in Hartree approximation. We show that local magnetism around individual impurities broadens the line, but quasiparticle interference between impurity states plays an important role in smearing out impurity satellite peaks. The model, together with estimates of vortex lattice effects, provides a semi-quantitative description of the impurity concentration dependence of the NMR line shape in the superconducting state, and gives a qualitative description of the temperature dependence of the line asymmetry. We argue that impurity-induced paramagnetism and resonant local density of states effects are both necessary to explain existing experiments.Comment: 15 pages, 23 figures, submitted to Phys. Rev.

Who I Am: The Meaning of Early Adolescents’ Most Valued Activities and Relationships, and Implications for Self-Concept Research

Self-concept research in early adolescence typically measures young people’s self-perceptions of competence in specific, adult-defined domains. However, studies have rarely explored young people’s own views of valued self-concept factors and their meanings. For two major self domains, the active and the social self, this mixed-methods study identified factors valued most by 526 young people from socioeconomically diverse backgrounds in Ireland (10-12 years), and explored the meanings associated with these in a stratified subsample (n = 99). Findings indicate that self-concept scales for early adolescence omit active and social self factors and meanings valued by young people, raising questions about content validity of scales in these domains. Findings also suggest scales may under-represent girls’ active and social selves; focus too much on some school-based competencies; and, in omitting intrinsically salient self domains and meanings, may focus more on contingent (extrinsic) rather than true (intrinsic) self-esteem

Nonlinear and time-resolved optical study of the 112-type iron-based superconductor parent Ca_(1−x)La_xFeAs_2 across its structural phase transition

The newly discovered 112-type ferropnictide superconductors contain chains of As atoms that break the tetragonal symmetry between the ɑ and b axes. This feature eliminates the need for uniaxial strain that is usually required to stabilize large single domains in the electronic nematic state that exists in the vicinity of magnetic order in the iron-based superconductors. We report detailed structural symmetry measurements of 112-type Ca_(0.73)La_(0.27)FeAs_2 using rotational anisotropy optical second-harmonic generation. This technique is complementary to diffraction experiments and enables a precise determination of the point-group symmetry of a crystal. By combining our measurements with density functional theory calculations, we uncover a strong optical second-harmonic response of bulk electric dipole origin from the Fe and Ca 3d-derived states that enables us to assign C_2 as the crystallographic point group. This makes the 112-type materials high-temperature superconductors without a center of inversion, allowing for the possible mixing of singlet and triplet Cooper pairs in the superconducting state. We also perform pump-probe transient reflectivity experiments that reveal a 4.6-THz phonon mode associated with the out-of-plane motion of As atoms in the FeAs layers. We do not observe any suppression of the optical second-harmonic response or shift in the phonon frequency upon cooling through the reported monoclinic-to-triclinic transition at 58 K. This allows us to identify C_1 as the low-temperature crystallographic point group but suggests that structural changes induced by long-range magnetic order are subtle and do not significantly affect electronic states near the Fermi level

Impact of aerobic and resistance exercise combination on physical self-perceptions and self-esteem in women with obesity with one-year follow-up

The effectiveness of an exercise intervention including both aerobics and resistance training components in improving physical self-perceptions and global self-esteem (GSE) in women with obesity was examined. An experimental design with a one-year follow-up was used. Women with obesity (n = 72) participated in a structured exercise programme for 12 weeks after being randomised into a control and an exercise group. Exercise self-efficacy, body attractiveness, physical strength, sport competence, physical condition, physical self-worth, and GSE were measured at pre-intervention, early intervention, mid-intervention, immediately after the intervention, and five times following programme termination at 1, 3, 6, 9, and 12 months, respectively. Analyses of covariance revealed exercise effects for all of the dependent variables except for body attractiveness. Generally, exercise effects lasted between 6 and 12 months. A 12-week physical exercise programme including aerobic and resistance training components has the potential to improve physical self-perceptions and self-esteem in women with obesity

Nuclear Tetrahedral Symmetry: Possibly Present Throughout the Periodic Table

More than half a century after the fundamental, spherical shell structure in nuclei has been established, theoretical predictions indicate that the shell-gaps comparable or even stronger than those at spherical shapes may exist. Group-theoretical analysis supported by realistic mean-field calculations indicate that the corresponding nuclei are characterized by the $T_d^D$ ('double-tetrahedral') group of symmetry, exact or approximate. The corresponding strong shell-gap structure is markedly enhanced by the existence of the 4-dimensional irreducible representations of the group in question and consequently it can be seen as a geometrical effect that does not depend on a particular realization of the mean-field. Possibilities of discovering the corresponding symmetry in experiment are discussed.Comment: 4 pages in LaTeX and 4 figures in eps forma

How Valid Are Measures of Children’s Self-Concept/ Self-Esteem? Factors and Content Validity in Three Widely Used Scales

Children’s self-esteem/self-concept, a core psychological construct, has been measured in an overwhelming number of studies, and the widespread use of such measures should indicate they have well-established content validity, internal consistency and factor structures. This study, sampling a demographically representative cohort in late childhood/early adolescence in Dublin, Ireland (total n = 651), examined three major self-esteem/self-concept scales designed for late childhood/early adolescence: Piers-Harris Self-Concept Scale for Children 2 (Piers et al. 2002), Self-Description Questionnaire I (Marsh 1992) and Self-Perception Profile for Children (Harter 1985). It also examined findings in light of the salient self factors identified by participants in a linked mixed-methods study. The factor structure of Piers-Harris Self-Concept Scale was not replicated. The Self-Description Questionnaire I and Self-Perception Profile for Children were replicated only in part although in similar ways. In all three scales, a global/ appearance self evaluation factor accounted for the largest variance in factor analyses. Sport/athletic ability, school ability, school enjoyment, maths and reading ability/enjoyment, behaviour, peer popularity, and parent factors were also identified but did not always reflect existing scale structures. Notably, the factors extracted, or items present in these scales, often did not reflect young people’s priorities, such as friendship over popularity, the importance of family and extended family members, and the significance of incremental personal mastery in activities rather than assessing oneself as comparatively good at preferred activities. The findings raise questions about how self-esteem/self-concept scales are used and interpreted in research with children and young people