Bond Length - Bond Valence Relationships for Carbon - Carbon and Carbon - Oxygen Bonds

In the present study, relationships are developed for determining bond orders (also referred to as bond valences or bond numbers) from published bond lengths for carbon-carbon (C-C) and carbon-oxygen (C-O) bonds. The relationships are based on Pauling’s empirical formula s = exp((Ro-R)/b)), where s is the bond order, R is the corresponding bond length, Ro is the unit valence bond length, and b is a fitting parameter. We use a recently derived relationship for the b parameter in terms of the bonding atoms’ published atomic orbital exponents. The resulting equations were checked against published x-ray diffraction (XRD) data for 176 carbon systems with 540 published C-C bond lengths, and 50 oxygen systems having 72 published C-O bond lengths. The C-C and C-O bond length-valence relationships are shown to have sufficient applicability and accuracy for use in any bonding environment, regardless of physical state or oxidation number

Single pilot IFR accident data analysis

The aircraft accident data recorded and maintained by the National Transportation Safety Board for 1964 to 1979 were analyzed to determine what problems exist in the general aviation single pilot instrument flight rules environment. A previous study conducted in 1978 for the years 1964 to 1975 provided a basis for comparison. The purpose was to determine what changes, if any, have occurred in trends and cause-effect relationships reported in the earlier study. The increasing numbers have been tied to measures of activity to produce accident rates which in turn were analyzed in terms of change. Where anomalies or unusually high accident rates were encountered, further analysis was conducted to isolate pertinent patterns of cause factors and/or experience levels of involved pilots. The bulk of the effort addresses accidents in the landing phase of operations. A detailed analysis was performed on controlled/uncontrolled collisions and their unique attributes delineated. Estimates of day vs. night general aviation activity and accident rates were obtained

The Classification of Extragalactic X-ray Jets

The overall classification of X-ray jets has clung to that prevalent in the radio: FRI vs. FRII (including quasars). Indeed, the common perception is that X-ray emission from FRI's is synchrotron emission whereas that from FRII's may be IC/CMB and/or synchrotron. Now that we have a sizable collection of sources with detected X-ray emission from jets and hotspots, it seems that a more unbiased study of these objects could yield additional insights on jets and their X-ray emission. The current contribution is a first step in the process of analyzing all of the relevant parameters for each detected component for the sources collected in the XJET website. This initial effort involves measuring the ratio of X-ray to radio fluxes and evaluating correlations with other jet parameters. For single zone synchrotron X-ray emission, we anticipate that larger values of fx/fr should correlate inversely with the average magnetic field strength (if the acceleration process is limited by loss time equals acceleration time). Beamed IC/CMB X-rays should produce larger values of fx/fr for smaller values of the angle between the jet direction and the line of sight but will also be affected by the low frequency radio spectral index.Comment: 4 pages; to appear in the conference proceedings: "X-Ray Astronomy 2009: Present Status, Multiwavelength Approach and Future Perspectives"; Bologna, Italy, September 2009, Editors: A. Comastri, M. Cappi, L. Angelini, 2010 AIP (in press

Web 2.0 and micro-businesses: An exploratory investigation

This is the author's final version of the article. This article is (c) Emerald Group Publishing and permission has been granted for this version to appear here. Emerald does not grant permission for this article to be further copied/distributed or hosted elsewhere without the express permission from Emerald Group Publishing Limited.This article was chosen as a Highly Commended Award Winner at the Emerald Literati Network Awards for Excellence 2013.Purpose – The paper aims to report on an exploratory study into how small businesses use Web 2.0 information and communication technologies (ICT) to work collaboratively with other small businesses. The study had two aims: to investigate the benefits available from the use of Web 2.0 in small business collaborations, and to characterize the different types of such online collaborations. Design/methodology/approach – The research uses a qualitative case study methodology based on semi-structured interviews with the owner-managers of 12 UK-based small companies in the business services sector who are early adopters of Web 2.0 technologies. Findings – Benefits from the use of Web 2.0 are categorized as lifestyle benefits, internal operational efficiency, enhanced capability, external communications and enhanced service offerings. A 2×2 framework is developed to categorize small business collaborations using the dimensions of the basis for inter-organizational collaboration (control vs cooperation) and the level of Web 2.0 ICT use (simple vs sophisticated). Research limitations/implications – A small number of firms of similar size, sector and location were studied, which limits generalizability. Nonetheless, the results offer a pointer to the likely future use of Web 2.0 tools by other small businesses. Practical implications – The research provides evidence of the attraction and potential of Web 2.0 for collaborations between small businesses. Originality/value – The paper is one of the first to report on use of Web 2.0 ICT in collaborative working between small businesses. It will be of interest to those seeking a better understanding of the potential of Web 2.0 in the small business community.WestFocu

A Cyclical Model of Exchange Rate Volatility

In this paper, we investigate the long run dynamics of the intraday range of the GBP/USD, JPY/USD and CHF/USD exchange rates. We use a non-parametric filter to extract the low frequency component of the intraday range, and model the cyclical deviation of the range from the long run trend as a stationary autoregressive process. We find that the long run trend is time-varying but highly persistent, while the cyclical component is strongly mean reverting. This has important implications for modelling and forecasting volatility over both short and long horizons. As an illustration, we use the cyclical volatility model to generate out-of-sample forecasts of exchange rate volatility for horizons of up to one year under the assumption that the long run trend is fully persistent. As a benchmark, we compare the forecasts of the cyclical volatility model with those of the two-factor intraday range-based EGARCH model of Brandt and Jones (2006). Not only is the cyclical volatility model significantly easier to estimate than the EGARCH model, but it also offers a substantial improvement in out-of-sample forecast performance.Conditional volatility, Intraday range, Hodrick-Prescott filter

Single pilot IFR accident data analysis

The aircraft accident data recorded by the National Transportation and Safety Board (NTSR) for 1964-1979 were analyzed to determine what problems exist in the general aviation (GA) single pilot instrument flight rule (SPIFR) environment. A previous study conducted in 1978 for the years 1964-1975 provided a basis for comparison. This effort was generally limited to SPIFR pilot error landing phase accidents but includes some SPIFR takeoff and enroute accident analysis as well as some dual pilot IFR accident analysis for comparison. Analysis was performed for 554 accidents of which 39% (216) occurred during the years 1976-1979

Motion Analysis Strategy Appropriate for 3D Kinematic Assessment of Children and Adults with Osteogenesis Imperfecta

Human motion analysis provides a quantitative means of assessing whole body and segmental motion of subjects with musculoskeletal pathologies. This chapter describes a low cost motion analysis appropriate for complete three-dimensional (3D) assessment of upper and lower extremity kinematics. The system has been designed to support lower cost outreach efforts that require accuracy and resolution on the order of classical fixed lot systems such as Vicon. The focus of this work addresses the assessment needs typically seen in adults and children with osteogenesis imperfect (OI) experiencing ambulatory and upper extremity challenges

Geologic considerations in underground coal mining system design

Geologic characteristics of coal resources which may impact new extraction technologies are identified and described to aid system designers and planners in their task of designing advanced coal extraction systems for the central Appalachian region. These geologic conditions are then organized into a matrix identified as the baseline mine concept. A sample region, eastern Kentucy is analyzed using both the developed baseline mine concept and the traditional geologic investigative approach