1,455 research outputs found
The effect of solvent and pressure on polycaprolactone solutions for particle and fibre formation
Polycaprolactone (PCL) is a widely used material in many applications to tackle health problems worldwide. Formed micro- or nanosized PCL particles and fibres benefit from a higher surface area to volume ratio and are valuable in those applications, thus there is always a push to achieve smaller diameters. Electrohydrodynamic (EHD) technologies have been at the forefront in the production of polymeric biomaterials, and pressurised gyration (PG) has also enhanced possibilities by its ability to spin comparable fibres at rapid speeds. In this work, PCL microparticles and fibres were separately produced by changing key operating parameters of EHD and PG systems and PCL solution properties. Initially, PCL microparticles were formed by electrospraying with different binary solvent systems, followed by pressurised gyration fibre production with various singular solvents and a pre-optimised binary solvent system. As anticipated, the use of binary systems altered particle morphologies and diameters, while increased pressure and the use of different solvents greatly affected the characteristics of resulting fibres. The morphology of PCL was found to be highly dependent on the solvents and operating parameters of the technology used
Bi2Te1.6S1.4 - a Topological Insulator in the Tetradymite Family
We describe the crystal growth, crystal structure, and basic electrical
properties of Bi2Te1.6S1.4, which incorporates both S and Te in its Tetradymite
quintuple layers in the motif -[Te0.8S0.2]-Bi-S-Bi-[Te0.8S0.2]-. This material
differs from other Tetradymites studied as topological insulators due to the
increased ionic character that arises from its significant S content.
Bi2Te1.6S1.4 forms high quality crystals from the melt and is the S-rich limit
of the ternary Bi-Te-S {\gamma}-Tetradymite phase at the melting point. The
native material is n-type with a low resistivity; Sb substitution, with
adjustment of the Te to S ratio, results in a crossover to p-type and resistive
behavior at low temperatures. Angle resolved photoemission study shows that
topological surface states are present, with the Dirac point more exposed than
it is in Bi2Te3 and similar to that seen in Bi2Te2Se. Single crystal structure
determination indicates that the S in the outer chalcogen layers is closer to
the Bi than the Te, and therefore that the layers supporting the surface states
are corrugated on the atomic scale.Comment: To be published in Physical Review B Rapid Communications 16 douuble
spaced pages. 4 figures 1 tabl
Recommended from our members
IL-27R signalling mediates early viral containment and impacts innate and adaptive immunity after chronic lymphocytic choriomeningitis virus infection
Chronic viral infections represent a major challenge to host's immune response and a unique network of immunological elements, including cytokines, are required for their containment. By using a model persistent infection with the natural murine pathogen lymphocytic choriomeningitis virus clone 13 (LCMV Cl13) we investigated the role of one such cytokine, interleukin 27 (IL-27), in the control of chronic infection. We found that IL-27R signalling promoted control of LCMV Cl13 as early as day 1 and 5 after infection and that il27p28 transcripts were rapidly elevated in multiple subsets of dendritic cells (DCs) and myeloid cells. In particular, plasmacytoid DCs (pDCs), the most potent type-1-interferon (IFN-I) producing cells, significantly increased il27p28 in a TLR7 dependent fashion. Notably, mice deficient in IL-27 specific receptor (R), WSX-1, exhibited a pleiotropy of innate and adaptive immune alterations after chronic LCMV infection, including compromised NK cell cytotoxicity and antibody responses. While, the majority of these immune alterations appeared cell-extrinsic, cell-intrinsic IL-27R was necessary to maintain early pDC numbers, which, alongside lower IFN-I transcription in CD11b+ DCs and myeloid cells, may explain the compromised IFN-I elevation that we observed early after LCMV Cl13 infection in IL-27R-deficient mice. Together these data highlight the critical role of IL-27 in enabling optimal anti-viral immunity early and late after infection with a systemic persistent virus and suggest that a previously unrecognized positive feedback-loop mediated by IL-27 in pDCs might be involved in this process
Radio Recombination Lines at Decametre Wavelengths: Prospects for the Future
This paper considers the suitability of a number of emerging and future
instruments for the study of radio recombination lines (RRLs) at frequencies
below 200 MHz. These lines arise only in low-density regions of the ionized
interstellar medium, and they may represent a frequency-dependent foreground
for next-generation experiments trying to detect H I signals from the Epoch of
Reionization and Dark Ages ("21-cm cosmology"). We summarize existing
decametre-wavelength observations of RRLs, which have detected only carbon
RRLs. We then show that, for an interferometric array, the primary instrumental
factor limiting detection and study of the RRLs is the areal filling factor of
the array. We consider the Long Wavelength Array (LWA-1), the LOw Frequency
ARray (LOFAR), the low-frequency component of the Square Kilometre Array
(SKA-lo), and a future Lunar Radio Array (LRA), all of which will operate at
decametre wavelengths. These arrays offer digital signal processing, which
should produce more stable and better defined spectral bandpasses; larger
frequency tuning ranges; and better angular resolution than that of the
previous generation of instruments that have been used in the past for RRL
observations. Detecting Galactic carbon RRLs, with optical depths at the level
of 10^-3, appears feasible for all of these arrays, with integration times of
no more than 100 hr. The SKA-lo and LRA, and the LWA-1 and LOFAR at the lowest
frequencies, should have a high enough filling factor to detect lines with much
lower optical depths, of order 10^-4 in a few hundred hours. The amount of
RRL-hosting gas present in the Galaxy at the high Galactic latitudes likely to
be targeted in 21-cm cosmology studies is currently unknown. If present,
however, the spectral fluctuations from RRLs could be comparable to or exceed
the anticipated H I signals.Comment: 9 pages; Astron. & Astrophys., in pres
Crystalline Silicate Emission in the Protostellar Binary Serpens--SVS20
We present spatially resolved mid-infrared spectroscopy of the class
I/flat-spectrum protostellar binary system SVS20 in the Serpens cloud core. The
spectra were obtained with the mid-infrared instrument T-ReCS on Gemini-South.
SVS20-South, the more luminous of the two sources, exhibits a mid-infrared
emission spectrum peaking near 11.3 \micron, while SVS20-North exhibits a
shallow amorphous silicate absorption spectrum with a peak optical depth of
. After removal of the the line-of-sight extinction by the
molecular common envelope, the ``protostar-only'' spectra are found to be
dominated by strong amorphous olivine emission peaking near 10 \micron. We also
find evidence for emission from crystalline forsterite and enstatite associated
with both SVS20-S and SVS20-N. The presence of crystalline silicate in such a
young binary system indicates that the grain processing found in more evolved
HAeBe and T Tauri pre-main sequence stars likely begins at a relatively young
evolutionary stage, while mass accretion is still ongoing.Comment: Accepted for publication by The Astrophysical Journa
Beta-delayed-neutron studies of Sb and I performed with trapped ions
Beta-delayed-neutron (n) spectroscopy was performed using the
Beta-decay Paul Trap and an array of radiation detectors. The n
branching ratios and energy spectra for Sb and I were
obtained by measuring the time of flight of recoil ions emerging from the
trapped ion cloud. These nuclei are located at the edge of an isotopic region
identified as having n branching ratios that impact the r-process
abundance pattern around the A~130 peak. For Sb and I,
n branching ratios of 14.6(11)%, 17.6(28)%, and 7.6(28)% were
determined, respectively. The n energy spectra obtained for Sb
and I are compared with results from direct neutron measurements, and
the n energy spectrum for Sb has been measured for the first
time
Foregrounds for observations of the cosmological 21 cm line: II. Westerbork observations of the fields around 3C196 and the North Celestial Pole
In the coming years a new insight into galaxy formation and the thermal
history of the Universe is expected to come from the detection of the highly
redshifted cosmological 21 cm line. The cosmological 21 cm line signal is
buried under Galactic and extragalactic foregrounds which are likely to be a
few orders of magnitude brighter. Strategies and techniques for effective
subtraction of these foreground sources require a detailed knowledge of their
structure in both intensity and polarization on the relevant angular scales of
1-30 arcmin. We present results from observations conducted with the Westerbork
telescope in the 140-160 MHz range with 2 arcmin resolution in two fields
located at intermediate Galactic latitude, centred around the bright quasar
3C196 and the North Celestial Pole. They were observed with the purpose of
characterizing the foreground properties in sky areas where actual observations
of the cosmological 21 cm line could be carried out. The polarization data were
analysed through the rotation measure synthesis technique. We have computed
total intensity and polarization angular power spectra. Total intensity maps
were carefully calibrated, reaching a high dynamic range, 150000:1 in the case
of the 3C196 field. [abridged]Comment: 20 pages, 22 figures, accepted for publication in A&A. A version with
full resolution figures is available at
http://www.astro.rug.nl/~bernardi/NCP_3C196/bernardi.pd
A Spitzer Study of Comets 2P/Encke, 67P/Churyumov-Gerasimenko, and C/2001 HT50 (LINEAR-NEAT)
We present infrared images and spectra of comets 2P/Encke,
67P/Churyumov-Gerasimenko, and C/2001 HT50 (LINEAR-NEAT) as part of a larger
program to observe comets inside of 5 AU from the sun with the Spitzer Space
Telescope. The nucleus of comet 2P/Encke was observed at two vastly different
phase angles (20 degrees and 63 degrees). Model fits to the spectral energy
distributions of the nucleus suggest comet Encke's infrared beaming parameter
derived from the near-Earth asteroid thermal model may have a phase angle
dependence. The observed emission from comet Encke's dust coma is best-modeled
using predominately amorphous carbon grains with a grain size distribution that
peaks near 0.4 microns, and the silicate contribution by mass to the sub-micron
dust coma is constrained to 31%. Comet 67P/Churyumov-Gerasimenko was observed
with distinct coma emission in excess of a model nucleus at a heliocentric
distance of 5.0 AU. The coma detection suggests that sublimation processes are
still active or grains from recent activity remain near the nucleus. Comet
C/2001 HT50 (LINEAR-NEAT) showed evidence for crystalline silicates in the
spectrum obtained at 3.2 AU and we derive a silicate-to-carbon dust ratio of
0.6. The ratio is an order of magnitude lower than that derived for comets
9P/Tempel 1 during the Deep Impact encounter and C/1995 O1 (Hale-Bopp).Comment: Accepted for publication in the Astrophysical Journal 48 pages, 15
figures, 10 table
- …