Radicals in carbonaceous residue deposited on mordenite from methanol

It is shown that control of the degree of coking can lead to the observation of hyperfine structures in the carbonaceous residues deposited from methanol over mordenite (H-MOR) at temperatures relevant to the conversion of methanol to hydrocarbons. EPR measurements of the catalyst samples at various times on stream have been recorded, with a rich hyperfine splitting pattern observed in the early stages of the reaction. Interpretation of the EPR data with the aid of density functional theoretical calculations has afforded the first definitive assignment of the radical cations formed in high temperature coke. The results detail a shortlist of six species: 2,3/2,6/2,7-dimethylnaphthalenium, 2,3,6-trimethylnaphthalenium, 2,3,6,7-tetramethylnaphthalenium, and anthracenium radical cations whose proton hyperfine splitting profiles match the experimental spectra; 2,3,6,7-tetramethylnaphthalenium showed the best agreement. The observation of these particular isomers of polymethylnaphthalene suggest the formation of more highly branched polyaromatic species is less likely within the confines of the H-MOR 12-membered ring channel. These radicals formed when the catalyst is active may constitute key intermediates in the conversion of methanol to light olefins

Access to healthcare for people seeking and refused asylum in Great Britain: a review of evidence

This research report is a review of evidence looking at the barriers people seeking or refused asylum face in trying to access healthcare services in the UK, and what may help them to do so more easily. This report, and the partner report on lived experiences (https://www.equalityhumanrights.com/en/publication-download/lived-experiences-access-healthcare-people-seeking-and-refused-asylum), will be of interest to people who play an important role in delivering healthcare and related support services to people seeking or refused asylum. We have also made recommendations for what changes are needed (https://www.equalityhumanrights.com/en/publication-download/making-sure-people-seeking-and-refused-asylum-can-access-healthcare-what-needs) to make sure that people seeking and refused asylum have full enjoyment of their right to health. This review was carried out by Imperial College London, with primary data provided by Doctors of the World UK

Hot methane line lists for exoplanet and brown dwarf atmospheres

We present comprehensive experimental line lists of methane (CH4) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for the temperatures 300 - 1400 degC at twelve 100 degC intervals spanning the 960 - 5000 cm-1 (2.0 - 10.4 microns) region of the infrared. This range encompasses the dyad, pentad and octad regions, i.e., all fundamental vibrational modes along with a number of combination, overtone and hot bands. Using our CH4 spectra, we have estimated empirical lower state energies (Elow in cm-1) and our values have been incorporated into the line lists along with line positions (cm-1) and calibrated line intensities (S' in cm molecule-1). We expect our hot CH4 line lists to find direct application in the modeling of planetary atmospheres and brown dwarfs.Comment: Supplementary material is provided via the Astrophysical Journal referenc

Participation in Transition(s):Reconceiving Public Engagements in Energy Transitions as Co-Produced, Emergent and Diverse

This paper brings the transitions literature into conversation with constructivist Science and Technology Studies (STS) perspectives on participation for the first time. In doing so we put forward a conception of public and civil society engagement in sustainability transitions as co-produced, relational, and emergent. Through paying close attention to the ways in which the subjects, objects, and procedural formats of public engagement are constructed through the performance of participatory collectives, our approach offers a framework to open up to and symmetrically compare diverse and interconnected forms of participation that make up wider socio-technical systems. We apply this framework in a comparative analysis of four diverse cases of civil society involvement in UK low carbon energy transitions. This highlights similarities and differences in how these distinct participatory collectives are orchestrated, mediated, and subject to exclusions, as well as their effects in producing particular visions of the issue at stake and implicit models of participation and ‘the public’. In conclusion we reflect on the value of this approach for opening up the politics of societal engagement in transitions, building systemic perspectives of interconnected ‘ecologies of participation’, and better accounting for the emergence, inherent uncertainties, and indeterminacies of all forms of participation in transitions

Low-energy electron scattering by tetrahydrofuran

Cross sections for elastic scattering of low-energy electrons by tetrahydrofuran, a prototype for the furanose ring found in the backbone of DNA, have been measured and calculated over a wide energy range, with an emphasis on energies below 6 eV, where previous data are scarce. The measurements employ a thin-aperture version of the relative-flow method, while the calculations employ the Schwinger multichannel method with an extensive treatment of polarization effects. Comparisons with earlier results, both experimental and theoretical, are presented and discussed. A proper accounting for the strong permanent electric dipole of tetrahydrofuran is found to be essential to obtaining reliable cross sections, especially at energies below 5 eV

Comparison of three fluorosis indices in a Namibian community with twice optimum fluoride in the drinking water

KIMIn Otjiwarongo, a town in Namibia with twice the optimum fluoride in the drinking water (1.56 ppm) the Dean (Dean, Arnold and Elvove, 1942), Thylstrup and Fejerskov (Thylstrup and Fejerskov, 1978) and TSIF (Horowitz et al, 1984) indices of fluorosis were compared in permanent teeth of the children aged 11 y living in the region. Fluorosis severety was skewed in all instances to lower scores within each index. With the Thylstrup and Fejerskov and TSIF indices it was possible to compare fluorosis by individual teeth; the former was significantly more sensitive in diagnosis (56 per cent vs 50 per cent prevalence). It is recommended that the aims of a fluorosis investigation be carefully detailed before selecting the fluorosis index to be used. If detailed information on individual teeth related to fluoride ingestion is needed the Thylstrup and Fejerskov index is recommended, especially in areas with raised fluoride intakes where it is anticipated that the fluorosis levels will be mainly in the low levels of severit

Dental caries of 11 to 12 year-old South African children and WHO guidelines for the year 2000

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Reaching older people with PA delivered in football clubs: the reach, adoption and implementation characteristics of the Extra Time Programme.

Background Older adults (OA) represent a core priority group for physical activity and Public Health policy. As a result, significant interest is placed on how to optimise adherence to interventions promoting these approaches. Extra Time (ET) is an example of a national programme of physical activity interventions delivered in professional football clubs for OA aged 55+ years. This paper aims to examine the outcomes from ET, and unpick the processes by which these outcomes were achieved. Methods This paper represents a secondary analysis of data collected during the evaluation of ET. From the 985 OA reached by ET, n=486 adopted the programme and completed post-intervention surveys (typically 12 weeks). We also draw on interview data with 18 ET participants, and 7 staff who delivered the programme. Data were subject to thematic analysis to generate overarching and sub themes. Results Of the 486 participants, the majority 95%, (n= 462) were White British and 59.7% (n=290) were female. Most adopters (65.4%/n=318) had not participated in previous interventions in the host clubs. Social interaction was the most frequently reported benefit of participation (77.2%, n=375). While the reach of the club badge was important in letting people know about the programme, further work enhanced adoption and satisfaction. These factors included (i) listening to participants, (ii) delivering a flexible age-appropriate programme of diverse physical and social activities, (iii) offering activities which satisfy energy drives and needs for learning and (iv) extensive opportunities for social engagement. Conclusions Findings emerging from this study indicate that physical activity and health interventions delivered through professional football clubs can be effective for engaging OA

Affective and evaluative responses to pop music

From reviews published in the “serious” pop music press, twenty recordings were selected which had received consistently favourable appraisals on affective and evaluative bases. A further twenty recordings were selected on the basis of high levels of chart performance but a lack of critical acclaim. Sixty-four subjects rated representative excerpts of these recordings on 11-point scales of either liking or artistic merit. The results indicated significantly lower liking and artistic merit ratings of critically praised excerpts; a positive liking-artistic merit correlation; and some “fragmentation” between affective and evaluative responses. The apparent discrepancy between the attitudes of the music press and subjects' ratings is discussed in terms of the availability and sophistication of evaluation cues