2,752 research outputs found
Plate Fin Heat Exchanger Model with Axial Conduction and Variable Properties
Future superconducting radio frequency (SRF) cavities, as part of Project X
at Fermilab, will be cooled to superfluid helium temperatures by a cryogenic
distribution system supplying cold supercritical helium. To reduce vapor
fraction during the final Joule-Thomson (J-T) expansion into the superfluid
helium cooling bath, counter-flow, plate-fin heat exchangers will be utilized.
Due to their compact size and ease of fabrication, plate-fin heat exchangers
are an effective option. However, the design of compact and high-effectiveness
cryogenic heat exchangers operating at liquid helium temperatures requires
consideration of axial heat conduction along the direction of flow, in addition
to variable fluid properties. Here we present a numerical model that includes
the effects of axial conduction and variable properties for a plate fin heat
exchanger. The model is used to guide design decisions on heat exchanger
material choice and geometry. In addition, the J-T expansion process is modeled
with the heat exchanger to analyze the effect of heat load and cryogenic supply
parameters.Comment: 8 pp. Cryogenic Engineering Conference and International Cryogenic
Materials Conference CEC-ICMC, 13-17 June 2011, Spokane, Washingto
Stability of the iterative solutions of integral equations as one phase freezing criterion
A recently proposed connection between the threshold for the stability of the
iterative solution of integral equations for the pair correlation functions of
a classical fluid and the structural instability of the corresponding real
fluid is carefully analyzed. Direct calculation of the Lyapunov exponent of the
standard iterative solution of HNC and PY integral equations for the 1D hard
rods fluid shows the same behavior observed in 3D systems. Since no phase
transition is allowed in such 1D system, our analysis shows that the proposed
one phase criterion, at least in this case, fails. We argue that the observed
proximity between the numerical and the structural instability in 3D originates
from the enhanced structure present in the fluid but, in view of the arbitrary
dependence on the iteration scheme, it seems uneasy to relate the numerical
stability analysis to a robust one-phase criterion for predicting a
thermodynamic phase transition.Comment: 11 pages, 2 figure
The Thermal Explosion Synthesis of AlNi Monitored by Neutron Thermodiffractometry
The synthesis of AlNi from thermally activated equimolar powder mixtures of aluminium and nickel was monitored in situ and acquired diffraction patterns every 2 s or less. The analysis of diffraction patterns permitted establishment of its kinetics, which could be modeled according to an equation expressed as kt=[α/(1-α)]3/2. From 1530 to an activation energy of 9 ± 2 kJ mol−1 was estimated. Also, the crystallite size evolution on cooling was established to vary from ≈14 nm at 1530 °C to ≈28 nm at 180 °C. Finally, the reaction was found to occur through the melting of aluminium and the subsequent dissolving of nickel to form the polycrystalline single-phase product, AlNi
Atomic force microscopy measurements of topography and friction on dotriacontane films adsorbed on a SiO2 surface
doi:10.1063/1.2060707 (8 pages)We report comprehensive atomic force microscopy (AFM) measurements at room temperature of the nanoscale topography and lateral friction on the surface of thin solid films of an intermediate-length normal alkane, dotriacontane (n-C32H66), adsorbed onto a SiO2 surface. Our topographic and frictional images, recorded simultaneously in the contact mode, reveal a multilayer structure in which one to two layers of molecules adsorb adjacent to the SiO2 surface oriented with their long axis parallel to the interface followed by partial layers of molecules oriented perpendicular to the surface. The thicknesses of the parallel and perpendicular layers that we measured with the AFM agree with those inferred from previous x-ray specular reflectivity measurements on similarly prepared samples. We also observe bulk dotriacontane particles and, in contrast with our previous measurements, are able to determine their location. Above a minimum size, the bulk particles are separated from islands of perpendicularly oriented molecules by regions of exposed parallel layers that most likely extend underneath the particles. We find that the lateral friction is sensitive to the molecular orientation in the underlying crystalline film and can be used effectively with topographic measurements to resolve uncertainties in the film structure. We measure the same lateral friction on top of the bulk particles as on the perpendicular layers, a value that is about 2.5 times smaller than on a parallel layer. Scans on top of parallel layers indicate a constant height but reveal domains having different sublevels of friction. We explain this by the domains having different azimuthal orientations of the molecules.This work was supported by U.S. National Science Foundation under Grant Nos. DMR-0109057 and DMR-0411748, by the Chilean government under FONDECYTGrant Nos. 1010548 and 7010548, and by the Fundacion Andes Grant No. C-13768
Resonant Absorption as Mode Conversion?
Resonant absorption and mode conversion are both extensively studied
mechanisms for wave "absorption" in solar magnetohydrodynamics (MHD). But are
they really distinct? We re-examine a well-known simple resonant absorption
model in a cold MHD plasma that places the resonance inside an evanescent
region. The normal mode solutions display the standard singular resonant
features. However, these same normal modes may be used to construct a ray
bundle which very clearly undergoes mode conversion to an Alfv\'en wave with no
singularities. We therefore conclude that resonant absorption and mode
conversion are in fact the same thing, at least for this model problem. The
prime distinguishing characteristic that determines which of the two
descriptions is most natural in a given circumstance is whether the converted
wave can provide a net escape of energy from the conversion/absorption region
of physical space. If it cannot, it is forced to run away in wavenumber space
instead, thereby generating the arbitrarily small scales in situ that we
recognize as fundamental to resonant absorption and phase mixing. On the other
hand, if the converted wave takes net energy way, singularities do not develop,
though phase mixing may still develop with distance as the wave recedes.Comment: 23 pages, 8 figures, 2 tables; accepted by Solar Phys (July 9 2010
Arachidonic acid, arachidonic/eicosapentaenoic acid ratio, stearidonic acid and eicosanoids are involved in dietary-induced albinism in Senegal sole (Solea senegalensis)
Senegal sole larvae were fed live prey enriched with different amounts of arachidonic acid (ARA, 20:4n-6) and eicosapentaenoic acid (EPA, 20:5n-3) to re-evaluate the effect of these two fatty acids on flatfish pigmentation. Echium oil, a plant derived oil rich in gamma-linolenic acid (GLA, 18:3n-6) and stearidonic acid (SDA, 18:4n-3) was also used as a component of one of the enrichment emulsions. Although ARA content did not have any effect on growth there was a clear influence on pigmentation that correlated clearly with prostaglandin production. Inclusion of Echium oil, on the contrary, exerted a positive effect on pigmentation rate even though dietary ARA levels were as high as in the other emulsions. The relationships between dietary ARA levels and dietary ARA/EPA ratio, prostaglandin production and pigmentation are discussed
Phase transitions in a ferrofluid at magnetic field induced microphase separation
In the presence of a magnetic field applied perpendicular to a thin sample
layer, a suspension of magnetic colloidal particles (ferrofluid) can form
spatially modulated phases with a characteristic length determined by the
competition between dipolar forces and short-range forces opposing density
variations. We introduce models for thin-film ferrofluids in which
magnetization and particle density are viewed as independent variables and in
which the non-magnetic properties of the colloidal particles are described
either by a lattice-gas entropy or by the Carnahan-Starling free energy. Our
description is particularly well suited to the low-particle density regions
studied in many experiments. Within mean-field theory, we find isotropic,
hexagonal and stripe phases, separated in general by first-order phase
boundaries.Comment: 12 pages, RevTex, to appear in PR
Variational theory for a single polyelectrolyte chain revisited
We reconsider the electrostatic contribution to the persistence length,
, of a single, infinitely long charged polymer in the presence of
screening. A Gaussian variational method is employed, taking as the
only variational parameter. For weakly charged and flexible chains, crumpling
occurs at small length scales because conformational fluctuations overcome
electrostatic repulsion. The electrostatic persistence length depends on the
square of the screening length, , as first argued by
Khokhlov and Khachaturian by applying the Odijk-Skolnick-Fixman (OSF) theory to
a string of crumpled blobs. We compare our approach to previous theoretical
works (including variational formulations) and show that the result
found by several authors comes from the improper use of
a cutoff at small length scales. For highly charged and stiff chains, crumpling
does not occur; here we recover the OSF result and validate the perturbative
calculation for slightly bent rods.Comment: 11 pages, 6 figure
Counterion Penetration and Effective Electrostatic Interactions in Solutions of Polyelectrolyte Stars and Microgels
Counterion distributions and effective electrostatic interactions between
spherical macroions in polyelectrolyte solutions are calculated via
second-order perturbation (linear response) theory. By modelling the macroions
as continuous charge distributions that are permeable to counterions,
analytical expressions are obtained for counterion profiles and effective pair
interactions in solutions of star-branched and microgel macroions. The
counterions are found to penetrate stars more easily than microgels, with
important implications for screening of bare macroion interactions. The
effective pair interactions are Yukawa in form for separated macroions, but are
softly repulsive and bounded for overlapping macroions. A one-body volume
energy, which depends on the average macroion concentration, emerges naturally
in the theory and contributes to the total free energy.Comment: 15 pages, 5 figure
Fatty Acid Methyl Esters as Biosolvents of Epoxy Resins: A Physicochemical Study
The C8 to C18 fatty acid methyl esters (FAME) have been compared as solvents for two epoxy resin pre-polymers, bisphenol A diglycidyl ether (DGEBA) and triglycidyl paminophenol ether (TGPA). It was found that the solubilization limits vary according to the ester and that methyl caprylate is the best solvent of both resins. To explain these solubility performances, physical and chemical properties of FAME were studied, such as the Hansen parameters, viscosity, binary diffusion coefficient and vaporization enthalpy. Determination of the physicochemical parameters of FAME was carried out by laboratory experimentations and by calculation from bibliographic data. The Hansen parameters of FAME and epoxy resins pre-polymers were theoretically and experimentally determined. The FAME chain length showed a long dependence on the binary diffusion parameters and kinematic viscosity, which are mass and momentum transport properties. Moreover, the vaporization enthalpy of these compounds was directly correlated with the solubilization limits
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