602 research outputs found

    Synthesis and characterization of new Discotic Polycyclic Aromatic Hydrocarbons and related pyrolytic nanostructures

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    Is it time for integration of surgical skills simulation into the United Kingdom undergraduate medical curriculum? A perspective from King’s College London School of Medicine

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    PURPOSE: Changes in undergraduate medical curricula, combined with reforms in postgraduate education, have training implications for surgical skills acquisition in a climate of reduced clinical exposure. Confidence and prior experience influences the educational impact of learning. Currently there is no basic surgical skills (BSS) programme integrated into undergraduate curricula in the United Kingdom. We explored the role of a dedicated BSS programme for undergraduates in improving confidence and influencing careers in King's College London School of Medicine, and the programme was evaluated. METHODS: A programme was designed in-line with the established Royal College of Surgeons course. Undergraduates were taught four key skills over four weeks: knot-tying, basic-suturing, tying-at-depth and chest-drain insertion, using low-fidelity bench-top models. A Likert-style questionnaire was designed to determine educational value and influence on career choice. Qualitative data was collected. RESULTS: Only 29% and 42% of students had undertaken previous practice in knot-tying and basic suturing, respectively. 96% agreed that skills exposure prior to starting surgical rotations was essential and felt a dedicated course would augment undergraduate training. There was a significant increase in confidence in the practice and knowledge of all skills taught (p<0.01), with a greater motivation to be actively involved in the surgical firm and theatres. CONCLUSION: A simple, structured BSS programme can increase the confidence and motivation of students. Early surgical skills targeting is valuable for students entering surgical, related allied, and even traditionally non-surgical specialties such as general practice. Such experience can increase the confidence of future junior doctors and trainees. We advocate the introduction of a BSS programme into United Kingdom undergraduate curricula

    First examples of neutral rhenium(V) complexes with a novel semi-rigid ligand containing a P,N,N,S donor atom set: Synthesis, characterisation and crystal structure

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    A new PN2S ligand, N-[2-(diphenylphosphino)phenyl]-2-[(S-trityl)acetylamino]ethanamide [Ph-P(Ph2)N2S(Trt)], was synthesised and reacted with ReV precursors. The reaction of both tritylated and detritylated ligands with ReOCl3(PPh3)2 gave the same expected neutral complex [ReO{Ph-P(Ph2)N2S}] (4) in good yield. An unexpected neutral and diamagnetic species, [ReN{Ph-P(Ph2)N2S(Trt)}] (5), has been isolated during the complexation of the tritylated ligand with ReNCl2(PPh3)2. The complexes, characterized by classical spectroscopic methods and X-ray analysis for 4, are the first examples of neutral semi-rigid-PN2S rhenium(V) complexes

    Intercultural Mediation and Accessibility in Heritage

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    This article aims to propose a strategy taking in consideration the accessibility of each European citizen to information in all its forms especially audio-visual Media and Heritage. It is known that interlingual mediators are playing a huge part in the world of Information and Communication with the involving difficulties of common core theory and training. Moreover, technology can be the ideal tool to enhance accessibility. Thus, mobile phone applications can offer sometimes both audio and visual content to Museum visitors as well as sign language and text. This part of our work clarifies the needs and the values of an adapted methodology for training.In addition, this project gives to inter-cultural mediators the opportunity to work and to research on different applications and software programs in screen-titling, dubbing, re-speaking and screen-titling for the Deaf and Hard of Hearing, audio description and to obtain a training at professional agencies as well as to present a final assistance of quality

    Étude statistique et comparative de modĂšles conceptuels hydrologiques pour des bassins versants de la province du QuĂ©bec, Canada

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    La description des processus de transformation des prĂ©cipitations (pluie et neige) en dĂ©bit dans un bassin versant passe par le choix d’un modĂšle hydrologique adĂ©quat. Les modĂšles hydrologiques conceptuels servent Ă  prĂ©dire les dĂ©bits dans les riviĂšres Ă  l’aide de plusieurs paramĂštres, qui n’ont pas toujours une signification physique. Les dĂ©bits doivent ĂȘtre dĂ©terminĂ©s par calibration. Le choix d’une tel modĂšle repose sur son efficacitĂ©, c’est-Ă -dire sa capacitĂ© Ă  fournir des jeux de paramĂštres permettant au modĂšle de donner des simulations satisfaisantes. (Perrin, 2002). La validation est l’étape qui suit la calibration oĂč on s'assure que le modĂšle peut faire des prĂ©dictions exactes et reproductibles en dehors de la pĂ©riode sur laquelle il a Ă©tĂ© calibrĂ© (Vogel, 2003). La mĂ©thode la plus courante pour valider un modĂšle hydrologique sur un bassin versant est d’ajuster les donnĂ©es simulĂ©es avec les mesures de terrain. La structure de modĂšle et leurs paramĂštres associĂ©s ne sont pas uniques. Il peut exister plusieurs reprĂ©sentations mathĂ©matiques, ce qui risque d’influencer la prĂ©cision des rĂ©sultats fournis par le modĂšle. Dans la plupart des applications de modĂšles hydrologiques, les rĂ©ponses simulĂ©es du bassin versant, autres que le dĂ©bit, restent internes (des variables d’état) au modĂšle. Ceci peut rendre discutable la validitĂ© de la description du modĂšle au processus interne du bassin versant. Il existe plusieurs mĂ©thodes pour valider un modĂšle hydrologique (Seibert, 1997) mais il n'existe pas encore de mĂ©thode ou de critĂšre quantitatif dĂ©finitif pour rejeter un modĂšle de bassin versant (Vogel & Sankarasubramanian, 2003). La mĂ©thode de covariance-variance proposĂ©e par Vogel offre une mĂ©thodologie quantitative pour accepter ou rejeter un modĂšle de bassin versant. L’objectif de cette Ă©tude est de s’assurer de la capacitĂ© du modĂšle Ă  dĂ©crire les Ă©changes dans un bassin versant. La mĂ©thode de covariance-variance est basĂ©e sur l’aptitude du modĂšle Ă  reprĂ©senter la covariance des donnĂ©es mĂ©trologiques avec les donnĂ©es de sortie (dĂ©bit) sans passer par l’étape de calibration. La calibration du modĂšle gĂ©nĂšre une erreur inĂ©vitable (Vogel & Sankarasubramanian, 2003). Afin de vĂ©rifier la pertinence de la mĂ©thode de la covariance et sa fiabilitĂ©, nous l’avons appliquĂ©e sur 125 bassins hydrographiques quĂ©bĂ©cois jaugĂ©s par le dĂ©partement de l’expertise hydraulique du QuĂ©bec (DEHQ), en nous servant des modĂšles hydrologiques GR4J (Perrin, Michel, & AndrĂ©assian, Improvement of a parsimonious model for streamflow simulation, 2003) Ă  quatre paramĂštres, qui est couplĂ© avec le module de neige CemaNeige (Valery, 2010), HBV (Lindstrom, Johansson, Persson, Gardelin, & Bergstrom, 1997) Ă  dix paramĂštres, MOHYSE (Fortin & Turcotte, 2007) Ă  dix paramĂštres et HMETS (Martel, Demeester, & Brissette, HMETS- A simple and efficient model for flow forecasting, climate studies and teaching hydrological modelling, 2014) Ă  vingt et un paramĂštres. Pour chaque bassin, une pĂ©riode de 16 ans situĂ©e entre 1980 et 2015 a Ă©tĂ© sĂ©lectionnĂ©e. La dĂ©marche consiste Ă  effectuer un grand nombre de simulations (Monte Carlo) et s’appuie sur les donnĂ©es observĂ©es disponibles (dĂ©bits, prĂ©cipitations, tempĂ©rature
) afin d’explorer exhaustivement l’espace des valeurs acceptables de dĂ©bits obtenues par les quatre modĂšles. Le but est de rĂ©ussir Ă  tirer l’information des donnĂ©es disponibles pour un bassin et d’en dĂ©duire la structure du modĂšle la plus adaptĂ©e. Nos rĂ©sultats montrent que les modĂšle GR4J et HMETS ont pu Ă©tablir une relation entre un ensemble de donnĂ©es simulĂ©es obtenues par la mĂ©thode de Monte-Carlo et l’observation pour tous les bassins, alors que les modĂšles hydrologiques MOHYSE et HBV n’ont pas pu Ă©tablir cette relation pour la majoritĂ© des bassins versants Ă©tudiĂ©s. Ces deux derniers modĂšles ont reprĂ©sentĂ© les bassins versants moins bien que les autres modĂšles

    Unga vuxnas mobiltelefonanvÀndning ur ett aktivitetsperspektiv

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    Bakgrund: Mobiltelefonens ökade anvÀndning bland unga vuxna i samhÀllet har visat pÄ fysiska belastningsskador, stress och distraktion. Syfte: Att genom en litteraturstudie lyfta fram vilken betydelse mobiltelefonanvÀndningen har för unga vuxna ur olika aktivitetsperspektiv. Metod: Studien har gjorts i form av en allmÀn litteraturöversikt. Med hjÀlp av bestÀmda sökord genomfördes litteratursökning i fem olika databaser, vilket resulterade i 12 artiklar. Data analyserades genom en kvalitativ innehÄllsanalys. Resultat: Trots att mobiltelefonen bidrar till en större sÀkerhet och trygghetskÀnsla visar resultatet pÄ övervÀgande negativa effekter pÄ mÀnniskors hÀlsa i form av belastningsskador, bristande koncentration- och uppmÀrksmhetsförmÄgor i trafiken samt psykiska pÄfrestningar. Konklusion: Eftersom studien visar att mobiltelefonanvÀndning utgör en hÀlsorisk för unga vuxna, behövs det ytterligare forskning inom detta omrÄde för att öka förstÄelse för hur mobilanvÀndning pÄverkar unga vuxna ur ett aktivitetsperspektiv
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