Swelling of particle-encapsulating random manifolds

We study the statistical mechanics of a closed random manifold of fixed area and fluctuating volume, encapsulating a fixed number of noninteracting particles. Scaling analysis yields a unified description of such swollen manifolds, according to which the mean volume gradually increases with particle number, following a single scaling law. This is markedly different from the swelling under fixed pressure difference, where certain models exhibit criticality. We thereby indicate when the swelling due to encapsulated particles is thermodynamically inequivalent to that caused by fixed pressure. The general predictions are supported by Monte Carlo simulations of two particle-encapsulating model systems -- a two-dimensional self-avoiding ring and a three-dimensional self-avoiding fluid vesicle. In the former the particle-induced swelling is thermodynamically equivalent to the pressure-induced one whereas in the latter it is not.Comment: 8 pages, 6 figure

The Potential of Restarts for ProbSAT

This work analyses the potential of restarts for probSAT, a quite successful algorithm for k-SAT, by estimating its runtime distributions on random 3-SAT instances that are close to the phase transition. We estimate an optimal restart time from empirical data, reaching a potential speedup factor of 1.39. Calculating restart times from fitted probability distributions reduces this factor to a maximum of 1.30. A spin-off result is that the Weibull distribution approximates the runtime distribution for over 93% of the used instances well. A machine learning pipeline is presented to compute a restart time for a fixed-cutoff strategy to exploit this potential. The main components of the pipeline are a random forest for determining the distribution type and a neural network for the distribution's parameters. ProbSAT performs statistically significantly better than Luby's restart strategy and the policy without restarts when using the presented approach. The structure is particularly advantageous on hard problems.Comment: Eurocast 201

Stability of Quasicrystals Composed of Soft Isotropic Particles

Quasicrystals whose building blocks are of mesoscopic rather than atomic scale have recently been discovered in several soft-matter systems. Contrary to metallurgic quasicrystals whose source of stability remains a question of great debate to this day, we argue that the stability of certain soft-matter quasicrystals can be directly explained by examining a coarse-grained free energy for a system of soft isotropic particles. We show, both theoretically and numerically, that the stability can be attributed to the existence of two natural length scales in the pair potential, combined with effective three-body interactions arising from entropy. Our newly gained understanding of the stability of soft quasicrystals allows us to point at their region of stability in the phase diagram, and thereby may help control the self-assembly of quasicrystals and a variety of other desired structures in future experimental realizations.Comment: Revised abstract, more detailed explanations, and better images of the numerical minimization of the free energ

Exact Nonperturbative Unitary Amplitudes for 1->N Transitions

I present an extension to arbitrary N of a previously proposed field theoretic model, in which unitary amplitudes for $1->8$ processes were obtained. The Born amplitude in this extension has the behavior $A(1->N)^{tree}\ =\ g^{N-1}\ N!$ expected in a bosonic field theory. Unitarity is violated when $|A(1->N)|>1$, or when $N>\N_crit\simeq e/g.$ Numerical solutions of the coupled Schr\"odinger equations shows that for weak coupling and a large range of N>\ncrit, the exact unitary amplitude is reasonably fit by a factorized expression |A(1->N)| \sim (0.73 /N) \cdot \exp{(-0.025/\g2)}. The very small size of the coefficient 1/\g2 , indicative of a very weak exponential suppression, is not in accord with standard discussions based on saddle point analysis, which give a coefficient $\sim 1.\$ The weak dependence on $N$ could have experimental implications in theories where the exponential suppression is weak (as in this model). Non-perturbative contributions to few-point correlation functions in this theory would arise at order $K\ \simeq\ \left((0.05/\g2)+ 2\ ln{N}\right)/ \ ln{(1/\g2)}$in an expansion in powers of$\g2.$Comment: 11 pages, 3 figures (not included

Excitonic Funneling in Extended Dendrimers with Non-Linear and Random Potentials

The mean first passage time (MFPT) for photoexcitations diffusion in a funneling potential of artificial tree-like light-harvesting antennae (phenylacetylene dendrimers with generation-dependent segment lengths) is computed. Effects of the non-linearity of the realistic funneling potential and slow random solvent fluctuations considerably slow down the center-bound diffusion beyond a temperature-dependent optimal size. Diffusion on a disordered Cayley tree with a linear potential is investigated analytically. At low temperatures we predict a phase in which the MFPT is dominated by a few paths.Comment: 4 pages, 4 figures, To be published in Phys. Rev. Let

Disorder and Funneling Effects on Exciton Migration in Tree-Like Dendrimers

The center-bound excitonic diffusion on dendrimers subjected to several types of non-homogeneous funneling potentials, is considered. We first study the mean-first passage time (MFPT) for diffusion in a linear potential with different types of correlated and uncorrelated random perturbations. Increasing the funneling force, there is a transition from a phase in which the MFPT grows exponentially with the number of generations $g$, to one in which it does so linearly. Overall the disorder slows down the diffusion, but the effect is much more pronounced in the exponential compared to the linear phase. When the disorder gives rise to uncorrelated random forces there is, in addition, a transition as the temperature $T$ is lowered. This is a transition from a high-$T$ regime in which all paths contribute to the MFPT to a low-$T$ regime in which only a few of them do. We further explore the funneling within a realistic non-linear potential for extended dendrimers in which the dependence of the lowest excitonic energy level on the segment length was derived using the Time-Dependent Hatree-Fock approximation. Under this potential the MFPT grows initially linearly with $g$ but crosses-over, beyond a molecular-specific and $T$-dependent optimal size, to an exponential increase. Finally we consider geometrical disorder in the form of a small concentration of long connections as in the {\it small world} model. Beyond a critical concentration of connections the MFPT decreases significantly and it changes to a power-law or to a logarithmic scaling with $g$, depending on the strength of the funneling force.Comment: 13 pages, 9 figure

Nitrogen-vacancy singlet manifold ionization energy

The singlet states of the negatively-charged nitrogen-vacancy centers in diamond play a key role in its optical spin control and readout. In this work, the hitherto unknown ionization energy of the singlet is measured experimentally and found to be between 1.91-2.25 eV. This is obtained by analyzing photoluminescence measurements incorporating spin control and NV charge state differentiation, along with simulations based on the nitrogen-vacancy's master equation. This work establishes a protocol for a more accurate estimate of this ionization energy, which can possibly lead to improved read-out methods

Predictions for the Cosmogenic Neutrino Flux in Light of New Data from the Pierre Auger Observatory

The Pierre Auger Observatory (PAO) has measured the spectrum and composition of the ultrahigh energy cosmic rays with unprecedented precision. We use these measurements to constrain their spectrum and composition as injected from their sources and, in turn, use these results to estimate the spectrum of cosmogenic neutrinos generated in their propagation through intergalactic space. We find that the PAO measurements can be well fit if the injected cosmic rays consist entirely of nuclei with masses in the intermediate (C, N, O) to heavy (Fe, Si) range. A mixture of protons and heavier species is also acceptable but (on the basis of existing hadronic interaction models) injection of pure light nuclei (p, He) results in unacceptable fits to the new elongation rate data. The expected spectrum of cosmogenic neutrinos can vary considerably, depending on the precise spectrum and chemical composition injected from the cosmic ray sources. In the models where heavy nuclei dominate the cosmic ray spectrum and few dissociated protons exceed GZK energies, the cosmogenic neutrino flux can be suppressed by up to two orders of magnitude relative to the all-proton prediction, making its detection beyond the reach of current and planned neutrino telescopes. Other models consistent with the data, however, are proton-dominated with only a small (1-10%) admixture of heavy nuclei and predict an associated cosmogenic flux within the reach of upcoming experiments. Thus a detection or non-detection of cosmogenic neutrinos can assist in discriminating between these possibilities.Comment: 10 pages, 7 figure