Optical bulk-boundary dichotomy in a quantum spin Hall insulator

The bulk-boundary correspondence is a key concept in topological quantum materials. For instance, a quantum spin Hall insulator features a bulk insulating gap with gapless helical boundary states protected by the underlying Z2 topology. However, the bulk-boundary dichotomy and distinction are rarely explored in optical experiments, which can provide unique information about topological charge carriers beyond transport and electronic spectroscopy techniques. Here, we utilize mid-infrared absorption micro-spectroscopy and pump-probe micro-spectroscopy to elucidate the bulk-boundary optical responses of Bi4Br4, a recently discovered room-temperature quantum spin Hall insulator. Benefiting from the low energy of infrared photons and the high spatial resolution, we unambiguously resolve a strong absorption from the boundary states while the bulk absorption is suppressed by its insulating gap. Moreover, the boundary absorption exhibits a strong polarization anisotropy, consistent with the one-dimensional nature of the topological boundary states. Our infrared pump-probe microscopy further measures a substantially increased carrier lifetime for the boundary states, which reaches one nanosecond scale. The nanosecond lifetime is about one to two orders longer than that of most topological materials and can be attributed to the linear dispersion nature of the helical boundary states. Our findings demonstrate the optical bulk-boundary dichotomy in a topological material and provide a proof-of-principal methodology for studying topological optoelectronics.Comment: 26 pages, 4 figure

Animal carcass- and wood-derived biochars improved nutrient bioavailability, enzyme activity, and plant growth in metal-phthalic acid ester co-contaminated soils: A trial for reclamation and improvement of degraded soils

Reclamation of degraded soils such as those with low organic carbon content and soils co-contaminated with toxic elements and phthalic acid esters (PAEs) is of great concern. Little is known about the efficiency of plantand animal-derived biochars for improving plant growth and physicochemical and biological properties of co-contaminated soils, particularly under low content of organic matter. Hence, a pot trial was carried out by growing pak choi (Brassica chinensis L.) to assess the influence of different doses (0, 0.5, 1, 2, and 4%) of animal (pig carcass) and wood (Platanus orientalis) derived biochars on soil properties, nutrient availabilities, plant growth, and soil enzyme activities in two soils containing low (LOC) and high (HOC) organic carbon contents and co-contaminated with di-(2-ethylhexyl) phthalic acid (DEHP) and cadmium (Cd). Biochar applications improved pH, salinity, carbon content, and cation exchange capacity of both soils. Addition of biochars significantly increased the bioavailability and uptake of phosphorus and potassium in the plants in both soils with greater effects from pig biochar than wood biochar. Biochar additions also significantly enhanced urease, sucrase, and catalase activities, but suppressed acid phosphatase activity in both soils. The impact of pig biochar was stronger on urease and acid phosphatase, while the wood biochar was more effective with sucrase and catalase activities. The biomass yield of pak choi was significantly increased after biochar addition to both soils, especially in 2% pig biochar treatment in the LOC soil. The positive response of soil enzymes activities and plant growth for biochar addition to the Cd and DEHP co-contaminated soils indicate that both biochars, particularly the pig biochar can mitigate the risk of these pollutants and prove to be eco-friendly and low-cost amendments for reclaiming these degraded soils

High acetylene/ethylene separation in a microporous zinc( ii

A novel zinc(II) metal-organic framework UTSA-67a with narrow one-dimensional (1D) pore channels and inner cages of moderate size has been developed for highly selective separation of C2H2/C2H4 mixtures at room temperature

Large room-temperature magnetoresistance in van der Waals ferromagnet/semiconductor junctions

The magnetic tunnel junction (MTJ) is the core component in memory technologies, such as the magnetic random-access memory, magnetic sensors and programmable logic devices. In particular, MTJs based on two-dimensional (2D) van der Waals (vdW) heterostructures offer unprecedented opportunities for low power consumption and miniaturization of spintronic devices. However, their operation at room temperature remains a challenge. Here, we report a large tunnel magnetoresistance (TMR) of up to 85% at room temperature (T = 300 K) in vdW MTJs based on a thin (< 10 nm) semiconductor spacer WSe2 layer embedded between two Fe3GaTe2 electrodes with intrinsic above-room-temperature ferromagnetism. The TMR in the MTJ increases with decreasing temperature up to 164% at T = 10 K. The demonstration of TMR in ultra-thin MTJs at room-temperature opens a realistic and promising route for next-generation spintronic applications beyond the current state of the art

A statistical method for excluding non-variable CpG sites in high-throughput DNA methylation profiling

<p>Abstract</p> <p>Background</p> <p>High-throughput DNA methylation arrays are likely to accelerate the pace of methylation biomarker discovery for a wide variety of diseases. A potential problem with a standard set of probes measuring the methylation status of CpG sites across the whole genome is that many sites may not show inter-individual methylation variation among the biosamples for the disease outcome being studied. Inclusion of these so-called "non-variable sites" will increase the risk of false discoveries and reduce statistical power to detect biologically relevant methylation markers.</p> <p>Results</p> <p>We propose a method to estimate the proportion of non-variable CpG sites and eliminate those sites from further analyses. Our method is illustrated using data obtained by hybridizing DNA extracted from the peripheral blood mononuclear cells of 311 samples to an array assaying 1505 CpG sites. Results showed that a large proportion of the CpG sites did not show inter-individual variation in methylation.</p> <p>Conclusions</p> <p>Our method resulted in a substantial improvement in association signals between methylation sites and outcome variables while controlling the false discovery rate at the same level.</p