Rheological Behavior of a Dispersion of Small Lipid Bilayer Vesicles

Rheological behavior of a dispersion of small nearly-unilamellar phospholipid bilayer vesicles has been investigated. We conducted steady-state shear experiments and linear viscoelastic experiments. In the dilute and semidilute regime the rheological behavior is similar to that of a hard-sphere dispersion as reported in the literature for viscoelastic measurements, but now also observed in steady shear experiments. The effect of the main acyl-chain phase transition, taking place at 23 °C, can be described with an increase of the effective volume fraction. As a result, with temperature variation one can obtain effective volume fractions larger than the maximum packing fraction for hard spheres. Near and above the maximum packing fraction a dynamic yield stress ty and a frequency independent storage modulus G' develop. In this concentration regime the rheological behavior is determined by the interplay between vesicle deformation and the intervesicle interaction, and so far, there is no indication which phenomenon is dominant. A comparison with recently reported measurements suggests that G' is proportional to a-3, where a is the vesicle radius. Furthermore, we show that ty = γcG' which is in agreement with theory. Here tγ is the dynamic yield stress and γc the critical strain which indicates the transition to nonlinear behavior in a viscoelastic experiment. There is a striking resemblance between our high concentration results and those reported in literature for vesicles in the so-called onion phase. To the best of our knowledge this is the first rheological study for concentrated nearly-unilamellar vesicle dispersions with volume fraction and temperature as variables

Phase diagram of three-leg ladders at strong coupling along the rungs

A phase diagram of the t-J three-leg ladder as a function of hole dopping is derived in the limit where the coupling parameters along the rungs, $t_{\perp}$ and $J_{\perp}$, are taken to be much larger than those along the legs, $t_{||}$ and $J_{||}$ At large exchange coupling along the rungs, $J_{\perp}/t_{\perp}> 3 / \sqrt{2}$, there is a transition from a low-dopping Luttinger liquid phase into a Luther-Emery liquid at a critical hole concentration $n_{crit}\approx 1/3$. In the opposite case, $J_{\perp}/t_{\perp}< 3 / \sqrt{2}$, there as a sequence of three Luttinger liquid phases (LLI, LLII and LLIII) as a function of hole dopping.Comment: 9 pages, 15 figure

Data access and integration in the ISPIDER proteomics grid

Grid computing has great potential for supporting the integration of complex, fast changing biological data repositories to enable distributed data analysis. One scenario where Grid computing has such potential is provided by proteomics resources which are rapidly being developed with the emergence of affordable, reliable methods to study the proteome. The protein identifications arising from these methods derive from multiple repositories which need to be integrated to enable uniform access to them. A number of technologies exist which enable these resources to be accessed in a Grid environment, but the independent development of these resources means that significant data integration challenges, such as heterogeneity and schema evolution, have to be met. This paper presents an architecture which supports the combined use of Grid data access (OGSA-DAI), Grid distributed querying (OGSA-DQP) and data integration (AutoMed) software tools to support distributed data analysis. We discuss the application of this architecture for the integration of several autonomous proteomics data resources

A counter-rotating Couette apparatus to study deformation of a sub-millimeter sized particle in shear flow

We describe a new counter-rotating Couette apparatus that has been developed for deformation studies of single sub-millimeter sized particles in shear flow. New features are the adaption to the low viscosities of water-based systems and temperature control of the device. The inner to outer radius ratio of the cylinders used is 0.9785 and the height to width aspect ratio of the gap is 4.0, while the inner radius is 100 mm. Because of the limited particle size a high mechanical accuracy of the Couette geometry is necessary. The swing of the inner cylinder is less than 2 μm and that of the outer cylinder less than 4 μm. We achieved this by carefully choosing the design parameters of the aerostatic bearing and the coupling between cylinder and motor unit. Furthermore, special drive units give a shear rate resolution of 0.018 s−1, while the maximum shear rate is 100 s−1. For a liquid viscosity on the order of 1 mPas the effective maximum shear rate is 30 s−1. We have shown that deformations as small as (L−B)/(L+B) ≈ 0.01 of giant bilayer vesicles (typical radius 10 μm) with length L and width B can be observed with our device

Excitation Spectra and Thermodynamic Response of Segmented Heisenberg Spin Chains

The spectral and thermodynamic response of segmented quantum spin chains is analyzed using a combination of numerical techniques and finite-size scaling arguments. Various distributions of segment lengths are considered, including the two extreme cases of quenched and annealed averages. As the impurity concentration is increased, it is found that (i) the integrated spectral weight is rapidly reduced, (ii) a pseudo-gap feature opens up at small frequencies, and (iii) at larger frequencies a discrete peak structure emerges, dominated by the contributions of the smallest cluster segments. The corresponding low-temperature thermodynamic response has a divergent contribution due to the odd-site clusters and a sub-dominant exponentially activated component due to the even-site segments whose finite-size gap is responsible for the spectral weight suppression at small frequencies. Based on simple scaling arguments, approximate low-temperature expressions are derived for the uniform susceptibility and the heat capacity. These are shown to be in good agreement with numerical solutions of the Bethe ansatz equations for ensembles of open-end chains.Comment: RevTex, 9 pages with 6 figure

33000 Photons per MeV from Mixed (Lu0.75Y0.25)3Al5O12:Pr Scintillator Crystals

(LuxY1-x)3Al5O12:Pr (x = 0.25, 0.50, 0.75) crystals have been grown by the Czochralski method and their scintillation properties have been examined. Compared to the well-respected LuAG:Pr scintillator, which has so extensively been studied in the recent years, the new mixed LuYAG:Pr crystals display markedly higher light yields, regardless of the value of x. In particular, (Lu0.75Y0.25)3Al5O12:0.2%Pr characterized by a yield of 33000 ph/MeV, an energy resolution of 4.4% (at 662 keV), and a density of 6.2 g/cm3, seems to be an ideal candidate to supercede Lu3Al5O12:0.2%Pr (19000 ph/MeV, 4.6%, 6.7 g/cm3) in various applications. The observed enhancement of light output following the partial substitution of lutetium by yttrium is most probably related to some specific differences in distributions of shallow traps in particular materials

Impurities and orbital dependent superconductivity in Sr_2RuO_4

There now exists a wealth of experimental evidence that Sr_2RuO_4 is an odd-parity superconductor. Experiments further indicate that among the bands stemming from the Ru {xy,xz,yz} orbitals, the portion of the Fermi surface arising from the xy orbitals exhibits a much larger gap than the portions of the Fermi surface arising from the {xz,yz} orbitals. In this paper the role of impurities on such an orbital dependent superconducting state is examined within the Born approximation. In contrast to expected results for a nodeless p-wave superconductor the unique nature of the superconducting state in Sr_2RuO_4 implies that a low concentration of impurities strongly influences the low temperature behavior.Comment: 5 pages 3 figure

Spectroscopy and Thermoluminescence of LuAlO3:Ce

The present status of the LuAlO3:Ce scintillator is reviewed. Scintillation mechanism of this material is based on capture by Ce3+ of holes and then electrons from their respective bands. Results of spectroscopic and thermoluminescence experiments are presented to support this model

Forages for Conservation and Improved Soil Quality

Forages provide several soil benefits, including reduced soil erosion, reduced water runoff, improved soil physical properties, increased soil carbon, increased soil biologic activity, reduced soil salinity, and improved land stabilization and restoration when grown continuously or as part of a crop rotation. Ongoing research and synthesis of knowledge have improved our understanding of how forages alter and protect soil resources, thus providing producers, policymakers, and the general public information regarding which forage crops are best suited for a specific area or use (e.g. hay, grazing or bioenergy feedstock). Forages can be produced in forestland, range, pasture, and cropland settings. These land use types comprise 86% of non-Federal United States rural lands (Table 12.1). In the United States, active forage production occurs on 22.6 million ha and is used for hay, haylage, grass silage, and greenchop (Table 12.2). Forages are used as cover crops in several production systems, and approximately 4.2 million ha were recently planted in cover crops (Table 12.3). Currently, the highest cover crop use rates, as a percentage of total cropland within a given state, occur in the northeastern United States. Globally, permanent meadows and pastures account for over 3.3 billion ha, greater than arable land and permanent crops combined (Table 12.4). Within all regions of the world, except Europe, permanent meadows and pastures are a greater proportion of land cover than permanent crops. Pasture management information and resources are available for countries around the world (FAO 2017a,b). As seen in Tables 12.1–12.4, forages are used globally and can provide soil benefits across varied soil and climate types

Single hole dynamics in the t-J model on two- and three-leg ladders

The dynamics of a single hole in the t-J model on two- (2LL) and three- (3LL) leg ladders is studied using a recently developed quantum Monte Carlo algorithm. For the 2LL it is shown that in addition to the most pronounced features of the spectral function, well described by the limit of strong coupling along the rungs, a clear shadow band appears in the antibonding channel. Moreover, both the bonding band and its shadow have a finite quasiparticle (QP) weight in the thermodynamic limit. For strong coupling along the rungs of the 3LL, the low-energy spectrum in the antisymmetric channel is similar to a one-dimensional chain, whereas in the two symmetric channels it resembles the 2LL. The QP weight vanishes in the antisymmetric channel, but is finite in the symmetric one