Exo-hydrogenated Single Wall Carbon Nanotubes

An extensive first-principles study of fully exo-hydrogenated zigzag (n,0) and armchair (n,n) single wall carbon nanotubes (C$_n$H$_n$), polyhedral molecules including cubane, dodecahedrane, and C$_{60}$H$_{60}$ points to crucial differences in the electronic and atomic structures relevant to hydrogen storage and device applications. C$_n$H$_n$'s are estimated to be stable up to the radius of a (8,8) nanotube, with binding energies proportional to 1/R. Attaching a single hydrogen to any nanotube is always exothermic. Hydrogenation of zigzag nanotubes is found to be more likely than armchair nanotubes with similar radius. Our findings may have important implications for selective functionalization and finding a way of separating similar radius nanotubes from each other.Comment: 5 pages, 4 postscript figures, Revtex file, To be appear in Physical Review

Impurity and interface bound states in dx2−y2+idxyd_{x^2-y^2}+id_{xy} and px+ipyp_x+ip_y superconductors

Motivated by recent discoveries of novel superconductors such as Na$_x$CoO$_2\cdot y$H$_2$O and Sr$_2$RuO$_4$, we analysize features of quasi-particle scattering due to impurities and interfaces for possible gapful $d_{x^2-y^2}+id_{xy}$ and $p_x+ip_y$ Cooper pairing. A bound state appears near a local impurity, and a band of bound states form near an interface. We obtained analytically the bound state energy, and calculated the space and energy dependent local density of states resolvable by high-resolution scanning tunnelling microscopy. For comparison we also sketch results of impurity and surface states if the pairing is nodal p- or d-wave.Comment: 4 pages, 4 figure

Palaeoproterozoic magnesite: lithological and isotopic evidence for playa/sabkha environments

Magnesite forms a series of 1- to 15-m-thick beds within the approximate to2.0 Ga (Palaeoproterozoic) Tulomozerskaya Formation, NW Fennoscandian Shield, Russia. Drillcore material together with natural exposures reveal that the 680-m-thick formation is composed of a stromatolite-dolomite-'red bed' sequence formed in a complex combination of shallow-marine and non-marine, evaporitic environments. Dolomite-collapse breccia, stromatolitic and micritic dolostones and sparry allochemical dolostones are the principal rocks hosting the magnesite beds. All dolomite lithologies are marked by delta C-13 values from +7.1 parts per thousand to +11.6 parts per thousand (V-PDB) and delta O-18 ranging from 17.4 parts per thousand to 26.3 parts per thousand (V-SMOW). Magnesite occurs in different forms: finely laminated micritic; stromatolitic magnesite; and structureless micritic, crystalline and coarsely crystalline magnesite. All varieties exhibit anomalously high delta C-13 values ranging from +9.0 parts per thousand to +11.6 parts per thousand and delta O-18 values of 20.0-25.7 parts per thousand. Laminated and structureless micritic magnesite forms as a secondary phase replacing dolomite during early diagenesis, and replaced dolomite before the major phase of burial. Crystalline and coarsely crystalline magnesite replacing micritic magnesite formed late in the diagenetic/metamorphic history. Magnesite apparently precipitated from sea water-derived brine, diluted by meteoric fluids. Magnesitization was accomplished under evaporitic conditions (sabkha to playa lake environment) proposed to be similar to the Coorong or Lake Walyungup coastal playa magnesite. Magnesite and host dolostones formed in evaporative and partly restricted environments; consequently, extremely high delta C-13 values reflect a combined contribution from both global and local carbon reservoirs. A C- 13-rich global carbon reservoir (delta C-13 at around +5 parts per thousand) is related to the perturbation of the carbon cycle at 2.0 Ga, whereas the local enhancement in C-13 (up to +12 parts per thousand) is associated with evaporative and restricted environments with high bioproductivity

The Dead Butler revisited: grammatical accuracy and clarity in the English Primary Curriculum 2013–2014

This paper is an analysis of the strengths and weaknesses of the grammatical description and advice contained in the new National Curriculum documentation from 2013, focusing on key stages 1 and 2. It builds on previous analyses of deficiencies in the systems of grammar and the materials in earlier incarnations of the National Curriculum. It suggests that there have been advances in the accuracy with which grammar terms are used and illustrated, although there is still no coherent overall view of what grammar is, nor a fully consistent approach to describing language. In addition, the lack of any pedagogic guidance save the most basic suggests that knowledge about language may continue to be taught in a way which is incompatible with real understanding and more in line with prescriptivist approaches

Shot noise in normal metal-d-wave superconducting junctions

We present theoretical calculations and predictions for the shot noise in voltage biased junctions of $d_{x^2-y^2}$ superconductors and normal metal counter-electrodes. In the clean limit for the d-wave superconductor the shot noise vanishes at zero voltage because of resonant Andreev reflection by zero-energy surface bound states. We examine the sensitivity of this resonance to impurity scattering. We report theoretical results for the magnetic field dependence of the shot noise, as well the fingerprints of subdominant $s$- and $d_{xy}$ pairing channels.Comment: 15 pages, 8 figures and 3 tables embedde

Influence of impurity scattering on tunneling conductance in normal metal- d -wave superconductor junctions

Tunneling conductance spectra between a normal metal / d-wave superconductor junction under the presence of bulk impurities in the superconductor are studied. The quasiclassical theory has been applied to calculate the spatial variation of the pair potential and the effect of impurity scattering has been introduced by t-matrix approximation. The magnitude of a subdominant s-wave component at the interface is shown to robust against the impurity scattering while that for a subdominant $d_{xy}$-wave component is largely suppressed with the increase of the impurity scattering rate. The zero-bias conductance peak due to the zero-energy Andreev bound states is significantly broadened for the case of Born limit impurity compared with that of unitary limit impurity.Comment: 14 pages, 5 figure

Anisotropy in the Hubble constant as observed in the HST Extragalactic Distance Scale Key Project results

Based on general relativity, it can be argued that deviations from a uniform Hubble flow should be thought of as variations in the Universe's expansion velocity field, rather than being thought of as peculiar velocities with respect to a uniformly expanding space. The aim of this paper is to use the observed motions of galaxies to map out variations in the Universe's expansion, and more importantly, to investigate whether real variations in the Hubble expansion are detectable given the observational uncertainties. All-sky maps of the observed variation in the expansion are produced using measurements obtained along specific lines-of-sight and smearing them across the sky using a Gaussian profile. A map is produced for the final results of the HST Extragalactic Distance Scale Key Project for the Hubble constant, a comparison map is produced from a set of essentially independent data, and Monte Carlo techniques are used to analyse the statistical significance of the variation in the maps. A statistically significant difference in expansion rate of 9 km/s/Mpc is found to occur across the sky. Comparing maps of the sky at different distances appears to indicate two distinct sets of extrema with even stronger statistically significant variations. Within our supercluster, variations tend to occur near the supergalactic plane, and beyond our supercluster, variations tend to occur away from the supergalactic plane. Comparison with bulk flow studies shows some concordance, yet also suggests the bulk flow studies may suffer confusion, failing to discern the influence of multiple perturbations.Comment: 23 pages, 5 figures, to be published in New Astronom