1 research outputs found
Base free transfer hydrogenation using a covalent triazine framework based catalyst
[EN] Isomerisation of allylic alcohols to saturated ketones can be efficiently catalysed by a heterogeneous molecular system resulting from (IrCp)-Cp-III* anchoring to a covalent triazine framework. The obtained catalysts are active, selective, and fully recyclable.Financial support from the Generalitat Valenciana (projects Consolider-Ingenio MULTICAT and AICO/2015/065), the Spanish Ministry of Economy and Competitiveness (MINECO) (program Severo Ochoa SEV20120267), and the Spanish Ministry of Science and Innovation (MICINN) (project MAT2014-52085-C2-1-P) are gratefully acknowledged. This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 641887 (project acronym: DEFNET). Also, financial support from the European Union Seventh Framework Programme (FP7/2007-2013) under the grant agreement number 309701, project Eco2CO2 is acknowledged.Bavykina, A.; Mautschke, H.; Makkee, M.; Kapteijn, F.; Gascon, J.; LlabrĂ©s I Xamena, FX. (2017). Base free transfer hydrogenation using a covalent triazine framework based catalyst. CrystEngComm. 19(29):4166-4170. https://doi.org/10.1039/C7CE00561JS416641701929Wang, D., & Astruc, D. (2015). The Golden Age of Transfer Hydrogenation. Chemical Reviews, 115(13), 6621-6686. doi:10.1021/acs.chemrev.5b00203Cirujano, F. G., Leyva-PĂ©rez, A., Corma, A., & LlabrĂ©sâ
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