Base free transfer hydrogenation using a covalent triazine framework based catalyst

[EN] Isomerisation of allylic alcohols to saturated ketones can be efficiently catalysed by a heterogeneous molecular system resulting from (IrCp)-Cp-III* anchoring to a covalent triazine framework. The obtained catalysts are active, selective, and fully recyclable.Financial support from the Generalitat Valenciana (projects Consolider-Ingenio MULTICAT and AICO/2015/065), the Spanish Ministry of Economy and Competitiveness (MINECO) (program Severo Ochoa SEV20120267), and the Spanish Ministry of Science and Innovation (MICINN) (project MAT2014-52085-C2-1-P) are gratefully acknowledged. This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 641887 (project acronym: DEFNET). 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