P20-08. Glycosylation: an important factor in Env diversity

Supported by a CAVD Grant from the Bill and Melinda Gates Foundation

Extracting the Redox Orbitals in Li Battery Materials with High-Resolution X-Ray Compton Scattering Spectroscopy

We present an incisive spectroscopic technique for directly probing redox orbitals based on bulk electron momentum density measurements via high-resolution x-ray Compton scattering. Application of our method to spinel LixMn2O4, a lithium ion battery cathode material, is discussed. The orbital involved in the lithium insertion and extraction process is shown to mainly be the oxygen 2p orbital. Moreover, the manganese 3d states are shown to experience spatial delocalization involving 0.16 electrons per Mn site during the battery operation. Our analysis provides a clear understanding of the fundamental redox process involved in the working of a lithium ion battery.Comment: 24 pages, 3 figure

Regularizing effect and local existence for non-cutoff Boltzmann equation

The Boltzmann equation without Grad's angular cutoff assumption is believed to have regularizing effect on the solution because of the non-integrable angular singularity of the cross-section. However, even though so far this has been justified satisfactorily for the spatially homogeneous Boltzmann equation, it is still basically unsolved for the spatially inhomogeneous Boltzmann equation. In this paper, by sharpening the coercivity and upper bound estimates for the collision operator, establishing the hypo-ellipticity of the Boltzmann operator based on a generalized version of the uncertainty principle, and analyzing the commutators between the collision operator and some weighted pseudo differential operators, we prove the regularizing effect in all (time, space and velocity) variables on solutions when some mild regularity is imposed on these solutions. For completeness, we also show that when the initial data has this mild regularity and Maxwellian type decay in velocity variable, there exists a unique local solution with the same regularity, so that this solution enjoys the $C^\infty$ regularity for positive time

Structure of 55Sc and development of the N=34 subshell closure

The low-lying structure of $^{55}$Sc has been investigated using in-beam $\gamma$-ray spectroscopy with the $^{9}$Be($^{56}$Ti,$^{55}$Sc+$\gamma$)$X$ one-proton removal and $^{9}$Be($^{55}$Sc,$^{55}$Sc+$\gamma$)$X$ inelastic-scattering reactions at the RIKEN Radioactive Isotope Beam Factory. Transitions with energies of 572(4), 695(5), 1539(10), 1730(20), 1854(27), 2091(19), 2452(26), and 3241(39) keV are reported, and a level scheme has been constructed using $\gamma\gamma$ coincidence relationships and $\gamma$-ray relative intensities. The results are compared to large-scale shell-model calculations in the $sd$-$pf$ model space, which account for positive-parity states from proton-hole cross-shell excitations, and to it ab initio shell-model calculations from the in-medium similarity renormalization group that includes three-nucleon forces explicitly. The results of proton-removal reaction theory with the eikonal model approach were adopted to aid identification of positive-parity states in the level scheme; experimental counterparts of theoretical $1/2^{+}_{1}$ and $3/2^{+}_{1}$ states are suggested from measured decay patterns. The energy of the first $3/2^{-}$ state, which is sensitive to the neutron shell gap at the Fermi surface, was determined. The result indicates a rapid weakening of the $N=34$ subshell closure in $pf$-shell nuclei at $Z>20$, even when only a single proton occupies the $\pi f_{7/2}$ orbital

Structural evolution in the neutron-rich nuclei 106Zr and 108Zr

The low-lying states in 106Zr and 108Zr have been investigated by means of {\beta}-{\gamma} and isomer spectroscopy at the RI beam factory, respectively. A new isomer with a half-life of 620\pm150 ns has been identified in 108Zr. For the sequence of even-even Zr isotopes, the excitation energies of the first 2+ states reach a minimum at N = 64 and gradually increase as the neutron number increases up to N = 68, suggesting a deformed sub-shell closure at N = 64. The deformed ground state of 108Zr indicates that a spherical sub-shell gap predicted at N = 70 is not large enough to change the ground state of 108Zr to the spherical shape. The possibility of a tetrahedral shape isomer in 108Zr is also discussed.Comment: 10 pages, 3 figures, Accepted for publication in Phys. Rev. Let

Study of J/psi to p pbar, Lambda Lambdabar and observation of eta_c to Lambda Lambdabar at Belle

We study the baryonic charmonium decays of B mesons, B+ to etac K+ and B+ to J/psi K+, where the etac and J/psi subsequently decay into a p pbar or Lambda Lambdabar pair. We measure the J/psi to p pbar, Lambda Lambdabar anisotropy parameters, alpha_B = -0.60 +- 0.13 +-0.14 (p pbar), -0.44 +- 0.51 +- 0.31 (Lambda Lambdabar) and compare to results from e+e- to J/psi formation experiments. We also report the first observation of etac to Lambda Lambdabar. The measured branching fraction is B(etac to Lambda Lambdabar) = (0.87 +0.24 -0.21(stat) +0.09 -0.14(syst) +- 0.27 (PDG)) x 10^-3. This study is based on a 357 fb^-1 data sample recorded on the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider.Comment: 8 pages, two figures (4 figure files), an update of hep-ex/0509020 for journal submissio

Time-Dependent CP Asymmetries in B0 -> Ks pi0 gamma transitions

We report measurements of CP violation parameters in B0->Ks pi0 gamma transitions based on a data sample of 535x10^6 BB pairs collected with the Belle detector at the KEKB asymmetric-energy e+ e- collider. One neutral B meson is fully reconstructed in the B0->Ks pi0 gamma mode. The flavor of the accompanying B meson is identified from its decay products. For a Ks pi0 invariant mass up to 1.8 GeV/c^2, we obtain S = -0.10 +- 0.31 +- 0.07 and A = -0.20 +- 0.20 +- 0.06. For a Ks pi0 invariant mass near the K*0(892) resonance, we obtain S = -0.32 +0.36-0.33 +-0.05 and A=-0.20 +-0.24 +-0.05.Comment: 6 pages, 3 figures, accepted by PR

Improved Measurements of Branching Fractions and CP Asymmetries in B-> eta h Decays

We report improved measurements of B decays with an eta meson in the final state using 492 fb^{-1} of data collected by the Belle detector at the KEKB e^+ e^- collider. We observe the decays B^{+-}-> eta pi^{+-} and B^{+-}-> eta K^{+-}; the measured branching fractions are Br(B^{+-}-> eta pi^{+-}) = (4.2+- 0.4(stat)+- 0.2(sys))x10^{-6} and Br(B^{+-}-> eta K^{+-}) = (1.9+-0.3(stat)^{+0.2}_{-0.1}(sys))x10^{-6}. The corresponding CP-violating asymmetries are measured to be -0.23+- 0.09(stat) +-0.02(sys) for eta pi^{+-} and -0.39+-0.16(stat)+-0.03(sys) for eta K^{+-}. We also search for B^0-> eta K^0 decays and set an upper limit of 1.9x10^{-6} at the 90% confidence level.Comment: 7 pages, 3 figure